THERMAL SCIENCE

International Scientific Journal

MOLECULAR CHARACTERISTICS OF SALIX CHEILOPHILA CHEMICAL COMPONENTS

ABSTRACT
Salix cheilophila plays a role in sand control. However, due to the lack of systematic and in-depth analysis on the chemical composition of Salix chei lophila, it is difficult to develop higher-value products, resulting in low efficiency or even outright abandonment. In this paper, the components of Salix cheilophila and its change rule before/after extraction were introduced, and the thermal loss rules and pyrolysis properties of Salix cheilophila were also explained. The analytic result of FT-IR further confirmed that: the Salix cheilophila contains components including esters, aldehydes, alcohols and ethers, etc., and the organic solvent extraction does not made compound groups of Salix cheilophila significantly changed. There are four obvious stages in thermal loss treatment of Salix cheilophila. During thermal loss treatment, three critical turning points of temperature (44°C, 78°C, and 219°C) were observed, accompanied by significantly chemical changes such as macromolecule pyrolyzed into small volatile molecules. The pyrolysis products of Salix cheilophila extractive including esters, acid, alcohols, aldehyde, ethers, alkene, ammonium, anhydride, phenols, ketone, furans and heterocyclic compounds. There were quite differences among properties and functions of the components. Thus, the application prospects were also significantly different.
KEYWORDS
PAPER SUBMITTED: 2019-05-17
PAPER REVISED: 2019-08-28
PAPER ACCEPTED: 2019-09-11
PUBLISHED ONLINE: 2020-02-15
DOI REFERENCE: https://doi.org/10.2298/TSCI190517074Y
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2020, VOLUME 24, ISSUE Issue 3, PAGES [1861 - 1868]
REFERENCES
  1. Zhao JB. A Brief Discussion on the Exploitation and Utilization of Salix. Inner Mongolia Forestry, 2013, (10): 29.
  2. Xue Y, Yang GH, Chen JC, et al. Salix Characteristics and Their Comprehensive Utilization. East China Paper Industry, 2011, 42(04): 57-60+64.
  3. Zhang W, Zhang GS, Ning MS, et al. Preliminary Investigation and Analysis of Germplasm Resources of North Salix. Water and Soil Conservation Bulletin, 2010, 30(03): 148-152.
  4. Liu LY, Hu CR, Liu LL, et al. Rapid Detection and Separation of Olive Oil and Camellia Oil Based on Ion Mobility Spectrometry Fingerprints and Chemometric Models. European Journal of Lipid Science and Technology, 2017, 119(3).
  5. Liu QM, Peng WX. Py-GC/MS Analysis of Bioactive Components of 450°C Pyrolyzate from Ethanol Extractives of Oil-tea Cake. Key Engineering Materials, 2011, 480-481: 513-518.
  6. He GX, Zhang DQ, Liu QM, et al. 450°C-based Pyrolysis- GC/MS Analysis of Utilization of Benzene/ethanol-Extracted Residue from Oil-tea Cake. Key Engineering Materials, 2011, 480-481: 472-477.
  7. Rohollah T, Reza SM, Shalaleh M. Biochemical Detection of N-Acyl Homoserine Lactone from Biofilm-forming Uropathogenic Escherichia Coli Isolated from Urinary Tract Infection Samples. Reports of Biochemistry & Molecular Biology, 2015, 3(2).
  8. Suksuwan A, Lomlim L, Dickert FL, et al. Tracking the Chemical Surface Properties of Racemic Thalidomide and Its Enantiomers Using a Biomimetic Functional Surface on a Quartz Crystal Microbalance. Journal of Applied Polymer Science, 2015, 132(30).
  9. Savchenko D, Vorliček V, Kalabukhova E, et al. Infrared, Raman and Magnetic Resonance Spectroscopic Study of SiO2: C Nanopowders. Nanoscale Research Letters, 2017, 12: 292.
  10. Chen QW. Chemical Composition Analysis of Wood of Main Tree Species in Hunan. Journal of Zhongnan Forestry College, 1995, (02): 190-194.
  11. Wang SX, Sun YD, Huang AM. Study on Tree Identification of Wood IR Spectra. Forest Engineering, 2015, 31(06): 65-70.
  12. Zhang ZT, Wang WL, Geng J, et al. The Pyrolysis Loss Property, Kinetics and Product Components of the Pretreatment of Salix. Lin Produces Chemistry and Industry, 2016, 36(03): 107-113.
  13. Wu YW, Gong JH, Gao XY, et al. The Pyrolysis and Pyrolysis Kinetics of Salix. Journal of Guangxi University (Natural Science Edition), 2016, 41(05): 1651-1661.
  14. Luo S. The Identification of FTIR and GC-MS Fingerprint Spectra of Four Kinds of Rosewood Extract. Zhongnan Forestry University, 2013.
  15. Miao YW, Zhang GL. The Liquefaction Process and Its Structural Characterization of Salix Wood Phenol. Journal of Northwest Forestry College, 2013, 28(04): 162-165.
  16. Feng LQ, Gao XX, Wang XM. Microstructure and Its Chemical Composition Analysis of Salix. Journal of Inner Mongolia Forestry College, 1996, (01): 38-42.
  17. Lokesha V, Deepika T, Ranjini PS, et al. Operations of Nanostructures via SDD, ABC4 and GA5 Indices. Applied Mathematics & Nonlinear Sciences, 2017, 2(1): 173-180.
  18. Dewasurendra M, Vajravelu K. On the Method of Inverse Mapping for Solutions of Coupled Systems of Nonlinear Differential Equations Arising in Nanofluid Flow, Heat and Mass Transfer. Applied Mathematics & Nonlinear Sciences, 2018, 3(1): 1-14.
  19. Zhang ZT, Wang WL, Chang JM. TG-FTIR Analysis of Main Component Pyrolysis Characteristics of Salix. Journal of Northeast Forestry University, 2016, 44(06): 49-52+62.
  20. Cuetos M J, Morán A, Otero M, et al. Anaerobic Co-digestion of Poultry Blood with OFMSW: FTIR and TG-DTG Study of Process Stabilization. Environmental Technology, 2009, 30(6): 571-582.
  21. Mujumdar A S. TG-DTG Analysis of Chemically Bound Moisture Removal of AlF·3HO. Drying Technology, 2007, 25(4): 675-680.
  22. Jia H, Zhao J Z, Pu W F, et al. Thermal Study on Light Crude Oil for Application of High-Pressure Air Injection (HPAI) Process by TG/DTG and DTA Tests. Energy & Fuels, 2012, 26(3): 1575-1584.
  23. Wang S, Guo X, Tao L, et al. Mechanism Research on Cellulose Pyrolysis by Py-GC/MS and Subsequent Density Functional Theory Studies. Bioresource Technology, 2012, 104(1): 722-728.
  24. Khabbaz F, Karlsson S, Albertsson A. PY-GC/MS an Effective Technique to Characterizing of Degradation Mechanism of poly (L-lactide) in the Different Environment. Journal of Applied Polymer Science, 2015, 78(13): 2369-2378.
  25. Zhang S, Dong Q, Zhang L, et al. Effects of Water Washing and Torrefaction on the Pyrolysis Behavior and Kinetics of Rice Husk through TGA and Py-GC/MS. Bioresource Technology, 2016, 199: 352.
  26. Becerra V, Odermatt J. Detection and Quantification of Traces of Bisphenol A and Bisphenol S in Paper Samples Using Analytical Pyrolysis-GC/MS. Analyst, 2012, 137(9): 2250.

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence