THERMAL SCIENCE
International Scientific Journal
CONTRIBUTION STUDY OF THE THERMODYNAMICS PROPERTIES OF THE AMMONIA-WATER MIXTURES
ABSTRACT
The full thermodynamic study of the absorption refrigeration units requires the knowledge of the thermodynamic properties of the used mixture. The present work deals with the mathematical modeling of the thermodynamic properties of ammonia-water mixtures using various models. The presented model covers high vapor-liquid equilibrium pressures up to 110 [bar] and temperatures from 230 to 600 [K]. Furthermore, the calculation of the thermodynamic properties of the ammonia-water mixtures and their pure components was carried out. The obtained results were compared with results given in the literature. This shows a good concordance.
KEYWORDS
PAPER SUBMITTED: 2011-02-06
PAPER REVISED: 2011-06-14
PAPER ACCEPTED: 2011-08-18
THERMAL SCIENCE YEAR
2013, VOLUME
17, ISSUE
Issue 3, PAGES [891 - 902]
- A. Sathyabhama and t. P. Ashok babu, Thermodynamic simulation of ammonia-water absorption refrigeration system, Thermal Science, 12 (2008), 3, pp. 45-53
- PIERRE Rapin, Form of the cold, 13 2nd Edition, DUNOD, 2006
- 10
- Eva Thorin, Power cycles with ammonia-water mixtures as working fluid, Doctoral Thesis, Royal Institute of Technology, Stockholm, Sweden, 2000
- D. Peng, D. Robinson, Two and Three Phase Equilibrium Calculations for Coal Gasification and Related Processes, Thermodynamics of Aqueous Systems with Industrial Applications, ACS Symposium Series, No. 133, American Chemical Society, Washington, DC, 1980
- Skogestad, S., Experience in Norsk-Hydro with Cubic Equations of State, Fluid Phase Equilibria, 13 (1983), pp.179-188
- H. Renon, J.L Guillevic, D Richon, J Boston, H Britt, A cubic equation of state representation of ammonia-water vapor-liquid equilibrium data, International Journal of Refrigeration, 9 (1986), 2, pp. 70-73
- Iseli M., Experimentelle und Thermodynamische Untersuchung des Siedegleichgewichtes des Systems NH3-H2O, bei Hohen Drücken, Dissertation No. 7743,Eidgenössischen Technischen Hochschule, Zürich, 1985
- R. Stryjek and J. H. Vera, An improved peng—Robinson equation of state for pure compounds and mixtures, Can. J. Chem. Eng., 64 (1986), pp.323-333
- Sturnfield Ballard E., Matherne J. L., Modeling of a Complex Polar System with a Modified Soave-Redlich-Kwong Equation, Chemical Engineering Communication, 84 (1989), pp. 81-95
- Huang H., A New Mixing Rule for the Patel-Teja Equation of State. Study of Vapor-Liquid Equilibria, Fluid Phase Equilibria, 58 (1990), 1-2, pp. 93-115
- Smolen T. M., Manley D. B., and Poling B. E., Vapor-liquid equilibrium data for the NH3-H2O system and its description with a modified equation of state, J. Chem. Eng. Data, 36 (1991), pp. 202-208
- Moshfeghian M., Shariat A., Maddox R. N., Prediction of Refrigerant Thermodynamic Properties by Equations of State: Vapor Liquid Equilibrium Behavior of Binary Mixtures, Fluid Phase Equilibria, 80 (1992), pp. 33-44
- Peters R., Keller J. U., Ein Assoziationsmodell zur Berechnung von Phasengleich-gewichtszuständen im Stoffsystem Ammoniak-Wasser, DKVTagungsber., 2 (1993), pp. 183-96
- Zhao E., Sugie H., Lu B. C.-Y., Calculation of Vapor-Liquid Equilibria and Saturated Liquid Volumes for Water-Ammonia Mixtures, Chemical Engineering Communication, 129 (1994), pp. 99-108
- Vidal J., Equations of State-Reworking the Old Forms, Fluid Phase Equilibria, 13(1983), pp. 15-33
- Gillespie P. C., Wilding W. V., Wilson G. M., Vapor-Liquid Equilibrium Measurements on the Ammonia-Water System from 313 K to 589 K, AICHE Symposium Series, 83(1987),254, pp. 97-127
- Thomsen K., Rasmussen P., Thermodynamic Model for the Ammonia-Water System, 13th International Conference on the Properties of Water and Steam, Toronto, Canada, 1999
- Rizvi, S. S. H., Measurement and Correlation of Ammonia-Water Equilibrium Data, Ph. D. Thesis, Dissertation, University of Calgary, 1985
- Tochigi K., Kurihara K., Satou T., Kojimi K., Prediction of Phase Equilibria for the Systems Containing Ammonia Using PRASOG, Journal of Supercritical Fluids, 13 (1998), pp. 61-67
- Enick, R.M., Donahey, G.P., Holsinger, Modeling the high-pressure ammonia-water system with WATAM and the Peng-Robinson Equation of state for Kalina cycle studies, Ind. Eng.
- 11
- Chem. Res., 37 (1998), pp. 1644-1650
- Enick R. M., Mcllvried H. G., Gale T. K., Klara J. M., The Modeling of LEBS Kalina Power Cycles, Proceedings of Joint Power Generation Conference, ASME, 1997, Vol. 2, pp. 55-67
- Duan Z., Møller N., Weare J. H., Equation of State for the NH3-H2O System, Journal of Solution Chemistry, 25 (1996), 1, pp. 43-50
- Harms-Watzenberg F., MesSUNg und Korrelation der Thermodynamischen Eigenschaften von Wasser-Ammoniak-Gemischen, VDI Fortschritt-Berichte, Series 3: Verfahrenstechnik, No. 380, VDI-Verlag, 1995
- Edwards T. J., Newman J., Prausnitz J. M., Thermodynamics of Vapor-Liquid Equilibria for the Ammonia-Water System, Industrial & Engineering Chemistry Fundamentals, 17 (1978), 4, pp. 264-269
- Schulz, S. C. G., Equations of State for the System Ammonia-Water for Use with Computers, Proceedings of the 13th International Congress of Refrigeration, 1973, Vol. 2, pp. 431-436
- Kouremenos D. A., Rogdakis E. D., The Temperature-Entropy (or Enthalpy) and the Enthalpy-Entropy (Mollier) Diagram of the Kalina Cycle, Fundamentals of Thermodynamics and Exergy Analysis, 19(1990), ASME, pp. 13-19
- Ziegler, B., Trepp, C, Equation of state for ammonia-water mixtures, International Journal of Refrigeration, 7 (1984), 2 March, pp. 101-106
- Ibrahim, O.M., Klein, S.A, Thermodynamic properties of ammonia-water mixtures, ASHRAE Trans. Symposia, 21 (1993), 2, pp. 1495-1502
- Xu, F., Yogi Goswami, D, Thermodynamic properties of ammonia-water mixtures for power-cycle applications, Energy, 24 (1999), 6, pp. 525-536
- Stecco S.S. and U. Desideri, Thermodynamic Analysis of the Kalina Cycles: Comparisons, Problems, Perspectives, ASME Paper, American Society of Mechanical Engineers, 89 (1989), GT, pp. 149
- Nag, P.K., Gupta, Exergy analysis of the Kalina cycle, Applied Thermal Engineering, 18 (1997), 6, pp. 427-439
- El-Sayed, Y.M., Tribus, Thermodynamic properties of water-ammonia mixtures theoretical implementation for use in power cycles analysis, ASME Paper AES, American Society of Mechanical Engineers, 1 (1985), pp. 89-95
- Kalina A., Tribus M., El-Sayed Y., A Theoretical Approach to the Thermophysical Properties of Two-Miscible-Component Mixtures For the Purpose of Power-Cycle Analysis, ASME Paper, American Society of Mechanical Engineers, 86 (1986), WA/HT, pp. 54
