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THE SNO2 NANOTUBE WITH CNT CORE STRUCTURE (SNO2@VOID@CNT) AND GRAPHENE COMPOSITE ELECTRODE FOR LI-ION BATTERIES

ABSTRACT
In this study, the problem of volume expansion and agglomeration of SnO2-based electrode materials has been solved with a unique and multifaced approach. Nanosized SnO2 is coated around CNT with a void and this structure is decorated between graphene sheets. The problem of aggregation and volume expansion has been solved with nanostructure and voided structure. Besides, conductivity and buffering contributions have been provided by the production composite with graphene and CNT. Herein graphene layers were decorated SnO2 nanotube with CNT core structure (SnO2@void@CNT) and used as an anode for Li-ion battery. The electrodes were produced by vacuum filtration technique as flexible and free-standing with no any binder. To compare, pure SnO2 and SnO2 decorated graphene/CNT skeleton anodes were prepared and characterized. The SnO2@void@CNT/graphene anode exhibited excellent cycling performance and rate capability properties.
KEYWORDS
PAPER SUBMITTED: 2022-11-18
PAPER REVISED: 2022-11-30
PAPER ACCEPTED: 2023-05-13
PUBLISHED ONLINE: 2023-09-17
DOI REFERENCE: https://doi.org/10.2298/TSCI2304217A
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2023, VOLUME 27, ISSUE Issue 4, PAGES [3217 - 3228]
REFERENCES
  1. Wen, Y., et al., Heteroatom-Doped Graphene for Electrochemical Energy Storage, Chinese Sci. Bull., 59, (2014), 18, pp. 2102-2121
  2. Li, Z., et al., Particulate Modification of Lithium-Ion Battery Anode Materials and Electrolytes, Particuology, 83, (2023), Dec., pp. 129-141
  3. Mand Khan, B., et al., Role of Graphene-Based Nanocomposites as Anode Material for Lithium-Ion Batteries, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol., 287 (2021), Sept., 116141
  4. Ullah, K., et al., Recent Trends in Graphene Based Transition Metal Oxides as Anode Materials for Rechargeable Lithium-Ion Batteries, Nano Trends, 1 (2022), Nov., 100004
  5. Nzereogu, P. U., et al., Anode Materials for Lithium-Ion Batteries: A Review, Appl. Surf. Sci. Adv., 9 (2022), Mar., 100233
  6. Yuan, S., et al., Carbon-Based Materials as Anode Materials for Lithium-Ion Batteries and Lithium-Ion Capacitors: A Review, J. Energy Storage, 61 (2022), Dec., 106716
  7. Li, X., et al., Recent Progress in the Carbon-Based Frameworks for High Specific Capacity Anodes/Cathode in Lithium/Sodium Ion Batteries, Xinxing Tan Cailiao/New Carbon Mater., 36 (2021), 1, pp. 106-116
  8. Deng, X., et al., SnO2-MoO3 Nanoparticles Anchored in Carbon Nanotubes as a Large-Capacity, High-Rate, and Long-Lifetime Anode for Lithium-Ion Batteries, Ceram. Int., 47 (2021), 19, pp. 27022-27031
  9. Li, Y., et al., A Nanoscale Interlayer Void Design Enabling High-Performance SnO2-Carbon Anodes, Carbon N. Y., 183 (2021), Oct., pp. 486-494
  10. Fan, B., et al., A Facile Strategy Towards High Capacity and Stable Sn Anodes for Li-Ion Battery: Dual-Confinement via Sn@SnO2 Core-Shell Nanoparticles Embedded in 3D Graphitized Porous Carbon Network, J. Alloys Compd., 857 (2021), Mar., 157920
  11. Wang, X., et al., Electrospun Layers by Layers Orderly Stacked SnO2@aligned Carbon Nanofibers as High Conductivity, Long Cycle Life Self-Standing Anode for Reversible Lithium Ions Batteries, Surfaces and Interfaces, 29 (2022), Feb., 101814
  12. Premasudha, M., et al., Hydrothermal Synthesis and Electrochemical Behaviour of SnO2/C@rGO as an Anode Material for Na-Ion Batteries, Chem. Phys. Lett., 805 (2022), Feb., 139970
  13. Wei, L., et al., A Facile Assembly of SnO2 Nanoparticles and Moderately Exfoliated Graphite for Advanced Lithium-Ion Battery Anode, Electrochim. Acta, 432 (2022), June, 141210
  14. Wei, L., et al., SnO2/Sn Particles Anchored in Moderately Exfoliated Graphite as the Anode of Lithium-Ion Battery, Electrochim. Acta, 442 (2022), Dec., 141908
  15. Yang, L., et al., SnO2 Nanoparticles Composited with Biomass N-Doped Carbon Microspheres as Low Cost, Environmentally Friendly and High-Performance Anode Material for Sodium-Ion and Lithium-Ion Batteries, J. Power Sources, 547 (2022), Sept., pp. 1-11
