THERMAL SCIENCE

International Scientific Journal

EFFECTS OF AMMONIA ADDITION ON COMBUSTION CHARACTERISTICS IN PARTIALLY-PREMIXED SWIRLING AMMONIA/METHANE/AIR FLAME

ABSTRACT
Ammonia combustion has received intense research interest recently for its potential to reduce CO2 emission. This study aims to investigate the turbulent combustion characteristics in a bluff-body burner for CH4/NH3 mixtures with different ammonia blending ratios (15%, 30%, and 45% by mole fraction) through large eddy simulation and experiments. The simulations are conducted using openFOAM with a low Mach number solver and the partially stirred reactor combustion model with a detailed reaction mechanism. The flow field of one typical case is measured using the particle image velocimetry technique to verify the accuracy of the numerical results.The combustion characteristics are discussed. As the ammonia blending ratio increases, the flame height shortens, the flame color gradually changes from blue to orange, and the intermittent local quenching zone moves upstream, indicating that the combustion is becoming unstable. Meanwhile, the flow fields exhibit similar characteristics though the ammonia concentration varies greatly. The CO and NO emissions are also discussed. The CO emission decreases and the NO emission increases as the ammonia blending ratio increases
KEYWORDS
PAPER SUBMITTED: 2021-10-20
PAPER REVISED: 2021-12-30
PAPER ACCEPTED: 2022-01-08
PUBLISHED ONLINE: 2022-02-05
DOI REFERENCE: https://doi.org/10.2298/TSCI211020013Z
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2022, VOLUME 26, ISSUE Issue 6, PAGES [4547 - 4559]
REFERENCES
  1. Jiang, J., et al., A Computational Study Of Preferential Diffusion And Scalar Transport In Nonpremixed Hydrogen-Air Flames, Int. J. Hydrogen Energy, 40 (2015), 45, pp. 15709-15722
  2. Kobayashi, H., et al., Science And Technology Of Ammonia Combustion, Proc. Combust. Inst., 37 (2019), 1, pp. 109-133
  3. Slefarski, R., et al., Experimental Study On Combustion Of CH4/NH3 Fuel Blends In An Industrial Furnace Operated In Flameless Conditions, Therm. Sci., 24 (2020), 6 PART A, pp. 3625-36235
  4. Michalsky, R., et al., Solar Thermochemical Production Of Ammonia From Water, Air And Sunlight: Thermodynamic And Economic Analyses, Energy, 42 (2012), 1, pp. 251-260
  5. Yang, S.J., et al., Recent Advances In Hydrogen Storage Technologies Based On Nanoporous Carbon Materials, Prog. Nat. Sci. Mater. Int., 22 (2012), 6, pp. 631-638
  6. Hayakawa, A., et al., Laminar Burning Velocity And Markstein Length Of Ammonia/Air Premixed Flames At Various Pressures, Fuel, 159 (2015), pp. 98-106
  7. Kumar, P., Meyer, T.R., Experimental And Modeling Study Of Chemical-Kinetics Mechanisms For H2-NH3-Air Mixtures In Laminar Premixed Jet Flames, Fuel, 108 (2013), pp. 166-176
  8. Um, D.H., et al., Combustion Stability Limits And NOx Emissions Of Nonpremixed Ammonia-Substituted Hydrogen-Air Flames, Int. J. Hydrogen Energy, 38 (2013), 34, pp. 14854-14865
  9. Okafor, E.C., et al., Experimental And Numerical Study Of The Laminar Burning Velocity Of CH4-NH3-Air Premixed Flames, Combust. Flame, 187 (2018), pp. 185-198
  10. Okafor, E.C., et al., Measurement And Modelling Of The Laminar Burning Velocity Of Methane-Ammonia-Air Flames At High Pressures Using A Reduced Reaction Mechanism, Combust. Flame, 204 (2019), pp. 162-175
  11. Okafor, E.C., et al., Control Of NOx And Other Emissions In Micro Gas Turbine Combustors Fuelled With Mixtures Of Methane And Ammonia, Combust. Flame, 211 (2020), pp. 406-416
  12. Zhang, M., et al., The blow-off and transient characteristics of co-firing ammonia/methane fuels in a swirl combustor, Proceedings, Proceedings of the Combustion Institute, January 1, 2021, Vol. 38, pp. 5859-5868
  13. Poinsot, T., Veynante, D., Theoretical And Numerical Combustion, 3rd Edition, R.T. Edwards, Inc, Pennsylvania, USA, 2012
  14. Germano, M., et al., A Dynamic Subgrid-Scale Eddy Viscosity Model, Phys. Fluids A, 3 (1991), 7, pp. 1760-1765
  15. Fureby, C., et al., A Computational Study Of Supersonic Combustion In Strut Injector And Hypermixer Flow Fields, Proc. Combust. Inst., 35 (2015), 2, pp. 2127-2135
  16. Sabelnikov, V., Fureby, C., LES Combustion Modeling For High Re Flames Using A Multi-Phase Analogy, Combust. Flame, 160 (2013), 1, pp. 83-96
  17. Miller, J.A., et al., Kinetic Modeling Of The Oxidation Of Ammonia In Flames, Combust. Sci. Technol., 34 (1983), 1-6, pp. 149-176
  18. Mathieu, O., Petersen, E.L., Experimental And Modeling Study On The High-Temperature Oxidation Of Ammonia And Related NOx Chemistry, Combust. Flame, 162 (2015), 3, pp. 554-570
  19. Dagaut, P., et al., The Oxidation Of Hydrogen Cyanide And Related Chemistry, Prog. Energy Combust. Sci., 34 (2008), 1, pp. 1-46
  20. Konnov, A.A., Implementation Of The NCN Pathway Of Prompt-NO Formation In The Detailed Reaction Mechanism, Combust. Flame, 156 (2009), 11, pp. 2093-2105
  21. Tian, Z., et al., An Experimental And Kinetic Modeling Study Of Premixed NH3/CH4/O2/Ar Flames At Low Pressure, Combust. Flame, 156 (2009), 7, pp. 1413-1426
  22. Smith, G.P., et al., GRI-Mech 3.0, combustion.berkeley.edu/gri-mech/version30/text30.html
  23. Mergheni, M.A., et al., Swirl Effects On Dynamics Characteristics Of A Coaxial Jet, Therm. Sci., 21 (2017), 6, pp. 2543-2552
  24. Zhang, B., et al., Simultaneous Deflection Tomography And PIV Measurements Of Non-Premixed Combustion, Opt. Lasers Eng., 127 (2020), April 2019, pp. 105944
  25. Patankar, S. V., Spalding, D.B., A Calculation Procedure For Heat, Mass And Momentum Transfer In Three-Dimensional Parabolic Flows, Int. J. Heat Mass Transf., 15 (1972), 10, pp. 1787-1806
  26. Issa, R.I., et al., The Computation Of Compressible And Incompressible Recirculating Flows By A Non-Iterative Implicit Scheme, J. Comput. Phys., 62 (1986), 1, pp. 66-82
  27. Mikofski, M.A., et al., Flame Height Measurement Of Laminar Inverse Diffusion Flames, Combust. Flame, 146 (2006), 1-2, pp. 63-72
  28. Huang, Y., Yang, V., Dynamics And Stability Of Lean-Premixed Swirl-Stabilized Combustion, Prog. Energy Combust. Sci., 35 (2009), 4, pp. 293-364
  29. Hung, H.Y., et al., Observation On A Fire Whirl In A Vertical Shaft Using High-Speed Camera And Associated Correlation Derived, Therm. Sci., 25 (2021), 2, pp. 1001-1012
  30. Valera-Medina, A., et al., Ammonia-Methane Combustion In Tangential Swirl Burners For Gas Turbine Power Generation, Appl. Energy, 185 (2017), pp. 1362-1371
  31. Somarathne, K.D.K.A., et al., Effects Of OH Concentration And Temperature On NO Emission Characteristics Of Turbulent Non-Premixed CH4/NH3/Air Flames In A Two-Stage Gas Turbine Like Combustor At High Pressure, Proc. Combust. Inst., 38 (2021), 4, pp. 5163-5170
  32. Wang, X., et al., Effects Of Pressure And Karlovitz Number On The Turbulence-Flame Interactions In Lean Premixed H2/Air Flames, Fuel, 234 (2018), pp. 1293-1300

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