- Weber, L.A, Estimating the virial coefficients of the ammonia-water mixture, Fluid Phase Equilibria, 162 (1999), 1-2, pp. 31-49
- Y. M. Park, A Generalized Equation of State Approach to the Thermodynamic Properties of Ammonia-Water Mixtures with Applications, Ph. D. Thesis, University of Michigan, UMI, 1988
- Ikegami Y., Nishida T., Uto M., Uehara H., Thermophysical Properties of Ammonia/Water by the BWR Equation of State, The Thirteenth Japan Symposium on Thermophysical Properties, 1992, pp. 213-216
- Friend D. G, Olson A. L, Nowarski A., Standard Thermophysical Properties of the Ammonia-Water Binary Fluid, Proceedings of the 12th International Conference on the Properties of
- 12
- Water and Steam, 1994, Orlando, Florida
- Nowarski A., Friend D. G., Application of the Extended Corresponding State Method to the Calculation of the Ammonia-Water Mixture Thermodynamic Surface, International Journal of Thermophysics, 19 (1998), 4, pp. 1133-1142
- Abovsky V., Thermodynamics of Ammonia-Water Mixture, Fluid Phase Equilibria, 116 (1996), pp. 170-176
- Rainwater J. C., Tillner-Roth R., Critical Region Vapor-Liquid Equilibrium Model of Ammonia-Water, 13th International Conference on the Properties of Water and Steam, 1999, Toronto, Canada
- Tillner-Roth R., Friend D. G., A Helmholtz Free Energy Formulation of the Thermodynamic Properties of the Mixture {Water+Ammonia}, Journal of Physical and Chemical Reference Data, 27 (1998), 1b, pp. 63-69
- Paték J., Klomfar J., Simple Functions for Fast Calculations of Selected Thermodynamic Properties of the Ammonia-Water System, International Journal of Refrigeration, 18 (1995), 4, pp. 228-234
- Jain P. C., Gable G. K., Equilibrium Property Data Equations for Aqua-Ammonia Mixtures, ASHRAE Transactions, 77 (1971), 1, pp.149-151
- Rukes, B., Dooley, R.B, Guideline on the IAPWS formulation 2001 for the thermodynamic properties of ammonia-water mixtures, IAPWS (The International Association for the Properties of Water and Steam), 2001, Maryland,USA
- Jordan, D.P, Aqua-ammonia properties, Department of Mechanical Engineering, 1997, Texas Tech University, Lubbock-Texas, pp. 19
- M. Barhoumi, A. Snoussi, N. Ben Ezzine, K. Mejbri, A. Bellagi, Modelling of the thermodnyamic properties of the ammonia-water mixture, International Journal of Refrigeration, 27 (2004), pp. 271-283
- Kh. Mejbri, A. Bellagi, Modelling of thermodynamic properties of the water-ammonia mixture by three different approaches, International Journal of Refrigeration, 29 (2006), pp. 211-218
- Amer. H. T., Michel. F, Olivier. L, Thermodynamic properties of ammonia-water mixtures, International Congress of Refrigeration, 2003, Washington, ICR , pp. 0113 -2003
- Dae.Wen. SUN, Comparison of the performance of NH3-H2O, NH3-LiNO3 and NH3-SCN absorption refrigeration systems, Energy Conversion, 39 (1998), 5/6, pp. 357-368
- ***, Thermodynamic and physical properties of NH3-H20, (IIR) International Institute of Refrigeration, (1994), pp. 88, France
- KUZMAN. Ražnjevic, Thermodynamic tables and charts, Edition EYROLES,1970
- L. Hear et al., Thermodynamic Properties of Ammonia, Journal of Physical Chemistry, 7 (1978), pp. 635-792