  16. Xin, Y., et al., Engineering Amorphous SnO2 Nanoparticles Integrated Into Porous N-Doped Carbon Matrix as High-Performance Anode for Lithium-Ion Batteries, J. Colloid Interface Sci., 639 (2023), June, pp. 133-144
  17. Li, W. L., et al., Heterojunction of SnO2/Sn Nanoparticles Coated by Graphene-Like Porous Carbon as Ultrahigh Capacity Anode of Lithium-Ion Batteries, J. Alloys Compd., 948 (2023), July, 169811
  18. Zhou, F. Y., et al., Porous SnO2 Nanospheres Coated with Reduced Graphene Oxide for Formaldehyde Gas Sensor: Synthesis, Performance and Mechanism, J. Mater. Res., 38 (2023), Jan., pp. 1266-1281
  19. Marcano, D. C., et al., Improved Synthesis of Graphene Oxide, ACS Nano, 4 (2010), 8, pp. 4806-4814
  20. Alaf, M., et al., Graphene Supported Heterogeneous Catalysts for Li-O2 Batteries, Appl. Surf. Sci., 380 (2016), Sept., pp. 185-192
  21. Zhang, M., et al., Fabrication of Mesoporous Silica-Coated CNT and Application in Size-Selective Protein Separation, J. Mater. Chem., 20 (2010), 28, pp. 5835-5842
  22. Alaf, M.,et al., Double Phase Tinoxide/tin/MWCNT Nanocomposite Negative Electrodes for Lithium Microbatteries, Microelectron. Eng., 126 (2014), Aug., pp. 143-147
  23. Akbulut, H., et al., The Superior Surface Discharge Capacity of Core-Shell Tinoxide/Multi Walled Carbon Nanotube Nanocomposite Anodes for Li-Ion Batteries, Acta Phys. Pol. A, 125 (2014), 2, pp. 335-337
  24. Zhang, J. Wang, X., Microwave Absorbing Property and Preparation of CoNi@SiO2@PPy Composite in X-Band, J. Mater. Sci. Mater. Electron., 29 (2018), 2, pp. 1592-1599
  25. Liang, Y., et al., Synthesis and Characterization of Core-Shell Structured SiO2@YVO4:Yb3+,Er3+ Micro-spheres, Appl. Surf. Sci., 258 (2012), 8, pp. 3689-3694
  26. Alaf, M., Akbulut, H., Electrochemical Energy Storage Behavior of Sn/SnO2 Double Phase Nanocomposite Anodes Produced on the Multiwalled Carbon Nanotube Buckypapers for Lithium-Ion Batteries, J. Power Sources, 247 (2014), Feb., pp. 692-702
  27. Zhou, S., et al., SnO2 Anchored in S and N Co-Doped Carbon as the Anode for Long-Life Lithium-Ion Batteries, Nanomaterials, 12 (2022), 4, 700
  28. Li, H., et al., Porous SNO2 hollow Microspheres as Anodes for High-Performance Lithium Ion Battery, Mater. Lett., 217 (2018), Apr., pp. 276-280
  29. Liu, M., et al., Octahedral Tin Dioxide Nanocrystals Anchored on Vertically Aligned Carbon Aerogels as High Capacity Anode Materials for Lithium-Ion Batteries, Nat. Publ. Gr., 6 (2016), Aug., 31496
  30. Zhang, D., et al., One-Step Synthesis of SnO2/carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries, Nanomaterials, 11 (2021), 11, 3138
  31. Jiang, S., et al., Free-Standing SnO2@rGO Anode via the Anti-solvent-assisted Precipitation for Superior Lithium Storage Performance, Front. Chem., 7 (2019), Dec., pp. 1-10
  32. Ma, D., et al., Novel Hollow SnO2 Nanosphere @ TiO 2 Yolk - Shell Hierarchical Nano-Spheres as Anode Material for High-Performance Lithium-Ion Batteries, Mater. Lett., 157 (2015), Oct., pp. 228-230
  33. Zhang, B., et al., SnO2-Graphene-Carbon Nanotube Mixture for Anode Material with Improved Rate Capacities, Carbon N. Y., 49 (2011), 13, pp. 4524-4534
  34. Kebede, M. A., Tin Oxide-Based Anodes for Both Lithium-Ion and Sodium-Ion Batteries, Curr. Opin. Electrochem., 21 (2020), 1, pp. 182-187
  35. Li, B., et al., Yolk-Shelled SnO2@NxC Spheres with Controllable Void Space as High-Capacity and Cycle-Stable Anode Materials for Lithium-Ion Batteries, Mater. Des., 219 (2022), July, 110745
  36. Zhou, D., et al., Three-Dimensional Porous Graphene-Encapsulated CNT@SnO2composite for High-Performance Lithium and Sodium Storage, Electrochim. Acta, 230 (2017), Mar., pp. 212-221
  37. Dhanabalan, A., et al., Porous SnO2/CNT Composite Anodes: Influence of Composition and Deposition Temperature on the Electrochemical Performance, J. Mater. Res., 25 (2010), 8, pp. 1554-1560
  38. Zhu, S., et al., Precise Growth of Al2O3/SnO2/CNT Composites by a Two-Step Atomic Layer Deposition and Their Application as an Improved Anode for Lithium Ion Batteries, Electrochim. Acta, 319 (2019), Oct., pp. 490-498

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