THERMAL SCIENCE

International Scientific Journal

INVESTIGATION OF NO EMISSION CHARACTERISTIC OF AMMONIA-HYDROGEN FLAME IN A TWO-STAGE MODEL COMBUSTOR

ABSTRACT
The laminar burning velocity and NO formation process of ammonia-hydrogen combustion within a two-stage combustion chamber were investigated numerically in the present study. A chemical reactor network method involving perfectly stirred reactor, plug flow reactor, and partially stirred reactor configurations with the 24-species Xiao mechanism was implemented to simulate the premixed ammonia-hydrogen-air combustion process. The effects of inlet temperature and pressure conditions on the laminar burning velocity were investigated. Results proved that elevated pressure condition decreased primary flame thickness leading to lower laminar burning velocity while inlet temperature increased flame temperature which in turn increased the laminar burning velocity. Investigation of the effect of humidification on the laminar burning velocity showed that humidification can counteract the effect of high inlet temperature. The NO emission studies indicated a twofold impact of pressure on NO formation processes: preventing NO formation in the primary combustion zone, and promoting thermal NO formation in the lean combustion zone. The minimum amounts of NO emission were obtained at total equivalence ratios of 0.4. Humidification prevented the NO formation in the lean combustion through the competitive effect of H2O on O, whilst temperature effect was comparatively small. Humidity and pressure were optimized in the two-stage configuration achieve both low emission and high efficiency.
KEYWORDS
PAPER SUBMITTED: 2023-04-28
PAPER REVISED: 2023-08-06
PAPER ACCEPTED: 2023-08-23
PUBLISHED ONLINE: 2023-10-08
DOI REFERENCE: https://doi.org/10.2298/TSCI230428199W
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2024, VOLUME 28, ISSUE Issue 2, PAGES [1689 - 1699]
REFERENCES
  1. Dunn, S., Hydrogen futures:Toward a Sustainable Energy System, Int. J. Hydrog. Energy, 27 (2002), 3, pp. 235-264
  2. Birol, F., Hydrogen: Accelerating and Expanding Deployment, IEA, Paris, France, 2018
  3. Chiuta S., et al., Reactor Technology Options for Distributed Hydrogen Generation via Ammonia Decomposition: A Review, Int.J. Hydrog. Energy., 38 (2013), 35, pp. 14968-14991
  4. Kobayashi, H., et al., Science and Technology of Ammonia Combustion, Proc. Combust Inst., 37 (2019), 1, pp. 109-133
  5. Hayakawa, A., et al., Laminar Burning Velocity and Markstein Length of Ammonia/Air Premixed Flames at Various Pressures, Fuel, 159 (2015), Nov., pp. 98-106
  6. Hayakawa, A., et al., Experimental Investigation of Stabilization and Emission Characteristics of Ammonia/Air Premixed Flames in a Swirl Combustor, Int. J. Hydrog. Energy., 42 (2017), 19, pp. 14010-14018
  7. Somarathne, K. D. K. A., et al., Numerical Investigation on the Combustion Characteristics of Turbulent Premixed Ammonia/Air Flames Stabilized by a Swirl Burner, Journal Fluid. Sci. Tec., 11 (2016), 4, pp. JFST0026-JFST0026
  8. Valera-Medina, A., et al., Ammonia-Methane Combustion in Tangential Swirl Burners for Gas Turbine Power Generation, Applied Energy., 185 (2017), 2, pp. 1362-1371
  9. Honzawa, T., et al., Predictions of NO and CO Emissions in Ammonia/Methane/Air Combustion by LES Using a Non-Adiabatic Flamelet Generated Manifold, Energy, 186 (2019), 115771
  10. Slefarski, R., et al., Experimental Study on Combustion of CH4/NH3 Fuel Blends in an Industrial Furnace Operated in Flameless Conditions, Thermal Science, 24 (2020), 6A, pp. 3625-3635
  11. Zhang, J., et al., Effects of Ammonia Addition on Combustion Characteristics in Partially-Premixed Swirling Ammonia/Methane/Air Flame, Thermal Science, 26 (2022), 6A, pp. 4547-4559
  12. Yi, S., et al., Flame and Emission Characteristics from NH3/CH4 Combustion under Ultrasonic Excitation, Thermal Science, 27 (2023), 5A, pp. 3607-3619
