THERMAL SCIENCE

International Scientific Journal

Ayşegül Çiğdem Adigüzel

,

Fatih Çakar

,

Bahire Filiz Şenkal

,

Özlem Cankurtaran

,

Yeşim Hepuzer Gürsel

,

Ferdane Karaman

DETERMINATION OF GLASS TRANSITION TEMPERATURE AND SURFACE PROPERTIES OF NOVEL CHALCONE MODIFIED POLY (STYRENE) BASED POLYMER

ABSTRACT
The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography (IGC) method, we determined glass transition temperature and surface properties of PVBC-DMAC. The obtained glass transition temperature, Tg, is a good agree with the one obtained by differential scanning calorimetry (DSC). Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters KA (acidic) and KD (basic) of the PVBC-DMAC surface were calculated. The obtained KA,KD values reflected that PVBC-DMAC surface has a basic character.
KEYWORDS
Inverse gas chromatography, chalcone modified poly (styrene) based polymer, glass transition temperature, surface properties, isomer solvent seperation
PAPER SUBMITTED: 2018-09-12
PAPER REVISED: 2018-10-27
PAPER ACCEPTED: 2018-11-26
PUBLISHED ONLINE: 2018-12-16
DOI REFERENCE: https://doi.org/10.2298/TSCI180912343A
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2019, VOLUME 23, ISSUE Supplement 1, PAGES [S193 - S202]
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Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

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