THERMAL SCIENCE
International Scientific Journal
OPTIMIZED BIODIESEL PRODUCTION FROM C. INNOPHYLLUM BIO-OIL USING KRIGING AND ANN PREDICITIVE MODELS
ABSTRACT
This work aimed at optimizing the two-stage transesterification efficiency of the production of C. inophyllum biodiesel using artificial neural network and Kriging predictive models. Response surface methodology was used to develop the central rotatable composite design of 27 trial experimental runs with variations in the input process parameters like methanol to oil molar ratio, potassium hydroxide catalyst loading, and reaction time. A multi-layered non-linear regressive artificial neural network model with feed-forward propagation and a numerical surrogate Kriging model was used to predict the C. inophyllum biodiesel yield. The efficacy of the developed model was verified using analysis of variance by com-paring its coefficient of determination and the mean relative percentage deviation values. The optimized C. inophyllum biodiesel as 98.1% is derived with 0.94 v/v of methanol to oil molar ratio, 0.98 wt.% of potassium hydroxide catalyst loading, and 80 minutes reaction time with 70ºC constant reaction temperature as predicted by Kriging model. The optimized parameters were also verified experimentally.
KEYWORDS
PAPER SUBMITTED: 2021-11-27
PAPER REVISED: 2022-01-25
PAPER ACCEPTED: 2022-02-01
PUBLISHED ONLINE: 2022-03-05
THERMAL SCIENCE YEAR
2022, VOLUME
26, ISSUE
Issue 5, PAGES [4217 - 4232]
- Demirbas, A., Importance of biodiesel as transportation fuel, Energy Policy, 35(9) (2007), pp. 4661-70. doi.org/10.1016/j.enpol.2007.04.003
- Venkatesan, H., et al., Cotton seed biodiesel as alternative fuel: Production and its characterization analysis using spectroscopic studies, International Journal of Renewable Energy Research, 7(3), 2017, pp. 1333-39.
- Cakirca, E. E., et al., Catalytic activity of CaO-based catalyst in transesterification of microalgae oil with methanol, Energy Environ, 30, 2018, pp. 176-87. doi.org/10.1177/0958305X18787317
- Betiku, E., Ajala, S. O, Modelling and optimization of Thevetia peruviana (Yellow oleander) oil biodiesel synthesis via Musa paradisiacal (plantain) peels as heterogeneous base catalyst: A case of artificial neural network vs. response surface methodology, Industrial Crops and Products, 53, 2014. pp. 314-22. doi.org/10.1016/j.indcrop.2013.12.046
- Arumugam., Ponnusami, V., Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview, Renewable Energy, 131, 2019, pp. 459-471. doi.org/10.1016/j.renene.2018.07.059
- Hariram, V., et al., Performance assessment of artificial neural network on the prediction of Calophyllum inophyllum biodiesel through two-stage transesterification, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 43(9), 2021, pp. 1060-1072. doi.org/10.1080/15567036.2019.1634164
- Venkanna, B. K., Venkataramana Reddy, C., Biodiesel production and optimization from Calophyllum inophyllum Linn oil (Honne oil) - A three stage method, Bio Resource Technology, 100, 2009, pp. 122-25. doi.org/10.1016/j.biortech.2009.05.023
- Ayoola, F. K., et al., Response surface methodology and artificial neural network analysis of crude palm kernel oil biodiesel production, Chemical Data Collection, 28, 2020, 100478. doi.org/10.1016/j.cdc.2020.100478
- Akshay Garg., Siddharth Jain., Process parameter optimization of biodiesel production from algal oil by response surface methodology and artificial neural networks, Fuel, 277, 2020, 118254. doi.org/10.1016/j.fuel.2020.118254
- Eriola Betiku., et al., Performance evaluation of artificial neural network coupled with generic algorithm and response surface methodology in modelling and optimization of biodiesel production process parameters from shea tree (Vitellaria paradoxa) nut butter, Renewable Energy, 76, 2015, pp. 408-417. doi.org/10.1016/j.renene.2014.11.049
- Benjamin Ogaga Oghose., et al., Optimization of biodiesel production from Thevetia peruviana seed oil by adaptive neuro-fuzzy interference system coupled with genetic algorithm and response surface methodology, Energy Conversion and Management, 132, 2017, pp. 231-240. doi.org/10.1016/j.enconman.2016.11.030
- Timothy, W., et al., Kriging models for global approximation in simulation-based multidisciplinary design optimization, AIAA Journal, 39 (12), 2001, pp. 2233 - 2241. doi.org/10.2514/2.1234
- Irfan Kaymaz. Application of Kriging method to structural reliability problems, Structural safety, 27, 2005, pp. 33-151. doi.org/10.1016/j.strusafe.2004.09.001
- Shinkyu Jeong., et al., Efficient optimization design method using Kriging model, Journal of Aircraft, 42(2), 2005, pp. 413-420. doi.org/10.2514/1.6386
- Hariram, V., Vasanthaseelan, S., Optimization of base catalyzed transesterification and characterization of Brassica napus (Canola seed) for the production of biodiesel, International Journal of ChemTech Research, 8(9), 2015, pp. 418-23.
- Selvabala, V. S., et al., Two-step biodiesel production from Calophyllum inophyllum oil: Optimization o modi ied β-zeolite catalyzed pre-treatment, Bio Resource Technology, 102, 2011, pp. 1066-72. doi.org/10.1016/j.biortech.2010.08.052
- Cressie, N., Statistics for Spatial Data, Wiley, Newyork, USA. 1993.
- Wackernagel, H., Geo-statistical models and kriging, IFAC Proceedings, 36(16), 2003, pp. 543-548. doi.org/10.1016/S1474-6670(17)34818-8
- Hariram, V et al., Spectrometric analysis of algal biodiesel as a fuel derived through base-catalysed transesterification, International Journal of Ambient Energy, 40 (2), 2019, pp. 195-202. doi.org/10.1080/01430750.2017.1381153
- Narula, V., et al., Process parameter optimization of low temperature transesterification of algae-Jatropha Curcas oil blend, Energy, 119, 2017, pp. 983-988. doi.org/10.1016/j.energy.2016.11.043
- Verma, P., Sharma, M, P., Review of process parameters for biodiesel production from different feedstocks, Renew Sustain Energy Rev, 62, 2016, pp. 1063-1071. doi.org/10.1016/j.rser.2016.04.054
- Hariram, V., et al., Reduction of exhaust emission using a nano-metallic enriched lemongrass biodiesel blend, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 39(21), 2017, pp. 2065-71. doi.org/10.1080/15567036.2017.1395495
- Vasudev, K. L., et al., A modular and integrated optimization model for UVs, Defence Sci. J, 66 (1), 2016, pp. 71-80. doi.org/10.14429/dsj.66.8889
- Zhao, X., et al., Optimization of transesterification of beef tallow for biodiesel production catalyzed by solid catalysts, Nongye Gongcheng Xuebao/Transactions Chinese Soc. Agric Eng; 29(17), 2013, pp. 196-203.