  13. Hewlett, S., et al., Industrial Wastewater As an Enabler of Green Ammonia to Power Via Gas Turbine Technology, Proceedings, Turbo Expo: Power for Land, Sea, and Air, 2020, Virtual. Vol. 84119. p. V003T03A006
  14. Lee, J. H., et al., Studies on Properties of Laminar Premixed Hydrogen-Added Ammonia/Air Flames for Hydrogen Production, Int. J. Hydrog. Energy, 35 (2010), 3, pp. 1054-1064
  15. Li, H., et al., Boosting Low-Temperature Selective Catalytic Reduction of NOx with NH3 of V2O5/TiO2 Catalyst via B-Doping, Chin. J. Chem. Eng., 44 (2022), Apr., pp. 377-383
  16. Zhao, H., et al., A Comparative Study of the Thermal and Hydrothermal Aging Effect on Cu-SSZ-13 for the Selective Catalytic Reduction of NOx with NH3, Chin. J. Chem. Eng., 45 (2022), May, pp.68-77
  17. Okafor, E. C., et al., Measurement and Modelling of the Laminar Burning Velocity of Methane-Ammonia-Air Flames at High Pressures Using a Reduced Reaction Mechanism, Combust. Flame, 204 (2019), June, pp. 162-175
  18. Han, X., et al., Experimental and Kinetic Modelling Study of Laminar Burning Velocities of NH3/Air,NH3/ H2/Air,NH3/CO/Air and NH3/CH4/air Premixed Flames,Combust, Flame., 206 (2019), Aug., pp. 214-226
  19. Valera-Medina A., et al., Preliminary Study on Lean Premixed Combustion of Ammonia-Hydrogen for Swirling Gas Turbine Combustors, Int. J. Hydrog. Energy., 42 (2017), 38, pp. 24495-24503
  20. Valera-Medina, A., et al., Premixed Ammonia/Hydrogen Swirl Combustion Under Rich Fuel Conditions for Gas Turbines Operation, Int. J. Hydrog. Energy, 44 (2019),16, pp. 8615-8626
  21. Kurata, O., et al., Performances and Emission Characteristics of NH3-Air and NH3CH4-Air Combustion Gas-Turbine Power Generations, Proc. Combust. Insti., 36 (2017), 3, pp. 3351-3359
  22. Somarathne, K. D. K. A., et al., Numerical Study of a low Emission Gas Turbine Like Combustor for Turbulent Ammonia/Air Premixed Swirl Flames with a Secondary Air Injection at High Pressure, Int. J. Hydrogen Energy., 42 (2017), 44, pp. 27388-27399
  23. Okafor, E. C., et al., Towards the Development of an Efficient low-NOx Ammonia Combustor for a Micro Gas Turbine, Proc. Combust. Insti., 37 (2019), 4, pp. 4597-4606
  24. Pugh, D., et al., Influence of Steam Addition and Elevated Ambient Conditions on NOx Reduction in a Staged Premixed Swirling NH3/H2 Flame, Proc. Combust. Insti., 37 (2019), 4, pp. 5401-5409
  25. ***, Cantera. www.cantera.org
  26. Xiao, H., et al., Study on Reduced Chemical Mechanisms of Ammonia/Methane Combustion under Gas Turbine Conditions, Energy Fuels, 30 (2016), 10, pp. 8701-8710
  27. Mao, C. L., et al., Laminar Flame Speed and NO Emission Characteristics of Premixed Flames with Different Ammonia-Containing Fuels (in Chinese), Journal Chem. Ind. Eng., 72 (2021), 10, pp. 5330-5343
  28. ***, ANSYS CHEMKIN PRO version18.1.www.ansys.com/products/fluidsansys-chemkin-proANSYS
  29. Li, S., et al., Analysis of Air-Staged Combustion of NH3/CH4 Mixture with Low NOx Emission at Gas Turbine Conditions in Model Combustors, Fuel, 237 (2019), Feb., pp. 50-59
  30. Mashruk, S., et al., Rich-Quench-Lean Model Comparison for the Clean Use of Humidified Ammonia/Hydrogen Combustion Systems, Int. J. Hydrogen Energy, 46 (2021), 5, pp. 4472-4484
  31. Hussein, N. A., et al., Ammonia-Hydrogen Combustion in a Swirl Burner with Reduction of NOx Emissions, Energy Procedia, 158 (2019), Feb., pp. 2305-2310
  32. Han, X., et al., The Temperature Dependence of the Laminar Burning Velocity and Superadiabatic Flame Temperature Phenomenon for NH3/Air Flames, Combust. Flame, 217 (2020), July, pp. 314-320
  33. da Rocha, R. C., et al., Chemical Kinetic Modelling of Ammonia/Hydrogen/Air Ignition, Premixed Flame Propagation and NO Emission, Fuel, 246 (2019), June, pp. 24-33

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence