THERMAL SCIENCE
International Scientific Journal
SELF-ASSEMBLY OF MACROMOLECULES IN A LONG AND NARROW TUBE
ABSTRACT
Many nature materials have hierarchical structure, and its last cascade is always on a molecule scale, e. g., double-stranded DNA, making the hierarchy effective with minimal building blocks. Now artificial hierarchy can begin with a nanoscale level to embody the material with remarkable and fascinating properties which can be never achieved using non-hierarchical structure. A strong desire to fabricate some biomimicking hierarchies from a molecule level has been stimulating scientists. Herein we show that molecular structure can be easily controlled by a long and narrow tube, and self-assembly of macromolecules can be achieved to improve its crystallinity with plenty of excellent properties. We anticipate this paper to be a starting point for more sophisticated fabrication of fibers with self-assembly of macromolecules.
KEYWORDS
PAPER SUBMITTED: 2018-03-05
PAPER REVISED: 2018-06-16
PAPER ACCEPTED: 2018-06-18
PUBLISHED ONLINE: 2018-09-09
THERMAL SCIENCE YEAR
2018, VOLUME
22, ISSUE
Issue 4, PAGES [1659 - 1664]
- Omenetto, F. G., et al., New Opportunities for an Ancient Material, Science, 329 (2010), 5991, pp. 528-531
- Gosline, J. M., et al., The Mechanical Design of Spider Silks: From Fibroin Sequence to Mechanical Function, Journal of Experimental Biology, 202 (1999), 23, pp. 3295-3303
- Meyers, M. A., et al., Structural Biological Materials: Critical Mechanics-Materials Connections, Sci-ence, 339 (2013), 6121, pp. 773-779
- Lee, S. M., et al., Greatly Increased Toughness of Infiltrated Spider Silk, Science, 324 (2009), 5926, pp. 488-492
- van Beek, J. D., et al., The Molecular Structure of Spider Dragline Silk: Folding and Orientation of the Protein Backbone, Proceedings of the National Academy of the Sciences of the United States of America, 99 (2002), 16, pp. 10266-10271
- Goldman, A., Hierarchical Structure of Spider Dragline Silk Prevents Spinning, MRS Bulletin, 42 (2017), 9, pp. 625-625
- Hagn, F., et al., A Conserved Spider Silk Domain Acts as a Molecular Switch that Controls Fibre As-sembly, Nature, 465 (2010), May, pp. 239-242
- Ittah, S., et al., An Essential Role for the C-Terminal Domain of a Dragline Spider Silk Protein in Di-recting Fiber Formation, Biomacromolecules, 7 (2006), 6, pp. 1790-1795
- Askarieh, G, et al., Self-Assembly of Spider Silk Proteins is Controlled by a pH-Sensitive Relay, Nature, 465 (2010), May, pp. 236-238
- Nomidis, S. K., et al., Twist-Bend Coupling and the Torsional Response of Double-Stranded DNA, Physical Review Letters, 118 (2017), 21, ID 217801
- Kuetche, V. K., Ab Initio Bubble-Driven Denaturation of Double-Stranded DNA: Self-Mechanical Theory, Journal of Theoretical Biology, 401 (2016), July, pp. 15-29 Tian, D., et al.: Self-Assembly of Macromolecules in a Long and Narrow Tube 1664 THERMAL SCIENCE: Year 2018, Vol. 22, No. 4, pp. 1659-1664
- Liu, P., et al., Geometrical Potential: an Explanation on of Nanofibers Wettability, Thermal Science, 22 (2018), 1A, pp. 33-38
- Tian, D., et al., Strength of Bubble Walls and the Hall-Petch Effect in Bubble-Spinning, Textile Re-search Journal, On-line first, doi.org/10.1177/0040517518770679
- Hardy, J., G., et al., Polymeric Materials Based on Silk Proteins, Polymer, 49 (2008), 20, pp. 4309-4327
- Batchelor, G. K., An Introduction to Fluid Mechanics, Cambridge University Press, Cambridge, UK, 2004
- He, J.-H., et al., Review on Fiber Morphology Obtained by the Bubble Electrospinning and Blown Bub-ble Spinning, Thermal Science, 16 (2012), 5, pp. 1263-1279
- Yu, D. N., et al., Snail-Based Nanofibers, Materials Letters, 220 (2018), June, pp. 5-7
- Kong, H. Y., et al., Fractal Harmonic Law and Waterproof/Dustproof, Thermal Science, 18 (2014), 5, pp. 1463-1467
- He, J.-H., Fractal Calculus and its Geometrical Explanation, Results in Physics, 10 (2018), Sept., pp. 272-276
- Fan, J., et al., Fractal Heat Transfer in Wool Fiber Hierarchy, Heat Transfer Research, 44 (2013), 5, pp. 399-407
- Fan, J., et al., Model of Moisture Diffusion in Fractal Media, Thermal Science, 19 (2015), 4, pp. 1161-1166
- Fan, C., et al., Fluid-Mechanic Model for Fabrication of Nanoporous Fibers by Electrospinning, Thermal Science, 21 (2017), 4, pp. 1621-1625
- Sun, Q. L., et al., Effect of Hot-Pressing on Properties of Bubble Electrospun Nanofiber Membrane, Thermal Science, 21 (2017), 4, pp. 1633-1637
- Zhao, L., et al., Sudden Solvent Evaporation in Bubble Electrospinning for Fabrication of Unsmooth Nanofibers, Thermal Science, 21 (2017), 4, pp. 1827-1832
- Liu, L. G., et al., Solvent Evaporation in a Binary Solvent System for Controllable Fabrication of Porous Fibers by Electrospinning, Thermal Science, 21 (2017), 4, pp. 1821-1825