THERMAL SCIENCE
International Scientific Journal
MEASUREMENT OF TRANSPORT PROPERTIES OF THIN FILMS AND COATINGS
ABSTRACT
Free-standing and substrate-mounted thin films have been widely used for microelectronic and optical devices. In particular, CVD diamond, as a new material with ideal combination of properties (electrical isolator,
excellent heat conductor, hardest known material) becomes important both in heat spreading and surface strengthening applications. Thermal barrier coatings are quickly gaining widest application in
heat management applications. In devices and systems design, demand for accurate thermophysical property functions of these materials, especially their thermal conductivity and thermal diffusivity, has been increasing. A variety
of methods have been applied, modified and developed to measure transport properties of thin films and CVD diamond. Paper reviews methods of measuring thermal conductivity and thermal diffusivity of thin films and
CVD diamond and discusses their advantages and disadvantages. Measurements of thermal diffusivity of tantalum, tungsten and nickel thin films at our laboratory applying 4C calorimetric technique are reported.
PAPER SUBMITTED: 1987-12-25
PAPER REVISED: 1998-02-28
PAPER ACCEPTED: 1998-03-09
PUBLISHED ONLINE: 2020-11-07
THERMAL SCIENCE YEAR
1997, VOLUME
1, ISSUE
Issue 2, PAGES [91 - 106]
- Laubitz, M. J., Axial Heat Flow Methods of Measuring Thermal Conductivity, in Compendium of Thermophysical Property Measurement Methods, Vol. 1: Survey of Measurement Techniques (Eds. K. D., Maglić, A. Cezairlyan, V. E. Peletsky), Plenum Press: New York and London, 1984, pp. 11-60
- Worner, E. , Wild, C., Sebert, W. M., Koidl, P., Thermal Conductivity Measurements on CVD Diamond Using Graphitic Microheaters Prepared by Laser Scribing, presented at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Cahill,D. G., Fischer, H. E., Klitsner, T., Swarts, E. T., Pohl, R. O., J. Vac. Sct. Technol. A, Vac. Surf. Films 7 (1989), 3, pp. 1259-1266
- Parker, W. J., Jenkins, R. J., Butler, C. P., Abbott, G. L., Flash Method of Determining Thermal Diffusivity, Heat Capacity and Thermal Conductivity, J. Appl. Phys. 32 (1961), 9, p. 1979
- ***Standard Test Method for Thermal Diffusivity of Solids by the Flash Method, ASTM Standard E 1461-92, (1992)
- Taylor, R. E., Maglić, K. D., Pulse Method for Thermal Diffusivity Measurement, in Compendium of Thermophysical Property Measurement Methods, Vol. 1: Survey of Measurement Techniques, (Eds., K. D. Maglić, A. Cezairlyan, V. E. Peletsky), Plenum Press: New York and London, 1984, pp. 305-336
- Maglić, K. D., Taylor, R. E., The Apparatus for Thermal Diffusivity Measurement by the Laser Pulse Method, in Compendium of Thermophysical Property Measurement Methods, Vol. 2: Recommended Measurement Techniques and Practices, (Eds. K. D. Maglić, A. Cezairlyan, V. E. Peletsky), Plenum Press: New York and London, 1992, pp. 281-314
- Remy, B., Maillet, D., Andre, S., Lascr Flash Diffusivity Measurement of Diamond Films: Some Experimental Specificities, presented at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Donaldson, A. B., Radial Conduction Effects in the Pulse Method of Measuring Thermal Diffusivity, J. Appl. Phys. 43 (1972), pp. 4226-4228
- Chu, F.I., Taylor, R. E., Donaldson, A. B., Thermal Diffusivity Measurements at High Temperatures by the Radial Flash Method, J. Appl. Phys. 51 (1980), pp. 336-341
- Amazouz, M., Moyne C., Degiovanni, A., Measurement of Thermal Diffusivity of Anisotropic Materials, High Temp. High Pressures, 19, (1987), pp. 37-41
- Batsale, J. C., Degiovanni, A., Extension de la méthode "flash" a deux cas particuliers: Les matériaux anisotropes et les liquides, Proc. Recontre Société Francaise des Thermiciens 88, Limoges, CPM-14-1, 1988 |
- Chu,F.1l., Taylor, R. E., Donaldson, A. B., Flash Diffusivity Measurements at High Temperatures by the Axial Heat Flow Method, in: Proc. Seventh Symposium on Thermophysical Properties, ASME 1977 (Ed. A. Cezairlyan), ASME, New York, 1977, pp. 148-154
- Ohta, H., Shibata, H., Waseda, Y., Rev. Sci. Instrum, 60 (1989), 3, pp. 317-321
- Leung, W. P., Tam, A. C., J. Appl. Phys. 56 (1984), 1, pp. 153-161
- Cielo, P., J. Appl. Phys. 56 (1984), 1, pp. 230-234
- Taketoshi, N., Baba,T., A. Ono, Development of a Thermal Diffusivity Measurement Sysytem With a Picosecond Thermoreflectance Technique, High Temp. — High Press., 29 (1997), pp. 59-66
- Jauregui, J., Matthias, E., J. Appl. Phys. A, Solids Surf., 54 (1992), pp. 35-39
