THERMAL SCIENCE
International Scientific Journal
INVESTIGATION OF GASIFICATION REACTIONS AND H2/CO RATIO ANALYSIS FOR RICE HUSK AIR GASIFICATION SIMULATION
ABSTRACT
The syngas generated during gasification process is used for industrial process heat, power generation and chemical feedstock production. Gas composition, H2/CO and CO/CO2 ratios are the deciding factors for producer gas end-use. In the present work, rice husk air gasification simulation is carried out by non-stoichiometric equilibrium model using Gibbs free energy minimization by FactSage 6.3 software. Influence of gasification reactions and effect of temperature, equiv¬alence ratio on gas composition was studied. The analysis was carried out to study the effect of operating conditions on producer gas heating value and gasification efficiency at various H2/CO ratios. Increase in temperature improves H2 and CO formation in water gas reaction and reduction of H2 formation was observed in water gas shift reaction due to endothermic behavior change. For all the values of the equivalence ratio, ϕ, an increase in temperature reduces the H2/CO and enhances the CO/CO2 ratio due to higher CO formation. For a particular, ϕ, value, maximum gas heating value and gasification efficiency were obtained at low H2/CO ratio.
KEYWORDS
PAPER SUBMITTED: 2022-01-19
PAPER REVISED: 2022-04-26
PAPER ACCEPTED: 2022-04-28
PUBLISHED ONLINE: 2022-07-09
THERMAL SCIENCE YEAR
2023, VOLUME
27, ISSUE
Issue 1, PAGES [881 - 890]
- +++, Ministry of New and Renewable Energy, Government of India,mnre.gov.in › bioenergy › current-status
- Niu, Y., et al., Experimental Study on Steam Gasification of Pine Particles for Hydrogen-Rich Gas, Journal of Energy Institute, 90 (2016), 5, pp. 715-724
- Zainal, Z. A., et al., Prediction of Performance of a Downdraft Gasifier Using Equilibrium Modelling for Different Biomass Materials, Energy Conversion and Management, 42 (2001), 12, pp. 1499- 1515
- Ardebili, Z. R., et al., Influence of the Effective Parameters on H2:CO Ratio of Syngas at Low Temperature Gasification, Chemical Engineering Transactions, 37 (2014), Jan., pp. 253-258
- Tristantini, D., et al., The Effect of Synthesis Gas Composition on the Fischer-Tropsch Synthesis Over Co/γ-Al2O3 and Co-Re/γ-Al2O3 Catalysts, Fuel Processing Technology, 88 (2007), 7, pp. 643-649
- Cao, Y., et al., Synthesis Gas Production with an Adjustable H2/CO Ratio through the Coal Gasification Process: Effects of Coal Ranks and Methane Addition, Energy Fuels, 22 (2008), 3, pp. 1720-1730
- Buragohain, B., et al., Thermodynamic Optimization of Biomass Gasification for Decentralized Power Generation and Fischer-Tropsch Synthesis, Energy, 35 (2010), 6, pp. 2557-2579
- Karmakar, M. K., et al., Investigation of Fuel Gas Generation in a Pilot Scale Fluidized Bed Autothermal Gasifier Using Rice Husk, Fuel, 111 (2013), Sept., pp. 584-591
- Li, X., et al., Equilibrium Modelling of Gasification: A Free Energy Minimization Approach and Its Application a Circulating Fluidized Bed Coal Gasifier, Fuel, 80 (2001), 2, pp. 195-207
- Altafini, C. R., et al., Prediction of the Working Parameters of a Wood Waste Gasifier through an Equilibrium Model, Energy Conversion and Management, 44 (2003), 17, pp. 2763-2777
- Yoshida, H., et al., Two-Stage Equilibrium Model for a Coal Gasifier to Predict the Accurate Carbon Conversion in Hydrogen Production, Fuel, 87 (2008) 10-11, pp. 2186-2193
- Lan, C., et al., Thermodynamic and Kinetic Behaviors of Coal Gasification, Thermochimica Acta, 666 (2018), June, pp. 174-180
