THERMAL SCIENCE

International Scientific Journal

THE INFLUENCE OF NATURAL AND SYNTHETIC ANTIOXIDANT ON OXIDATION STABILITY AND EMISSION OF SAPOTA OIL METHYL ESTER AS FUEL IN CI ENGINE

ABSTRACT
In this present study oxidation stability of sapota oil methyl ester with synthetic and natural antioxidant additives using Rancimat test is investigate. The performance and emission characteristics of the B20 blend of sapota oil methyl ester with different antioxidant additive are evaluated in a Diesel engine. The natural antioxidants namely citric acid, rosemary extract and leaf extract and synthetic antioxidants namely pyrogallol, propyl gallate and butylated hydroxylanisole are selected. Addition of all the antioxidant additive found to have improved the oxidation stability of the biodiesel to the required level. Pyrogallol is found to be the best among the synthetic antioxidant, while leaf extract is the best among the natural antioxidant. From the emission test it is found that B20 has better emission characters compared to diesel except NOx. Further the addition of leaf extract slightly reduces the NOx emission of B20 and appreciably suppresses smoke emission.
KEYWORDS
PAPER SUBMITTED: 2015-09-24
PAPER REVISED: 2016-01-21
PAPER ACCEPTED: 2016-02-12
PUBLISHED ONLINE: 2016-11-13
DOI REFERENCE: https://doi.org/10.2298/TSCI16S4991R
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2016, VOLUME 20, ISSUE Supplement 4, PAGES [S991 - S997]
REFERENCES
  1. Singh, S. P., Dipti, S., Biodiesel Production through the Use of Different Sources and Characterization of Oils and Their Esters as the Substitute of Diesel: A Review, Renewable and Sustainable Energy Reviews, 14 (2010), 1, pp. 200-216
  2. Liaquat, A. M., et al., Effect of Coconut Biodiesel Blended Fuels on Engine Performance and Emission Characteristic, Procedia Engineering, 56 (2013), pp. 583-590
  3. Freedman, B., Pryde, E. H., Fatty Esters from Vegetable Oils for Use as a Diesel Fuel, Transactions of the ASAE, 1 (1982), 1, pp. 117-122
  4. Qi, D. H., et al., Experimental Studies on the Combustion Characteristics and Performance of a Direct Injection Engine Fueled with Biodiesel/Diesel Blends, Energy Conversion and Management, 51 (2010), 1, pp. 2985-2992
  5. Roy, M. M., et al., Biodiesel Production and Comparison of Emissions of a DI Diesel Engine Fueled by Biodiesel-Diesel and Canola Oil-Diesel Blends at High Idling Operations, Applied Energy, 106 (2013), June, pp. 198-208
  6. Cheng, T. C., Hochgreb, S., Fundamental Spray Combustion Characteristics of Rapseed Biodiesel, Diesel and Blend, Energyprocedia, 75 (2015), 1, pp. 2394-2399
  7. Buyukkaya, E., Effects of Biodiesel on a DI Diesel Engine Performance, Emission and Combustion Characteristics, Fuel, 89 (2010), 10, pp. 3099-3105
  8. Altin, R., et al., The Potential of Using Vegetable Oil Fuels as Fuel for Diesel Engines, Energy Conversion and Management, 42 (2001), 5, pp. 529-538
  9. De Almeida, S. C. A., et al., Performance of a Diesel Generator Fueled with Palm Oil, Fuel, 81 (2002), 1,pp. 2097-2102
  10. Haseeb, A. S. M. A., et al., Compatibility of Automotive Materials in Biodiesel: A Review, Fuel, 90 (2011), 3, pp. 922-931
  11. Zhu, L., et al., Experimental Study on Particulate and NOx Emissions of a Diesel Engine Fueled with Ultra Low Sulfur Diesel, RME-Diesel Blends and PME-Diesel Blends, Science of Total Environment, 408 (2010), 5, pp. 1050-1058
  12. Ergenc, A. T., et al., Performance, Emission, and Heat Release Analyses of a Direct Injection Diesel Engine Running on Diesel and Soybean Ester Blend, Turkish Journal of Engineering & Environmental Sciences, 37 (2013), 1, pp. 23-32
  13. Godiganur, S., et al., 6BTA 5.9 G2-1 Cummins Engine Performance and Emission Tests Using Methyl Ester Mahua (Madhucaindica) Oil/Diesel Blends, Renewable Energy, 34 (2009), 1, pp. 2172-2177
  14. Bangkok, N., Biodiesel as an Additive for Diesohol, International Journal of Green Energy, 6 (2009), 1, pp. 57-72
  15. Srithar, K., et al., An Experimental Investigation on Diesel and Low Heat Rejection Engines with Dual Biodiesel Blends, International Journal of Green Energy, 10 (2013), 10, pp. 1041-1055
  16. Dunn, R. O., Antioxidants for Improving Storage Stability of Biodiesel, Biofuels, Bioproducts biorefining, 2 (2008), 1, pp. 304-318
  17. Tang, H., et al., The Oxidative Stability of Biodiesel:Effect of FAME Composition and Antioxidant, Lipid Technology, 20 (2008), 1, pp. 249-252
  18. Mittelbach, M., Schober, S., Influence of Antioxidants on Oxidation Stability of Biodiesel, Journal of American Oil Chemists Society, 80 (2003), 1, pp. 817-823
  19. Sarin, A., et al., Natural and Synthetic Antioxidants: Influence on the Oxidative Stability of Biodiesel Synthesized from Non-Edible Oils, Energy, 35 (2010), 1, pp. 867-870
  20. Liang, Y., et al., The Effect of Natural and Synthetic Antioxidants of Palm Biodiesel, Fuel, 85 (2005), 5-6, pp. 867-870

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