THERMAL SCIENCE

International Scientific Journal

HIGH-PRESSURE IGNITION BEHAVIORS OF METHANE/ETHANE/PROPANE-N-HEPTANE MIXTURES REPRESENTING NATURAL GAS-DIESEL DUAL FUEL

ABSTRACT
Considering that natural gas is the key transition fuel towards the carbon-neutral future, the objective of the present study is to gain insight into evolution features of natural gas-diesel dual fuel during ignition process. Firstly, new experimental data of ignition delay times for the stoichiometric methane/ethane/propane-n-heptane mixtures, which is of significance for validating and optimizing chemical kinetic models of the dual fuel at engine-relevant conditions, were acquired through a shock-tube facility at pressure of 40 atmopshere within temperature range of 1200-1600 K, and quantitative influences of components of the fuel mixtures on ignition were determined. Then importance of species including typical radicals and alkenes during ignition processes were identified. Besides, stage characteristics of the fuel mixtures during ignition processes were analyzed. The result shows that the ignition of real natural gas which contains some ethane and propane is greatly different from that of methane. It can be seen that the C2 substances are significant to control ignition of the mixtures. For methane-n-heptane and methane/ethane-n-heptane mixtures, the whole ignition process can be divided into decomposition and oxidation stages. While for the fuel mixtures containing propane and n-heptane, it seems to be more reasonable to divide the whole ignition process into three-stages, i.e., decomposition, mixed and oxidation stages.
KEYWORDS
PAPER SUBMITTED: 2023-01-09
PAPER REVISED: 2023-04-26
PAPER ACCEPTED: 2023-04-29
PUBLISHED ONLINE: 2023-06-11
DOI REFERENCE: https://doi.org/10.2298/TSCI230109120H
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2024, VOLUME 28, ISSUE Issue 1, PAGES [115 - 132]
REFERENCES
  1. Ogden, J., et al., Natural Gas as a Bridge to Hydrogen Transportation Fuel: Insights from the Literature, Energy Policy, 115 (2018), Apr., pp. 317-329
  2. Papagiannakis, R. G., Hountalas, D. T., Combustion and Exhaust Emission Characteristics of a Dual Fuel Compression Ignition Engine Operated with Pilot Diesel Fuel and Natural Gas, Energy Conversion and Management, 45 (2004), 18-19, pp. 2971-2987
  3. Korakianitis, T., et al., Natural-Gas Fueled Spark-Ignition (SI) and Compression-Ignition (CI) Engine Performance and Emissions, Progress in Energy and Combustion Science, 37 (2011), 1, pp. 89-112
  4. Lu, X., et al., Experimental Studies on the Dual-Fuel Sequential Combustion and Emission Simulation, Energy, 51 (2013), 1, pp. 358-373
  5. Liang, J., et al., Experimental and Kinetic Studies of Ignition Processes of the Methane-n-Heptane Mixtures, Fuel, 235 (2019), Jan., pp. 522-529
  6. El Bakali, A., et al., Experimental and Modelling Study of the Oxidation of Natural Gas in a Premixed Flame, Shock Tube, and Jet-Stirred Reactor, Combustion and Flame, 137 (2004), 1-2, pp. 109-128
  7. Huang, J., Bushe, W. K., Experimental and Kinetic Study of Autoignition in Methane/Ethane/Air and Methane/Propane/Air Mixtures under Engine-Relevant Conditions, Combustion and Flame, 144 (2006), 1-2, pp. 74-88
  8. Healy, D., et al., Methane/Ethane/Propane Mixture Oxidation at High Pressures and at High, Intermediate and Low Temperatures, Combustion and Flame, 155 (2009), 3, pp. 441-448
  9. Bourque, G., et al., Ignition and Flame Speed Kinetics of Two Natural Gas Blends with High Levels of Heavier Hydrocarbons, Journal of Engineering for Gas Turbines and Power, 132 (2010), 2, 021504
  10. Healy, D., et al., Oxidation of C1-C5 Alkane Quinternary Natural Gas Mixtures at High Pressures, Energy and Fuels, 24 (2010), 3, pp. 1521-1528
  11. Aul, C. J., et al., Ignition and Kinetic Modelling of Methane and Ethane Fuel Blends with Oxygen: A Design of Experiments Approach, Combustion and Flame, 160 (2013), 7, pp. 1153-1167
  12. Kuppa, K., et al., Predicting Ignition Delay Times of C1-C3 Alkanes/Hydrogen Blends at Gas Engine Conditions, Fuel, 222 (2018), June, pp. 859-869
  13. Bergman, M., Golovitchev, V. I., Modification of a Diesel Oil Surrogate Model for 3-D CFD Simulation of Conventional and HCCI Combustion, SAE Technical Papers, 2008-01-2410, 2008
  14. Wang, H., et al., Development of an n-heptane/Toluene/Polyaromatic Hydrocarbon Mechanism and Its Application for Combustion and Soot Prediction, International Journal of Engine Research, 14 (2013), 5, pp. 434-451
  15. Pei, Y., et al., A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications, Journal of Engineering for Gas Turbines and Power, 137 (2015), 11, 111502
  16. Aggarwal, S. K., et al., Ignition Characteristics of Heptane-Hydrogen and Heptane-Methane Fuel Blends at Elevated Pressures, International Journal of Hydrogen Energy, 36 (2011), 23, pp. 15392-15402
  17. Hu, E., et al., Kinetic Study on Laminar Burning Velocities and Ignition Delay Times of C1-C4 Alkanes (in Chinese), Journal of Engineering Thermophysics, 34 (2013), 3, pp. 558-562
  18. Ramalingam, A., et al., An RCM Experimental and Modelling Study on CH4 and CH4/C2H6 Oxidation at Pressures up to 160 bar, Fuel, 206 (2017), Oct., pp. 325-333
  19. Holton, M. M., et al., Autoignition Delay Time Measurements of Methane, Ethane, and Propane Pure Fuels and Methane-Based Fuel Blends, Journal of Engineering for Gas Turbines and Power, 132 (2010), 091502
  20. Zhang, K., et al., An Updated Experimental and Kinetic Modelling Study of n-Heptane Oxidation, Combustion and Flame, 172 (2016), Oct., pp. 116-135
  21. Mehl, M., et al., Kinetic Modelling of Gasoline Surrogate Components and Mixtures under Engine Conditions, Proceedings of the Combustion Institute, 33 (2011), 1, pp. 193-200
  22. Morley, C., Gaseq Chemical Equilibrium Program N. D. http://www.gaseq.co.uk/, 2005
  23. Plichta, D., et al., Laminar Flame Speeds of Natural Gas Blends with Hydrogen at Elevated Pressures and Temperatures, Proceedings, 8th U. S. National Combustion Meeting, Park City, Ut., USA, 2013
  24. Abd El-Sabor, M. A., et al., The Ignition of C1-C7 Natural Gas Blends and the Effect of Hydrogen Addition in the Low and High Temperature Regimes, Journal of Engineering for Gas Turbines and Power, 143 (2022), 8, 081022
  25. Eric, L. P., et al., A Facility for Gas- and Condensed-Phase Measurements behind Shock Waves, Measurement Science and Technology, 16 (2005), 9, pp. 1716-1729
  26. Shen, H. P., et al., A Shock Tube Study of Iso-Octane Ignition at Elevated Pressures: The Influence of Diluent Gases, Combustion and Flame, 155 (2008), 4, pp. 739-755
  27. Turns, S. R., An Introduction Combustion: Concepts and Applications, 2nd ed., McGraw-Hill, Singapore, Singapore, 2000
  28. Wang, H., et al., A Physics-Based Approach to Modelling Real-Fuel Combustion Chemistry-I, Evidence from Experiments, and Thermodynamic, Chemical Kinetic and Statistical Considerations, Combustion and Flame, 193 (2018), 4, pp. 502-519

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence