THERMAL SCIENCE

International Scientific Journal

Authors of this Paper

External Links

Ya Li

,

Leigen Liu

,

Zhenfeng Lin

,

Shao-Wen Yao

A FREE-STANDING PAN/PMMA/RGO CARBON PAPER AS AN EFFECTIVE INTERLAYER FOR HIGH PERFORMANCE LITHIUM-SULFUR BATTERIES

ABSTRACT
The limitations of the polysulfides shuttling and lithium dendrites have been obstacles to improve the lithium-sulfur battery technology, resulting in low active material utilization and poor cycle life. Here we report a simple modification of the traditional lithium-sulfur battery configuration to achieve high capacity with a long cycle life and high reversible rate. Great improvement was observed with a carbonized PAN/PMMA/rGO paper between the anode and the separator in the active material utilization and capacity retention. The adding of a free-standing PAN/PMMA/rGO carbon interlayer demonstrated the feasibility of enhancing the performance of lithium-sulfur batteries.
KEYWORDS
PAN/PMMA/rGO carbon paper, interlayer, lithium-sulfur battery, performance
PAPER SUBMITTED: 2019-04-30
PAPER REVISED: 2019-09-22
PAPER ACCEPTED: 2019-09-22
PUBLISHED ONLINE: 2020-06-21
DOI REFERENCE: https://doi.org/10.2298/TSCI2004485L
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2020, VOLUME 24, ISSUE Issue 4, PAGES [2485 - 2490]
REFERENCES
  1. Yang, Y., et al., Nanostructured Sulfur Cathodes，Chem. Soc. Rev., 42 (2013), 7, pp. 3018-3032
  2. Zhang, S. S., Liquid Electrolyte Lithium/Sulfur Battery: Fundamental Chemistry, Problems, and Solutions, J. Power Sources, 231 (2013), June, pp. 153-162
  3. Gao, T. J., et al., Effects of Electrospun Carbon Nanofibers' Interlayers on High-Performance Lithium-Sulfur Batteries. Materials, 10 (2017), 4, 376
  4. Ji, X. L., et al., A Highly Ordered Nanostructured Carbon-Sulphur Cathode for Lithium-Sulphur Batteries, Nat. Mater., 8 (2009), 6, pp. 500-506
  5. Jayaprakash, N., et al., Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries, Angew. Chem., Int. Ed., 50 (2011), 26, pp. 5904-5908
  6. Yuan, L. X., et al., Improvement of Cycle Property of Sulfur-Coated Multi-walled Carbon Nanotubes Composite Cathode for Lithium/Sulfur Batteries, J. Power Sources, 189 (2009), 2, pp. 1141-1146
  7. Wei, S., et al., Sulphur-TiO2 Yolk-Shell Nanoarchitecture with Internal Void Space for Long-Cycle Lithium-Sulphur Batteries. Nat. Commun., 4 (2013), 1, pp. 1-6
  8. Ponraj, R., et al., Improvement of Cycling Performance of Lithium-Sulfur Batteries by Using Magnesium Oxide as a Functional Additive for Trapping Lithium Polysulfide, ACS Appl. Mater. Interfaces, 8 (2016), 6, pp. 4000-4006
  9. Liang, X., et al., A Highly Efficient Polysulfide Mediator for Lithium-Sulfur Batteries, Nat. Commun., 6 (2015), 1, pp. 1-8
  10. Li, G. C., et al., A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries, Adv. Energy Mater., 2 (2012), 10, pp. 1238-1245
  11. Zhou, W. D., et al., Yolk-Shell Structure of Polyaniline-Coated Sulfur for Lithium-Sulfur Batteries. J. Am. Chem. Soc., 135 (2013), 44, pp. 16736-16743
  12. Wu, B., et al., Enhanced Cycling Stability of Sulfur Cathode Surface-Modified By Poly (n-methyl-pyrrole), Electrochim Acta, 135 (2014), July, pp. 108-113
  13. Li, Y., et al., Ultrafine and Polar ZrO2-Inlaid Porous Nitrogen-Doped Carbon Nanofiber as Efficient Polysulfide Absorbent for High-performance Lithium-Sulfur Batteries with Long Lifespan, Chem. Eng. J., 349 (2018), Oct., pp. 376-387
  14. Su, Y. S., et al., Lithium-Sulphur Batteries with a Microporous Carbon Paper as a Bifunctional Interlay-er, Nat. Commun., 3 (2012), 1, pp. 1-6
  15. Zhou, G. M., et al., A Graphene-Pure-Sulfur Sandwich Structure for Ultrafast, Long-Life Lithium-Sulfur Batteries, Adv. Mater. 26 (2014), 4, pp. 625-631
  16. Xing, L. B., et al., Nitrogen, Sulfur-Codoped Graphene Sponge as Electroactive Carbon Interlayer for High-Energy and -Power Lithium-Sulfur Batteries, J. Power Sources, 303 (2016), Jan., pp. 22-28
  17. Wei, H., et al., Enhanced Cycle Performance of Lithium-Sulfur Batteries Using a Separator Modified with a PVDF-C Layer, ACS Appl. Mater. Interfaces, 6 (2014), 22, pp. 20276-20281
  18. Singhal, R., et al., A FreeStanding Carbon Nanofiber Interlayer for High-Performance Lithium-Sulfur batteries, J. Mater. Chem. A, 3 (2015), 8, pp. 4530-4538
  19. Balach, J., et al., Mesoporous Carbon Interlayers with Tailored Pore Volume as Polysulfide Reservoir for High-Energy Lithium-Sulfur Batteries, J. Phys. Chem. C, 119 (2015), 9, pp. 4580-4587
  20. Xue, J., et al., Electrospinning and Electrospun Nanofibers: Methods, Materials, and Applications, Chem. Rev., 119 (2019), 8, pp. 5298-5415
  21. Yu, D. N., et al., Snail-based nanofibers, Materials Letters, 220 (2018), 1, pp. 5-7
  22. Li, X. X., He, J. H., Nanoscale Adhesion and Attachment Oscillation Under the Geometric Potential, Part 1: The formation Mechanism of Nanofiber Membrane in the Electrospinning, Results in Physics, 12 (2019), Mar., pp. 1405-1410
  23. Liu, Y. Q., et al., Nanoscale Multi-Phase Flow and Its Application to Control Nanofiber diameter, Thermal Science, 22 (2018), 1, pp. 43-46
  24. He, J. H., et al., Review on Fiber Morphology Obtained by the Bubble Electrospinning and Blown Bubble Spinning, Thermal Science, 16 (2012), 5, pp. 1263-1279
  25. Zhao, L., et al., Sudden Solvent Evaporation in Bubble Electrospinning for Fabrication of Unsmooth Nanofibers, Thermal Science, 21 (2017), 4, pp. 1827-1832
  26. Liu, L. G., et al., Solvent Evaporation in a Binary Solvent System for Controllable Fabrication of Porous Fibers by Electrospinning, Thermal Science, 21 (2017), 4, pp. 1821-1825
  27. Tian, D., et al., Self-Assembly of Macromolecules in a Long and Narrow Tube, Thermal Science, 22 (2018), 4, pp. 1659-1664
  28. Peng, N. B., et al., A Rachford-Rice Like Equation for Solvent Evaporation in the Bubble Electrospinning, Thermal Science, 22 (2018), 4, pp. 1679-1683
  29. Liu, Z., et al., A Mathematical Model for the Formation of Beaded Fibers in Electrospinning, Thermal Science, 19 (2015), 4, pp. 1151-1154
  30. Tian, D., et al., Macromolecular Electrospinning: Basic Concept & Preliminary Experiment, Results in Physics, 11 (2018), Dec., pp. 740-742
  31. Li, X. X., et al., The Effect of Sonic Vibration on Electrospun Fiber Mats, Journal of Low Frequency Noise, Vibration and Active Control, 38 (2019), 3-4, pp. 1246-1291
  32. Tian, D., et al., Geometrical Potential and Nanofiber Membrane's Highly Selective Adsorption Property, Adsorption Science & Technology, 37 (2019), 5-6, pp. 367-388
  33. Liu, L. G., et al., Electrospun Polysulfone/Poly (Lactic Acid) Nanoporous Fibrous Mats for Oil Removal from Water, Adsorption Science & Technology, 37 (2019), 5-6, pp. 438-450
  34. Li, Y., et al., Fabrication and Characterization of ZrO2 Nanofibers by Critical Bubble Electrospinning for High-Temperature-Resistant Adsorption and Separation, Adsorption Science & Technology, 37 (2019), 5-6, pp. 425-437
  35. Zhou, C. J., et al., Silkworm-Based Silk Fibers by Electrospinning, Results in Physics, 15 (2019), Dec., ID 102646
  36. Zhao, J. H., et al., Needle's Vibration in Needle-Disk Electrospinning Process: Theoretical Model and Experimental Verification, Journal of Low Frequency Noise, Vibration and Active Control, 38 (2019) 3-4, pp. 1338-1344
PDF VERSION [DOWNLOAD]
A free-standing PAN/PMMA/rGO carbon paper as an effective interlayer for high performance lithium-sulfur batteries

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence