THERMAL SCIENCE

International Scientific Journal

TECHNICAL ASPECTS OF BIODIESEL PRODUCTION FROM VEGETABLE OILS

ABSTRACT
Biodiesel, a promising substitute as an alternative fuel has gained significant attention due to the finite nature of fossil energy sources and does not produce sulfur oxides and minimize the soot particulate in comparison with the existing one from petroleum diesel. The utilization of liquid fuels such as biodiesel produced from vegetable oil by transesterification process represents one of the most promising options for the use of conventional fossil fuels. In the first step of this experimental research, edible rice bran oil used as test material and converted into methyl ester and non-edible jatropha vegetable oil is converted into jatropha oil methyl ester, which are known as biodiesel and they are prepared in the presence of homogeneous acid catalyst and optimized their operating parameters like reaction temperature, quantity of alcohol and the catalyst requirement, stirring rate and time of esterification. In the second step, the physical properties such as density, flash point, kinematic viscosity, cloud point, and pour point were found out for the above vegetable oils and their methyl esters. The same characteristics study was also carried out for the diesel fuel for obtaining the baseline data for analysis. The values obtained from the rice bran oil methyl ester and jatropha oil methyl ester are closely matched with the values of conventional diesel and it can be used in the existing diesel engine without any hardware modification. In the third step the storage characteristics of biodiesel are also studied. .
KEYWORDS
PAPER SUBMITTED: 2008-01-20
PAPER REVISED: 2008-01-21
PAPER ACCEPTED: 2008-03-15
DOI REFERENCE: https://doi.org/10.2298/TSCI0802159K
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2008, VOLUME 12, ISSUE Issue 2, PAGES [159 - 169]
REFERENCES
  1. Ma, F., Hanna, M. A., Biodiesel Production: A Review, Bio resource Tech., 990, pp. 1-15
  2. Demirbas, A., Biodiesel Fuels from Vegetable Oils via Catalytic and Non Catalytic Supercritical Alcohol Transesterification and other Methods: A Survey, Energy Convers Management, 44 (2003), pp. 93-109
  3. Tewari, K. S., Mehrrota, S. N., Vishnoi, N. K., Text Book of Organic Chemistry, Vikas Publishing House Pvt. Ltd., New Delhi, 1985, pp. 585- 609
  4. Morrison. R. T., Boyd, R. N., Organic Chemistry, 6th ed., Prentice Hall of India pvt. Ltd., 2005, pp. 771-778
  5. Krishnakumar, J., Venkatachalapathy, V. S. K., Comparative Analysis of Mineral Diesel, Vegetable Oil and Their Blends, Proceedings, National Conference Organized by the Department of Mechanical Engineering, Kumaraguru College of Technology, Coimbatore, India, Vol. 1, 2007
  6. Freedman, B., Pryde, E. H., Mounts, T. L., Variables Affecting the Yields of Fatty Esters from Transesterified Vegetable Oils, J. Am. Oil Chem. Soc., 61 (1984), 10, pp. 1638-1643
  7. Zhang, Y., Dube, M. A., Mclean, D. D., et al., Biodiesel Production from Waste Cooking Oil, Process Design and Technological Assessment, Bio Resource Tech., 2003, pp. 1 -15
  8. Barn Wall, B. K., Sharma, M. P., Prospects of Biodiesel Production from Vegetable Oils in India, Renewable & Sustainable Energy Review, 9 (2005), pp. 363-378
  9. ***, Nandhini chemical journal., Sept, Oct., Nov., 2005
  10. Silva, F. N. D., Prata, A. S., Teixcira, J. R., Technical Feasibility Assessment of Oleic Sunflower Methyl Ester Utilization in Diesel Bus Engines, Energy Conversion and Management, 44 (2003), pp. 2857-2878
  11. Meher, L. C., Sagar, D. V., Naik, S. N., Technical Aspects of Biodiesel Production by Transesterification - A Review, Renewable and Sustainable Energy Review, 20 (2004), pp. 1-21
  12. Hass, M. J., Scott, K. M., Marmer, W. N., Foliga, T. A., In Situ Alkaline Transesterification; an Effective Method for the Production of Fatty Acid Esters from Vegetable Oils, J. Am. Oil Chem. Soc., 81 (2004), pp. 83-89
  13. Dorado, M. P., et al., Optimization of Alkali Catalized Transesterifaction of Brassica Carinata Oil for Biodiesel Production, Energy Fuel, 18 (2004), pp. 77-83
  14. Igwe, I. O., The Effects of Temperature on the Viscosity of Vegetable Oils in Solution, Industrial Crops and Products, 19 (2004), pp. 185-190
  15. Ryan III, T. W., Dodge, L. G., Callahan,T. J., The Effects of Vegetable Oil Properties on Injection and Combustion in Two Different Diesel Engines, J. Am. Oil Chem. Soc., 61 (1984), 10, pp. 1610-1619

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