THERMAL SCIENCE

International Scientific Journal

FLAME AND EMISSION CHARACTERISTICS FROM NH3/CH4 COMBUSTION UNDER ULTRASONIC EXCITATION

ABSTRACT
As a high energy density hydrogen-rich carrier, ammonia (NH3) is a highly promising carbon-free fuel. The large-scale industrial application of NH3 is limited by its low reactivity and high NOx emission. In this work, the flame and emission characteristics of ammonia/methane (NH3/CH4) non-premixed combustion were investigated under ultrasonic excitation. An experimental system was designed and built, including non-premixed combustion system, loading ultrasonic system, deflectionmography temperature measurement system and flue gas measurement system. Combustion and measurement experiments at different ultrasonic frequencies and NH3/CH4 blending ratios were carried out. Flame images and flue gas species concentrations under ultrasonic excitation were acquired. The 3-D temperature field was reconstructed. The influence of ultrasonic excitation at different frequencies on flame characteristics, flame temperature field and emission characteristics of the combustion process was analysed. The mechanism of NH3/CH4 combustion enhancement and emission reduction was revealed when the flame was ex-cited by ultrasonic waves. Results showed that part of the hydrocarbon fuels was replaced by NH3 to reduce CO2 emission. The height and color of the NH3/CH4 flame were changed and the high temperature area of the flame gradually expanded as ultrasonic acted on the flame. As ultrasonic frequency increased, the emission concentrations of unburned CH4, unburned NH3, and NO decreased significantly. The flame was ex-cited by ultrasonic waves, which reduced its local equivalent ratio, improved combustion efficiency and suppressed NOx generation.
KEYWORDS
PAPER SUBMITTED: 2022-10-08
PAPER REVISED: 2023-01-04
PAPER ACCEPTED: 2023-01-05
PUBLISHED ONLINE: 2023-02-11
DOI REFERENCE: https://doi.org/10.2298/TSCI221008029S
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2023, VOLUME 27, ISSUE Issue 5, PAGES [3607 - 3619]
REFERENCES
  1. Kobayashi, H., et al., Science and Technology of Ammonia Combustion, Proc. Combust. Inst., 37 (2019), 1, pp. 109-133
  2. Elbaz, A. M., et al., Review on the Recent Advances on Ammonia Combustion From the Fundamentals to the Applications, Fuel Commun., 10 (2022), 100053
  3. Shu, T., et al., An Experimental Study of Laminar Ammonia/Methane/Air Premixed Flames Using Expanding Spherical Flames, Fuel, 290 (2021), 120003
  4. Ji, L., et al., Experimental Study on Structure and Blow-off Characteristics of NH3/CH4 Co-Firing Flames in a Swirl Combustor, Fuel, 314 (2022), 123027
  5. Somarathne, K. D. K. A., et al., Modelling of Ammonia/Air Non-Premixed Turbulent Swirling Flames in a Gas Turbine-Like Combustor at Various Pressures, Combust. Theory Model., 22 (2018), 5, pp. 973-997
  6. Tian, Z., et al., An Experimental and Kinetic Modelling Study of Premixed NH3/CH4/O2/Ar Flames at Low Pressure, Combust. Flame, 156 (2009), 7, pp. 1413-1426
  7. Okafor, E. C., et al., Measurement and Modelling of The Laminar Burning Velocity of Methane-Ammonia-Air Flames at High Pressures Using a Reduced Reaction Mechanism, Combust. Flame, 204 (2019), June, pp. 162-175
  8. Mathieu, O., Petersen, E. L., Experimental and Modelling Study on the High-Temperature Oxidation of Ammonia and Related NOx Chemistry, Combust. Flame, 162 (2015), 3, pp. 554-570
  9. Juangsa, F. B., et al., The CO2-Free Power Generation Employing Integrated Ammonia Decomposition and Hydrogen Combustion-Based Combined Cycle, Therm. Sci. Eng. Prog., 19 (2020), 100672
  10. Cardoso, J. S., et al., Ammonia as an Energy Vector: Current and Future Prospects for Low-Carbon Fuel Applications In Internal Combustion Engines, Journal Clean. Prod., 296 (2021), 126562
  11. Dai, L., et al., Ignition Delay Times of NH3/DME Blends at High Pressure and Low DME Fraction: RCM Experiments And Simulations, Combust. Flame, 227 (2021), May, pp. 120-134
  12. Chen, Y., et al., Effect and Mechanism of Combustion Enhancement and Emission Reduction for Non-Premixed Pure Ammonia Combustion Based on Fuel Preheating, Fuel, 308 (2022), 122017
  13. Khateeb, A. A., et al., Stability Limits and Exhaust NO Performances of Ammonia-Methane-Air Swirl Flames, Exp. Therm. Fluid Sci., 114 (2020), 110058
  14. Ju, Y., Sun, W., Plasma Assisted Combustion: Dynamics and Chemistry, Prog. Energy Combust. Sci., 48 (2015), June, pp. 21-83
  15. Valera-Medina, A., et al., Premixed Ammonia/Hydrogen Swirl Combustion under Rich Fuel Conditions For Gas Turbines Operation, Int. J. Hydrogen Energy, 44 (2019), 16, pp. 8615-8626
  16. Kim, M., et al., Flame-Vortex Interaction and Mixing Behaviors of Turbulent Non-Premixed Jet Flames under Acoustic Forcing, Combust. Flame, 156 (2009), 12, pp. 2252-2263
  17. Guo, H., et al., Influence of Acoustic Energy on Suppression of Soot from Acetylene Diffusion Flame, Combust. Flame, 230 (2021), 111455
  18. Hirota, M., et al., Soot Control of Laminar Jet-Diffusion Lifted Flame Ex-Cited by High-Frequency Acoustic Oscillation, Journal Therm. Sci. Technol., 12 (2017), 2, pp. 1-10
  19. Lee, S. S., et al., An Experimental Study on the Structural Alteration of C3H8-Air Premixed Flame Affected by Ultrasonic Standing Waves of Various Frequencies, Journal Mech. Sci. Technol., 29 (2015), 3, pp. 917-922
  20. [20] Su, Y., et al., The 3-D Velocity and Temperature Distribution Measurement and Characteristic Analysi of Swirling Combustion, Measurement, 193 (2022), 110949
  21. Zhang, B., et al., Flame Four-Dimensional Deflectionmography with Compressed-Sensing-Revision Re-Construction, Opt. Lasers Eng., 83 (2016), Aug., pp. 23-31
  22. Zhang, B., et al., Deflectionmographic Reconstructions of a 3-D Flame Structure and Temperature Distribution Oo Premixed Combustion, Appl. Opt., 54 (2015), 6, 1341
  23. Ahn, M., et al., Effects of Acoustic Excitation on Pinch-off Flame Structure and NOx Emissions in H2/CH4 Flame, Int. J. Hydrogen Energy, 47 (2022), 26, pp. 13178-13190
  24. Mikofski, M. A., et al., Flame Height Measurement of Laminar Inverse Diffusion Flames, Combust. Flame, 146 (2006), 1-2, pp. 63-72
  25. Hayakawa, A., et al., Laminar Burning Velocity And Markstein Length of Ammonia/Air Premixed Flames at Various Pressures, Fuel, 159 (2015), Nov., pp. 98-106

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence