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ADDITION OF N-OCTANOL TO BIODIESELS OBTAINED FROM DIFFERENT OIL SOURCES AND INVESTIGATION OF THE EFFECTS OF THE OBTAINED BLENDS ON FUEL PROPERTIES

ABSTRACT
Petroleum-based liquid fuels such as gasoline and diesel have dominated the trans-portation sectors in recent centuries. However, the need to reduce the emission of GHG and the dependency on fossil fuels has motivated researchers across the globe to look for alternative and renewable fuels sources. Vegetable oils, alcohols and fats from animal waste are the potential candidates for biofuel since they are renewable and cleaner burning fuels. Biofuel has higher cetane number, which lowers idle noise and endorses easier start. Biodiesel consists of long-chain fatty acid alkyl esters and is obtained from renewable vegetable oils, recycled cooking oils or animal fats. Biodiesel can be used in Diesel engines with minor or no modifications. Fuels derived from various bio-based feedstocks have attracted great attention in recent decades. Oxygen containing biofuels, such as alcohols, have exhibited considerable promise, because they are renewable and considered neutral with regard to net GHG emissions. The n-octanol is a new promising fuel, which is considered as an alternative to conventional diesel. Octanol has raised a significant amount of interest, where recently new pathways have been described to obtain n-octanol from biomass or bio-oil. In this study, the addition of n-octanol to biodiesels obtained from different oil sources and the effects of the resulting mixtures on the fuel properties will be investigated.
KEYWORDS
PAPER SUBMITTED: 2024-12-08
PAPER REVISED: 2025-02-10
PAPER ACCEPTED: 2025-04-29
PUBLISHED ONLINE: 2025-09-26
DOI REFERENCE: https://doi.org/10.2298/TSCI2505707Y
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2025, VOLUME 29, ISSUE Issue 5, PAGES [3707 - 3722]
REFERENCES
  1. Said, Z., et al., 4E (Energy, Exergy, Economic, and Environment) Examination of a Small LFR Solar Water Heater: An Experimental and Numerical Study, Case Stud. Therm. Eng., 27 (2021), 101277
  2. Hassan, F., et al., Recent Advancements in Latent Heat Phase Change Materials and Their Applications for Thermal Energy Storage and Buildings: A State of the Art Review, Sustain. Energy Technol. Assessments, 42 (2022), 101646
  3. Jaiswal, K. K., et al., Renewable and Sustainable Clean Energy Development and Impact on Social, Economic, and Environmental Health, Energy Nexus, 7 (2022), 100118
  4. Cakmak, A., et al., The Experimental Investigation on the Impact of n-Octanol in the Compression-Ignition Engine Operating with Biodiesel/Diesel Fuel Blends: Exergy, Exergoeconomic, Environmental Analyses, J. Therm. Anal. Calorim., 147 (2022), Apr., pp. 11231-11259
  5. Fidan, M. S., Alkan, E., Use As An Alternative Energy Source of Biodiesel Derived From Plant Raw Materials TT, Gumushane Universitesi Fen Bilim Derg, 4 (2015), Jan., pp. 144-160
  6. Alengebawy, A., et al., Conversion of Bioenergy Materials to Secondary Fuels, in Reference Module in Earth Systems and Environmental Sciences, Edition 1, Chapters, 2 and 3, May 2023, pp. 1-14
  7. Bhatia, S. C., in Advanced Renewable Energy Systems, 2014
  8. Gamage, A., et al., Role of Organic Farming for Achieving Sustainability in Agriculture, Farming System, 1 (2023), 1, 100005
  9. Motevali, A., et al., Environmental Impacts of Biodiesel Production Cycle from Farm to Manufactory, An Application of Sustainable Systems Engineering, Atmosphere, 14 (2023), 399
  10. Coronado, C. R., et al., Biodiesel CO2 Emissions: A Comparison with the Main Fuels in the Brazilian Market, Fuel Processing Technology, 90 (2009), 2, pp. 204-211
  11. Nour, M., et al., Adding N-Butanol, N-Heptanol, and N-Octanol to Improve Vaporization, Combustion, and Emission Characteristics of Diesel/Used Frying Oil Biodiesel Blends in DICI Engine, Environ. Prog. Sustainable Energy, 40 (2021), 3, 13549
  12. Ma, Q., et al., The Performance and Emissions Characteristics of Diesel/Biodiesel/Alcohol Blends in a Diesel Engine, Energy Reports, 7 (2021), Nov., pp. 1016-1024
  13. Gulum, M., Bilgin, A., A Comprehensive Study on Measurement and Prediction of Viscosity of Biodiesel-Diesel-Alcohol Ternary Blends, Energy, 148 (2018), Apr., pp. 341-361
  14. Atmanli, A., et al., Experimental Investigation of the Effect of Diesel-Cotton Oil-N-Butanol Ternary Blends on Phase Stability, Engine Performance and Exhaust Emission Parameters in a Diesel Engine, Fuel, 109 (2013), July, pp. 503-511
  15. Gulum, M., et al., Measurement and Estimation of Densities of Different Biodiesel - Diesel - Alcohol Ternary Blends, Environ. Prog. Sustain. Energy, 38 (2019), 6, pp. 1-20
  16. Yilmaz, N., Atmanli, A., Experimental Evaluation of a Diesel Engine Running on the Blends of Diesel and Pentanol as a Next Generation Higher Alcohol, Fuel, 210 (2017), Dec., pp. 75-78
  17. Yesilyurt, M. K., A Detailed Investigation on the Performance, Combustion, and Exhaust Emission Characteristics of a Diesel Engine Running on the Blend of Diesel Fuel, Biodiesel and 1-Heptanol (C7 Alcohol) as a Next-Generation Higher Alcohol, Fuel, 275 (2020), 117893
  18. Goktas, M., et al., An Evaluation of the Use of Alcohol Fuels in SI Engines in Terms of Performance, Emission and Combustion Characteristics: A Review, Fuel, 286 (2021), Part 2, 119425
  19. Celebi, Y. Aydin, H., An Overview on the Light Alcohol Fuels in Diesel Engines, Fuel, 236 (2019), Jan., pp. 890-911
  20. Zhang, F., et al., Metabolic Engineering of Microbial Pathways for Advanced Biofuels Production, Current Opinion in Biotechnology, 22 (2011), 6, pp. 775-783
  21. Ewing, T. A., et al., Fermentation for the Production of Biobased Chemicals in a Circular Economy: A Perspective for the Period 2022-2050, Green Chem, 24 (2022), July, pp. 6373-6405
  22. Kumar, B. R., et al., Effect of a Sustainable Biofuel - N-Octanol on the Combustion, Performance and Emissions of a DI Diesel Engine under Naturally Aspirated and Exhaust Gas Recirculation (EGR) Modes, Energy Conversion and Management, 118 (2016), June, pp. 275-286
  23. Rakopoulos, C. D., et al., Investigating the Emissions During Acceleration of a Turbocharged Diesel Engine Operating with Bio-Diesel or N-Butanol Diesel Fuel Blends, Energy, 35 (2010), 12, pp. 5173-5184
  24. Rakopoulos, D. C., et al., Effects of Butanol-Diesel Fuel Blends on the Performance and Emissions of a High-Speed DI Diesel Engine, Energy Convers. Manage., 5 (2010), 10, pp. 1989-1997
  25. Yao, M., et al., Experimental Study of N-Butanol Additive and Multi-Injection on HD Diesel Engine Performance and Emissions, Fuel, 89 (2010), 9, pp. 2191-2201
  26. Merola, S. S., et al., Combustion Process Investigation in a High Speed Diesel Engine Fuelled with N-Butanol Diesel Blend by Conventional Methods and Optical Diagnostics, Renew Energy, 64 (2014), Apr., pp. 225-237
  27. Zhang, Z. H., Balasubramanian, R., Influence of Butanol-Diesel Blends on Particulate Emissions of a Non-Road Diesel Engine, Fuel, 118 (2014), Feb., pp. 130-136
  28. Sahin, Z., Aksu, O. N., Experimental Investigation of the Effects of Using Low Ratio N-Butanol/Diesel Fuel Blends on Engine Performance and Exhaust Emissions in a Turbocharged DI Diesel Engine, Renew Energy, 77 (2015), May, pp. 279-290
  29. Al-Hasan, M. I., Al-Momany, M., The Effect of Iso-Butanol-Diesel Blends on Engine Performance, Transport, 23 (2008), 4, pp. 306-310
  30. Karabektas, M., Hosoz, M., Performance and Emission Characteristics of a Diesel Engine Using Iso-Butanol-Diesel Fuel Blends, Renew. Energy, 34 (2009), 6, pp. 1554-1559
  31. Ozsezen, A., et al., Comparison of Performance and Combustion Parameters in a Heavy-Duty Diesel Engine Fueled with Iso-Butanol/Diesel Fuel Blends, Energy Explor. Exploit., 29 (2011), 5, pp. 525-541
  32. Kumar, B. R., Saravanan, S., Effect of Iso-Butanol Addition to Diesel Fuel on Performance and Emissions of a DI Diesel Engine with Exhaust Gas Recirculation, Proc. Inst. Mech. Eng., Part A: J Power Energy, 230 (2015), 1, pp. 112-125
  33. Li, L., et al., Combustion and Emissions of Compression Ignition in a Direct Injection Diesel Engine Fueled with Pentanol, Energy, 80 (2015), Feb., pp. 575-581
  34. Campos, J. F., et al., Performance Tests of a Diesel Engine Fueled with Pentanol/Diesel Fuel Blends, Fuel, 107 (2013), May, pp. 866-872
  35. Wei, L., et al., Effect of N-Pentanol Addition on the Combustion, Performance and Emission Characteristics of a Direct-Injection Diesel Engine, Energy, 70 (2014), June, pp. 172-180
  36. Rajesh, B. K., Saravanan, S., Effect of Exhaust Gas Recirculation (EGR) on Performance and Emissions of a Constant Speed DI Diesel Engine Fueled with Pentanol/Diesel Blends, Fuel, 160 (2015), Nov., pp. 217-226
  37. Rajesh, B.K., Saravanan, S., Effects of Iso-Butanol/Diesel and N-Pentanol/Diesel Blends on Performance and Emissions of a DI Diesel Engine under Premixed LTC (Low Temperature Combustion) Mode, Fuel, 170 (2016), Apr., pp. 49-59
  38. Sundar, R., Saravanan, G., Influence of Hexanol-Diesel Blends on Constant Speed Diesel Engine, Thermal Science, 15 (2011), 4, pp. 215-222
  39. Daheriya, L. K., Shrivastava, N., Effect of Performance and Emissions on DI Diesel Engine Using Ethanol Diesel Blends - A Review, International Journal of Engineering Research & Technology, 1 (2012), 6
  40. Liu, H., et al., Effects of Different Alcohols Additives on Solubility of Hydrous Ethanol/Diesel Fuel Blends, Fuel, 184 (2016), Nov., pp. 440-448
  41. Li, J., et al., Blending N-Octanol with Biodiesel for more Efficient and Cleaner Combustion in Diesel Engines: A Modeling Study, Journal of Cleaner Production, 403 (2023), 136877
  42. Garcia, A., et al., Potential of 1-Octanol and Di-N-Butyl Ether (DNBE) to Improve the Performance and Reduce the Emissions of a Direct Injected Compression Ignition Diesel Engine, Energy Conversion and Management, 177 (2018), Dec., pp. 563-571
  43. Kerschgens, B., et al., Di-N-Buthylether, Noctanol, and N-Octane as Fuel Candidates for Diesel Engine Combustion, Combust. Flame, 163 (2016), Jan., pp. 66-78
  44. Preus, J., et al., Performance and Emissions of Long-Chain Alcohols as Drop-in Fuels for Heavy Duty Compression Ignition Engines, Fuel, 216 (2018), 15, pp. 890-897
  45. Ashok, B., et al., Effects of N-Octanol as a Fuel Blend with Biodiesel on Diesel Engine Characteristics, Fuel, 235 (2019), Jan., pp. 363-373
  46. Kumar, B. R., et al., Effect of a Sustainable Biofuel - N-Octanol - on the Combustion, Performance and Emissions of a DI Diesel Engine under Naturally Aspirated and Exhaust Gas Recirculation (EGR) Modes. Energy Convers. Manag., 118 (2016), June, pp. 275-286
  47. Li, J., et al., Evaluating Performance and Emissions of a CI Engine Fueled with N-Octanol/Diesel and N-Butanol/Diesel Blends under Different Injection Strategies, Fuel, 284 (2021), 119085
  48. Kaliyaperumal, G., et al., Prediction of Emissions and Performance of a Diesel Engine Fueled with N-Octanol/Diesel Blends Using Response Surface Methodology, J. Clean. Prod., 184 (2018), May, pp. 423-439
  49. Devarajan, Y., et al., Performance, Combustion and Emission Analysis of Mustard Oil Biodiesel and Octanol Blends in Diesel Engine, Heat Mass Tran., 54 (2018), Jan., pp. 1803-1811
  50. Mahalingam, A., et al., Emissions Analysis on Mahua Oil Biodiesel and Higher Alcohol Blends in Diesel Engine, Alex. Eng. J., 57 (2018), 4, pp. 2627-2631
  51. Sidharth, K. N., Performance and Emission Studies of Ternary Fuel Blends of Diesel, Biodiesel and Octanol, Energy Sources, Part A Recovery, Util. Environ. Eff., 42 (2020), 18, pp. 2277-2296
  52. Atabani, A. E., Al Kulthoom, S., Spectral, Thermoanalytical Characterizations, Properties, Engine and Emission Performance of Complementary Biodiesel-Diesel-Pentanol/Octanol Blends, Fuel, 282 (2020), 118849
  53. Fernandez, J. C., et al., A Comparison of Performance of Higher Alcohols/Diesel Fuel Blends in a Diesel Engine, Appl. Energy, 95 (2012), July, pp. 267-275
  54. Akhtar, M. K., et al., Microbial Production of 1-Octanol: A Naturally Excreted Biofuel with Diesel-Like Properties, Metab. Eng. Commun., 2 (2015), Dec., pp. 1-5
  55. Kremer, F., et al., A Comparison of the Microbial Production and Combustion Characteristics of Three Alcohol Biofuels: Ethanol, 1-Butanol, and 1-Octanol, Front Bioeng. Biotechnol., 3 (2015), 7
  56. Nguyen, D. T., et al., Impacts of Charge Air Parameters on Combustion and Emission Characteristics of a Diesel Marine Engine, Thermo, 3 (2023), 3, pp. 494-514
  57. Pratas, M. J., et al., Biodiesel Density: Experimental Measurements and Prediction Models, Energy Fuels, 25 (2011), 5, pp. 2333-2340
  58. Alptekin, E., Canakci, M., Determination of the Density and the Viscosities of Biodiesel-Diesel Fuel Blends, Renewable Energy, 33 (2008), 12, pp. 2623-2630
  59. Tat, M. E., Gerpen, J. V., The Specific Gravity of Biodiesel and Its Blends with Diesel Fuels, JAOCS, 77 (2000), 2, pp. 115-119
  60. Bahadur, N. P., et al., Liquid Hydrocarbons from Catalytic Pyrolysis of Sewage Sludge Lipid and Canola Oil: Evaluation of Fuel Properties, Energy Fuels, 9 (1995), 2, pp. 248-256
  61. De Poures, M. V., et al., Using Renewable N-Octanol in a Non-Road Diesel Engine with Some Modifications, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 41 (2019), 10, pp. 1194-1208
  62. Karakus, N., The Effect of Fuel Properties on Diesel Engine Performance and Emissions, Ph. D. thesis, Gazi Univeristesi Institute of Science and Technology, Ankara 2000
  63. Icingur, Y., Eray, M. E., Experimental Investigation of the Usability of Different Fuel Blends in Diesel Engines, Gazi University Journal of Science and Technology, 16 (2003), 3, pp. 589-599
  64. Guru, M., et al., Investigation of Viscosity of Heavy Fuel Oil with Manganese Additive and Temperature, J. Fac. Eng. Arch. Gazi Univ., 26 (2011), 3, pp. 631-634
  65. Das, S., Chowdhury, A., An Exploration of Biodiesel for Application in Aviation and Automobile Sector, Energy Nexus, 10 (2023), 100204
  66. De Carvalhoa, M. J. S., et al., Lubricant Viscosity and Viscosity Improver Additive Effects on Diesel Fuel Economy, Tribology International, 43 (2010), 12, pp. 2298-2302
  67. Aminian, A., Nezhad, B. Z., Accurate Predicting the Viscosity of Biodiesels and Blends Using Soft Computing Models, Renewable Energy, 120 (2018), May, pp. 488-500
  68. Li, Z., et al., Effect of Liquid Viscosity on Atomization in an Internal-Mixing Twin-Fluid Atomizer, Fuel, 103 (2013), Jan., pp. 486-494
  69. Shu, Q., et al., Predicting the Viscosity of Biodiesel Fuels Based on the Mixture Topological Index Method, Fuel, 86 (2007), 12-13, pp. 1849-1854
  70. Knothe, G., Steidley, K. R., Kinematic Viscosity of Biodiesel Fuel Components and Related Compounds, Influence of Compound Structure and Comparison to Petrodiesel Fuel Components, Fuel, 84 (2005), 9, pp. 1059-1065
  71. Ghurri, A., Kim, J. D., et al., The Effect of Injection Pressure and Fuel Viscosity on the Spray Characteristics of Biodiesel Blends Injected into an Atmospheric Chamber, Journal of Mechanical Science and Technology, 26 (2012), 9, pp. 2941-2947
  72. Boateng, E. K., et al., Assessment of Diesel Fuel Quality, Heliyon, 10 (2024), e24733