- Shabbar, S., Janajreh, I., Thermodynamic Equilibrium Analysis of Coal Gasification Using Gibbs Energy Minimization Method, Energy Conversion and Management, 65 (2013), Jan., pp. 755-763
- Cheng, G., et al., Gasification of Biomass Micron Fuel with Oxygen-Enriched Air: Thermogravimetric Analysis and Gasification in a Cyclone Furnace, Energy, 43 (2012), 1, pp. 329-333
- Proll, T., Hofbauer, H., The H2 Rich Syngas by Selective CO2 removal from Biomass Gasification in a Dual Fluidized Bed System-Process Modelling Approach, Fuel Processing Technology, 89 (2008), 11, pp. 1207-1217
- Ngo, S. I., et al., Performance Evaluation for Dual Circulating Fluidized-Bed Steam Gasifier of Biomass Using Quasi-Equilibrium Three-Stage Gasification Model, Applied Energy, 88 (2011), 12, pp. 5208-5220
- Dillibabu, V., et al., Energy, Exergy and Sustainability Analysis of Rice Husk Air Gasification Process, Thermal Science, 23 (2019), 2A, pp. 549-560
- Dillibabu, V., et al., Air and Oxygen Gasification Simulation Analysis of Sawdust, Thermal Science, 23 (2019), 2B, pp. 1043-1053
- Mohamed Zakriya, G., Ramakrishnan, G., Insulation and Mechanical Properties of Jute and Hollow Conjugated Polyester Reinforced Non-Woven Composite, Energy and Buildings, 158 (2018), Jan., pp. 1544-1552
- Mothilal, T., Pitchandi, K., Influence of Inlet Velocity of Air and Solid Particle Feed Rate on Holdup Mass and Heat Transfer Characteristics in Cyclone Heat Exchanger, Journal of Mechanical Science and Technology, 29 (2015), 10, pp. 4509-4518
- Subramanian, P., et al., Fluidized Bed Gasification of Select Granular Biomaterials, Bioresource Technology, 102 (2011), 2, pp. 1914-1920
- Azzone, E., et al., Development of an Equilibrium Model for the Simulation of Thermo Chemical Gasification and Application Agricultural Residues, Renewable Energy, 46 (2012), Oct., pp. 248-254
- Gambarotta, A., et al., A Non-Stoichiometric Equilibrium Model for the Simulation of the Biomass Gasification Process, Applied Energy, 227 (2018), Oct., pp. 119-127
- Gai, C., Dong, Y., Experimental Study on Non-Woody Biomass Gasification in a Downdraft Gasifier, International Journal of Hydrogen Energy, 37 (2012), 6, pp. 4935-4944
- Loha, C., et al., Performance of Fluidized Bed Steam Gasification of Biomass-Modelling and Experiment, Energy Conversion and Management, 52 (2011), 3, pp. 1583-1588
- Melgar, A., et al., Thermochemical Equilibrium Modelling of a Gasifying Process, Energy Conversion and Management, 48 (2007), 1, pp. 59-67
- Parvez, A. M., et al., Energy, Exergy and Environmental Analyses of Conventional, Steam and CO2-Enhanced Rice Straw Gasification, Energy, 94 (2016), Jan., pp. 579-588
- Rosen, M. A., et al., Role of Exergy in Increasing Efficiency and Sustainability and Reducing Environmental Impact, Energy Policy, 36 (2008), 1, pp. 128-137
- Wang, L. Q., Chen, Z. S., Gas Generation by Co-Gasification of Biomass and Coal in an Autothermal Fluidized Bed Gasifier, Applied Thermal Engineering, 59 (2013), 1-2, pp. 278-282
- Bridgwater, A. V., Renewable Fuels and Chemicals by Thermal Processing of Biomass, Chemical Engineering Journal, 91 (2003), 2-3, pp. 87-102
- Broer, K. M., et al., Steam/Oxygen Gasification System for the Production of Clean Syngas from Switchgrass, Fuel, 140 (2015), Jan., pp. 282-292
- Moghadam, R. A., et al., Investigation on Syngas Production Via Biomass Conversion through the Integration of Pyrolysis and Air-Steam Gasification Processes, Energy Conversion and Management, 87 (2014), Nov., pp. 670-675