THERMAL SCIENCE
International Scientific Journal
CARBON DIOXIDE AS THE REPLACEMENT FOR SYNTHETIC REFRIGERANTS IN MOBILE AIR CONDITIONING
ABSTRACT
Based on Kyoto Protocol and the decisions of European Commission R134a refrigerant, currently dominantly used in mobile air conditioning systems, needs to be phased-out. At present automotive industry looks at carbon dioxide (CO2; R744) as the refrigerant of the future. Apart from the environmental benefits discussed are the technical characteristics of carbon dioxide refrigeration cycle and mobile air-conditioning systems in comparison to R134a refrigerant. Analyzed are challenges emerged from the use of CO2 as refrigerant and improvement opportunities in regards to increase of the system performance and efficiency. Particular attention is dedicated to the advantages of CO2 utilization in prospective automotive heat pump systems.
KEYWORDS
PAPER SUBMITTED: 2008-03-04
PAPER REVISED: 2008-07-07
PAPER ACCEPTED: 2008-08-31
THERMAL SCIENCE YEAR
2008, VOLUME
12, ISSUE
Issue 3, PAGES [55 - 64]
- Vesovic, V., et al., The Transport Properties of Carbon Dioxide, Journal of Physical and Chemical Reference Data, 19 (1990), 3, pp. 763-808
- Choi, K. I., et al., Boiling Heat Transfer of R-22, R-134a and CO2 in Horizontal Smooth Minichannels, International Journal of Refrigeration, 30 (2007), 8, pp. 1336-1346
- Pettersen, J., Rieberer, R., Leister, A., Heat Transfer and Pressure Drop Characteristics of Supercritical Carbon Dioxide in Microchannel Tubes under Cooling, Proceedings, 4th IIR Gustav Lorenzen Conference on Natural Working Fluids, West Lafayette, Ind., USA, 2000, pp. 99-106
- Pitla, S., et al., Convective Heat Transfer from in-Tube Flow of Turbulent Supercritical Carbon Dioxide, Part 1: Numerical Analysis, International Journal HVAC&R Research, 7 (2001), 4, pp. 345-366
- Pitla, S., Groll, E., Ramadhyani, S., Convective Heat Transfer from in-Tube Flow of Turbulent Supercritical Carbon Dioxide, Part 2: Experimental Data and Numerical Predictions, International Journal HVAC&R Research, 7 (2001), 4, pp. 367-382
- Liao, S., Zhao, T., Measurements of Heat Transfer Coefficients from Supercritical Carbon Dioxide Flowing in Horizontal Mini/Meso Channels, Journal of Heat Transfer, 124 (2002), 3, pp. 413-420
- Lorentzen, G., Pettersen, J., New Possibilities for Non-CFC Refrigeration, Proceedings, IIR International Symposium on Refrigeration, Energy and Environment, Trondheim, Norway, 1992, pp. 147-163
- Lorentzen, G., Revival of Carbon Dioxide as a Refrigerant, International Journal of Refrigeration, 17 (1993), 5, pp. 292-301
- Pettersen, J., Skaugen, G., Operation of Transcritical CO2 Vapour Compression Systems in Vehicle Air Conditioning, Proceedings, International Conference on New Applications of Natural Working Fluids in Refrigeration and Air Conditioning, Hanover, Germany, 1994, pp. 495-505
- Billiard, F., The New European Regulation on Substances that Deplete the Ozone Layer Has Come into Force: What's New?, International Journal of Refrigeration, 24 (2001), 3, pp. 205-207
- Memory, S. et al., Vehicular CO2 AC System, Proceedings on CD Rom, 5th Vehicle Thermal Management Systems Conference, Nashwille, Tenn., USA, 2001
- Schwartz, W., R134a Emissions from Passenger Car Air Conditioning Systems, Proceedings on CD Rom, VDA Alternate Refrigerant Winter Meeting, Saalfelden, Austria, 2002
- Pearson, A., Carbon Dioxide New Uses for an Old Refrigerant, International Journal of Refrigeration, 28 (2005), 8, pp. 1140-1148