- Graebner, J. E., Jin, S., Kammlott, G. W., Herb, J. A., Gardiner, C. F., Nature, (1992), p. 658 |
- Angstrom, A. J., Ann. Phys. Chem. (Pogg. Ann.) 114 (1861), pp. 513-530
- Phylippov, L. P., Temperature Wave Techniques, in Compendium of Thermophysical Property Measurement Methods, Vol. 1: Survey of Measurement Techniques, (Eds., K. D. Maglić, A. Cezairlyan, V. E. Peletsky), Plenum Press: New York and London, 1984, pp. 337-366
- De Coninck, R., Peletsky, V. E., Electron Bombardment Modulated Heat Input Method, in Compendium of Thermophysical Property Measurement Methods, 1: Survey of Measurement Techniques (Eds. K. D. Maglić, A. Cezairlyan, V. E. Peletsky), Plenum Press: New York and London, 1984, pp. 367-429
- Gu, Y. Q., Yu, L. X., Hatta, I., Thermal Diffusivity of Diamond/Si Composite Films Measured by an AC Calorimetric Method. II. Characterization of Deposited Diamond Layers, Int. J. Thermophys, Vol. 18 (1997), 2, pp. 525-534
- Hatta,
- Macsono, A., Tye, R. P., Gardner, R. L., Methods to Measure Relevant Thermal Characteristics of Thin Films of CVD Diamond and Other Highly Conducting Materials, High Temp., High Pressures, Vol. 25 (1993), pp. 329-336
- Hatta, I., Kato, R., Maesono, A., Development of AC Calorimetric Method for Thermal Diffusivity Measurement I. Contribution of Thermocouple Attachment in a Thin Sample, Jpn. J. Appl. Phys., 25 (1986), 6, pp. L493-L495
- Hatta, I., Kato, R., Maesono, A., Development of AC Calorimetric Method for Thermal Diffusivity Measurement I. Sample Dimension Required for the Measurement, Jpn. J. Appl. Phys., 26 (1987), 3, pp. 475-478
- Gu, Y., Hatta, 1., Effect of Edge Sample in AC Calorimetric Method for Measuring Thermal Diffusivity of Thin Films with High Thermal Diffusivity, Jpn. J. Appl. Phys., 30, (1991), 5, pp. 1137-1138
- Gu, Y., Tang, X., Xu, Y., Hatta, I. Ingenious Method for Elliminating Effects of Heat Loss in Measurements of Thermal Diffusivity by AC Calorimetric Method, Jpn. J. Appl. Phys., 32, Pt. 2 (1993), 9B, pp. L1365—L1367 KO
- Hatta, I., Sasuga, Y., Kato, R., Maesono, A., Thermal Diffusivity Measurements of Thin Films by Means of an AC Calorimetric Method, Rev. Sci. Instr., 56 (1985), 8, pp. 1643-1647
- Kato, R., Maesono, A., Hatta, I., Measurement of the Thermal Diffusivity of Films Using Advanced AC Calorimetric Method, Proceedings, Fourth Asian Thermophys. Properties Conference, Tokyo, 1995
- Kato, R., Maesono, A., Hatta, I., Development of AC Calorimetric Method for Thermal Diffusivity Measurement, V. Modulated Laser Beam Irradiation, Jpn. J. Appl. Phys., 32, Pt. 1 (1993), 8, pp. 3656-3658
- Feldman, A., N., Balzaretti, M., A Modification of Angstrom's Method that Employs Photothermal Radiometry to Measure Thermal Diffusivity: Application to CVD Diamond, presented at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Almond, D. P., Patel, P. M., Pickup, I. M., Reiter, H., NDT Int., 18 (1985),1, pp. 17-24
- Frederikse, H. P. R., Ying, X. T., Feldman, A., Proceedings, Materials Research Society Symposium, 142 (1989), pp. 289-294
- Aamodt, L. C., Spicer, J. W. M., Murphy, J. C., J. Appl. Phys. 68 (1990),12, pp. 6087-6098
- Akabori, M., Sawajiri, O., Nagasaka, Y., Thermal Diffusivity of Thin Films on Substrate by the Photoacoustic Method, presented at 13. European Conference of Thermophysical Properties, Lisboa, 1993
- Bertolotti, M., Liakhou, G. L., Voti, R. L., Paoloni, S., Sibilia, C., Yakovlev, V. P., New Compact Setup for Thermal Diffusivity Measurement by Photothermal Deflection Technique, presented at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Cahill, D. G., Lee, S. M., Heat Transport Measurements of Thin Films and Interfaces Using the 3a Method, presented at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Feldman, A., Round Robin Thermal Conductivity Measurements on CVD Diamond, Proceedings, Third Intl. Conf. on Applications of Diamond Films and Related Materials, 1995, pp. 627-630
- Graebner, J., Discussion of Diamond Round-Robin IJ, held at 13. Symposium on Thermophysical Properties, Boulder, 1997
- Stanimirović, A. M., Maglić, K. D., Perović, N. Lj., Vuković, G. S., Measurement of Thermal Diffusivity of Thin Films by AC Calorimetric Method, presented at 14. European Conference of Thermophysical Properties, Lyon, 1996
- Maglić, K. D., Stanimirović, A. M., Thin Film Thermal Diffusivity Measurement (in Scrbian), Proceedings XLI ETRAN, Vol. J, 1997, pp. 171-173
- Touloukian, Y.S., Powell, R. W., Ho, C. Y., Nicolaou, M. C., Thermophysical Properties of Matter, Vol. 10: Thermal Diffusivity, IFI/Plenum, New York, 1973