THERMAL SCIENCE

International Scientific Journal

Thermal Science - Online First

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Study of bio-oil production from sewage sludge of a municipal wastewater treatment plant by using hydrothermal liquefaction (HTL)

ABSTRACT
To overcome the problem of rapid depletion of natural energy reserves and consequent pollution caused by them, this work explored the possibility of utilizing sewage sludge biomass to produce bio-oil using hydrothermal liquefaction (HTL) pathway. In this study, effect of different reaction parameters such as reaction temperature, residence time, and sludge-to-water (ss-to-water) ratio on solid biomass conversion and bio-yield and its higher heating value (HHV) were investigated. Although maximum conversion of (99.7 %) and highest bio-oil yield (22.01 wt%) was achieved at 330°C, however optimum temperature was chosen as 300°C which produced conversion efficiency and yield of bio-oil very close (98.07 % and 21.5 wt% respectively) to what was obtained at 330°C as lower temperature is beneficial for overall economy of the process. Similarly, a residence time of 60 min and ss-to-water ratio of 1:6 was screened to be producing optimized yield of bio-oil. HHV of different fractions bio-oil was much improved (30.18 MJ kg-1 of acetone phase and 38.04 MJ kg-1of DCM phase) as compared to that of raw feedstock (12.74 MJ kg-1). Carbon balance performed on the products indicated that maximum amount of carbon went to bio-oil phase (53.4 wt%). However, a significant portion of carbon was lost (33.9 wt%) due to the limitation of experiments at lab scale which involves evaporation and drying to reach final products. FTIR spectral analysis of different bio-oil phases showed that it was mainly made up of alcohols, alkane, ketones, aldehydes and carboxylic acids.
KEYWORDS
PAPER SUBMITTED: 2023-07-28
PAPER REVISED: 2023-10-10
PAPER ACCEPTED: 2023-10-22
PUBLISHED ONLINE: 2023-12-10
DOI REFERENCE: https://doi.org/10.2298/TSCI230728262Z
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