- Neksa, P., Wolf, F., R744 the Global Solution, Advantages and Possibilities, Proceedings on CD Rom, VDA Alternate Refrigerant Winter Meeting, Saalfelden, Austria, 2007
- Kim, M. H., Pettersen, J., Bullard, C., Fundamental Process and System Design Issues in CO2 Vapour Compression Systems, Progress in Energy and Combustion Science, 30 (2004), 2, pp. 119-174
- Boewe, D., et al., Contribution of Internal Heat Exchanger to Transcritical R744 Cycle Performance, International Journal HVAC&R Research, 7 (2001), 2, pp. 155-168
- Hrnjak, P., Design and Performance of Improved R744 System Based On 2002 Technology, Proceedings on CD Rom, SAE Automotive Alternate Refrigerant Systems Symposium, Scottsdale, Ariz., USA, 2003
- Chen, Y., Gu, J., The Optimum High Pressure for CO2 Transcritical Refrigeration Systems with Internal Heat Exchangers, International Journal of Refrigeration, 28 (2005), 8, pp. 1238-1249
- Antonijević, D., Froehling, J., Multichannel Heat Exchanger and Connection Unit (in Germany), Deutsches Patent- und Markenamt, DE10303595B4, 2005
- Dickson, T., Whittle, W., Stobbart, M., Internal Heat Exchanger Accumulator, US patent US6463757, 2004
- Petersen, J., et al., Development of Compact Heat Exchangers for CO2 Air-Conditioning Systems, International Journal of Refrigeration, 21 (1998), 3, pp. 180-193
- Antonijević, D., Hoffmann, H., Multichanel Flat Tube for Heat Exchanger (in German), Deutsches Patent und- Markenamt, DE102005052683.7, 2005
- Antonijević, D., Fin for Heat Exchanger with Flat and Parallel Refrigerant Tubes (in German), Deutsches Patent- und Markenamt, DE10360240B4, 2005
- Antonijević, D., Multiple Flow Heat Exchanger (in German), Deutsches Patent- und Markenamt, DE102006017434A1 (WO2007/014560), 2007
- Brown, J., Yana-Motta, S. F., Domanski, P. A., Comparitive Analysis of an Automotive Air Conditioning Systems Operating with CO2 and R134a, International Journal of Refrigerationm, 25 (2002), 1, pp. 19-32
- Hrnjak, P., Tehnological and Theoretical Opportunities for Further Improvement of Efficiency and Performance of the Refrigerant Candidates, Proceedings on CD Rom, VDA Alternate Refrigerant Winter Meeting, Saalfelden, Austria, 2007
- Wiesholek, F., Heckt, R., Improved Efficiency for Small Cars with R744, Proceedings on CD Rom, VDA Alternate Refrigerant Winter Meeting, Saalfelden, Austria, 2007
- Nickl, J., et al., Integration of a Three-Stage Expander into a CO2 Refrigeration System, International Journal of Refrigeration, 28 (2005), 8, pp. 1219-1224
- Elbel, S., Hrnjak, P., Experimental Validation of a Prototype Ejector Designed to Reduce Throttling Losses Encountered in Transcritical R744 System Operation, International Journal of Refrigeration, 31 (2008), 3, pp. 411-422
- Heckt, R., Antonijević, D., Heating Heat Exchanger (in German), Deutsches Patent- und Markenamt, DE10313234A1, 2004
- Heckt, R., Antonijević, D., Heat Exchanger Assembly, US Patent Application Publication, US20040231825A1, 2004
- Antonijević, D., Heckt, R., Heat Pump Supplementary Heating for Motor Vehicles, Journal of Automobile Engineering, 218 (2004), 10, pp. 1111-1117
- Heckt, R., CO2 Heat Pump Optimized for Fuel Economy, Proceedings on CD Rom, VDA Alternate Refrigerant Winter Meeting, Saalfelden, Austria, 2004
- Tamura, T., Yakumaru, Y., Nishiwaki, F., Experimental Study on Automotive Cooling and Heating Air Conditioning System Using CO2 as a Refrigerant, International Journal of Refrigeration, 28 (2005), 8, pp. 1302-1307