  73. Liu, Y. J., et al., Efficiency Model of Pumping Low Viscosity Fluids, IOP Conf. Series: Materials Science and Engineering, 52 (2013), 072002
  74. Sergek, B., Ozcelik, A. E., Investigation of Tribological Analysis of Safflower Oil and 15W40 Engine Lubrication Oil and Their Blends, International Journal of Energy Applications and Technologies, 10 (2023), 2, pp. 92-102
  75. Ghurri, A., et al., The Effect of Injection Pressure and Fuel Viscosity on the Spray Characteristics of Biodiesel Blends Injected into an Atmospheric Chamber, Journal of Mechanical Science and Technology, 26 (2012), 9, pp. 2941-2947
  76. Bravo, L., et al., Effects of Fuel Viscosity on the Primary Breakup Dynamics of a High-Speed Liquid Jet with Comparison to X-Ray Radiography, Proceedings of the Combustion Institute, 37 (2019), 3, pp. 3245-3253
  77. Zhang, Y., et al., A Comprehensive Review on Combustion, Performance and Emission Aspects of Higher Alcohols and Its Additive Effect on the Diesel Engine, Fuel, 335 (2023), 127011
  78. Hossain, A. K., Davies, P. A., Plant Oils as Fuels for Compression Ignition Engines: A Technical Review and Life-Cycle Analysis, Renewable Energy, 35 (2010), 1, pp. 1-13
  79. Lois, E., Gupta, A. K., Fuels, III.G.7 Flash Point, Encyclopedia of Physical Science and Technology, Book, Reference Work, Third Edition, 2003
  80. Garcia, J. I., et al., Experimental Organic Chemistry, Book, 2015
  81. Stauffer, E., Newman, R., Fire Debris Analysis, in: Chemistry and Physics of Fire and Liquid Fuels, Elsevier, Amsterdam, The Netherlands, 2008
  82. Yesilyurt, M. K., et al., The Production of Biodiesel from Safflower (Carthamus tinctorius L.) Oil as a Potential Feedstock and Its Usage in Compression Ignition Engine: A Comprehensive Review, Renewable and Sustainable Energy Reviews, 119 (2020), 109574
  83. Knothe, G., Steidley, K. R., Kinematic Viscosity of Biodiesel Components (Fatty Acid Alkyl Esters) and Related Compounds at Low Temperatures, Fuel, 86 (2007), 16, pp. 2560-2567
  84. Boz, N., et al., Investigation of the Fuel Properties of Biodiesel Produced over an Alumina-Based Solid Catalyst, Turkish Journal of Chemistry, 33 (2009), 3, pp. 433-442
  85. Ilcin, K., et al., Effect of Blending Ratio and Injection Timing on Combustion and Emissions of a Common-Rail Diesel Engine Fueled by Iso-Propanol-Butanolethanol (IBE) and Conventional Diesel, Journal of Polytechnic, 26 (2023), 4, pp. 1327-1339
  86. Liu, J., et al., Experimental Investigation on Combustion Characteristics and Influencing Factors of PODE/Methanol Dual-Fuel Engine, Energy, 260 (2022), 1, pp. 125-131
  87. Wang, X., et al., Analysis of Diesel Knock for High-Altitude Heavy-Duty Engines Using Optical Rapid Compression Machines, Energies, 13 (2020), 3080
  88. Simsek, S., Uslu, S., Analysis of the Effects of Cetane Improver Addition to Diesel on Engine Performance and Emissions, International Journal of Automotive Engineering and Technologies, 10 (2021), 1, pp. 26-32
  89. Besergil, B., Fuels Oils, Gazi Bookstore Editions, Ankara, 2014
  90. Aleme, H. G., Barbeira, P. J. S., Determination of Flash Point and CI in Diesel Using Distillation Curves and Multivariate Calibration, Fuel, 102 (2012), Dec., pp. 129-134
  91. Luning Prak, D., et al., Cetane Number, Derived Cetane Number, and CI: When Correlations Fail to Predict Combustibility, Fuel, 289 (2021), 119963
  92. ***, ASTM D4737-10(2016), Standard Test Method for Calculated Cetane Index by Four Variable Equation. West Conshohocken: ASTM International; 2016
  93. ***, ASTM D976-06(2016), Standard Test Method for Calculated Cetane Index of Distillate Fuels, West Conshohocken, PA: ASTM International; 2016
  94. ***: United States Department of Defense, Naval Distillate, Military Specification MIL-PRF-16884N. 431 Washington, DC; April 2014

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