ABSTRACT
This study presents a comprehensive numerical investigation comparing the combustion characteristics and emission behavior of conventional diesel and biodiesel fuel (methyl oleate, C₁₉H₃₈O₂) in a single-cylinder Antor 6LD400 Diesel engine using CONVERGE CFD software. The simulations were carried out under identical operating conditions to evaluate temperature and pressure evolution, heat release profiles, and pollutant formation, including CO, CO₂, NOₓ, soot, and unburned hydrocarbons. Results indicate that biodiesel ignites earlier due to its higher cetane number and oxygenated structure, leading to faster combustion, lower peak in-cylinder pressure and temperature, and reduced emissions of CO, hydrocarbon, and soot. Although biodiesel emits slightly more CO₂, indicative of more complete combustion, it consistently demonstrates lower NOₓ levels due to shorter residence time at high temperatures. These findings confirm that biodiesel offers cleaner combustion with significant emission benefits, making it a promising alternative fuel for reducing the environmental impact of compression ignition engines.
KEYWORDS
PAPER SUBMITTED: 2025-03-02
PAPER REVISED: 2025-04-10
PAPER ACCEPTED: 2025-06-19
PUBLISHED ONLINE: 2025-09-26
THERMAL SCIENCE YEAR
2025, VOLUME
29, ISSUE
Issue 4, PAGES [3123 - 3130]
- Yilmaz, N., Vigil, F. M., Potential Use of a Blend of Diesel, Biodiesel, Alcohols and Vegetable Oil in Compression Ignition Engines, Fuel, 124 (2014), May, pp. 168-172
- Hoekman, S. K., et al., Review of Biodiesel Composition, Properties, and Specifications, Renewable and Sustainable Energy Reviews, 16 (2012), 1, pp. 143-169
- Equbal, M. N., et al., Advances in Hydrogen-Enriched Biogas/Biodiesel Combustion for Near-Zero Emissions in Direct Injection Engines, International Journal of Thermofluids, 27 (2025), 101269
- Yadav, M., et al., Enhancing Combustion and Emission Characteristics of CI Engines through Atomization and Fuel-Air Mixing Using Non-Circular Orifices: A Path Towards Sustainable Biodiesel Utilization, Green Technologies and Sustainability, 3 (2024), 3, 100161
- Kumar, V., Choudhary, A. K., A Comparative Review on Evaluation of Performance, Combustion, and Emission Characteristics of Biodiesel Blends Enriched with Hydrogen, Additives and Their Combined Effect, Thermal Science and Engineering Progress, 46 (2023), 102185
- Celebi, Y., et al., Biofuel Usage in Diesel Engines Powered By Butanol and Its Blends: A review, Fuel, 387 (2025), 134316
- Al-Hwaiti, M., et al., Effect of Catalysts On Performance and Emission in a Combustion Diesel Engine Using Biodiesel Derived from Non-Edible Plant "Handal": Case study in Jordan, Energy, 321 (2025), 135432
- Hariram, V., et al., Enhanced Combustion and Emission Characteristics of Diesel-Algae Biodiesel-Hydrogen Blends in a Single-Cylinder Diesel Engine, Results in Engineering, 26 (2025), 104676
- Akintunde, S. B., et al., Numerical and Experimental Studies on Combustion of Hura Crepitans Biodiesel-Diesel Blends in a Compression Ignition (CI) Engine, Thermal Advances, 2 (2025), 100012
- Lakshmikanth, G., et al., Performance, Combustion, and Emission Evaluation of Cassia Fistula Biodiesel Blends with Hydrogen Induction in a Low Heat Rejection Diesel Engine, International Journal of Hydrogen Energy, 143 (2025), July, pp. 468-478
- Vellaiyan, S., Optimization of Hydrogen-Enriched Biodiesel-Diesel Dual-Fuel Combustion with EGR for Sustainable Engine Performance, International Journal of Hydrogen Energy, 128 (2025), May, pp. 85-94
- Mofijur, et al., Impact of Nanoparticle-Based Fuel Additives on Biodiesel Combustion: An Analysis of Fuel Properties, Engine Performance, Emissions, and Combustion Characteristics - A Review, Energy Conversion and Management, X (2024), 21, 100515
- Srinivasan, D. R., et al., A Hybrid Approach to Optimize Engine Performance and Emission Control in Internal Combustion Engines Using Graphene Quantum Dots-Enhanced Biodiesel-Diesel Blends, Applied Thermal Engineering, 276 (2025), 126841
- Hamzah, A. H., et al., Effect of Nanoparticles and Biodiesel Blended with Diesel on Combustion Parameters in Compression Ignition Engine: Numerical Analysis, Energy Engineering, 122 (2025), 5, pp. 2059-2075
- Kumar, K., et al., Effect of TiO2 Nanoparticles and Hydrogen on the Combustion, Performance, and Emissions of Madhuca Biodiesel in a Diesel Engine, International Journal of Hydrogen Energy, 143 (2025), July, pp. 635-649
- Dhamodaran, G., Elumalai, A., Effect of ternary Nanocomposite in Margosa Biodiesel Microemulsion Blends on Performance, Emission, and Combustion Characteristics of a Diesel Engine, Energy, 326 (2025), 136362
- Kul, V. S., et al., Investigation of the Effect of Utilisation of Nanoboron, Diesel and Biodiesel Fuels with Together Hydrogen in a Compression Ignition Engine on Combustion Characteristics, International Journal of Thermofluids, 27 (2025), 101232
- Manesh, M. M., et al., Comparative Analysis of Water Injection and EGR Effects on Combustion, Performance, and Emission Characteristics of a Diesel Engine Using Diesel-Biodiesel Blends, Cleaner Engineering and Technology, 26 (2025), 100965
- Soyler, H., Boost Pressure Influence on Combustion, Emission Characteristics, and Performance of Diesel Engines with Various Fuel Types, Engineering Science and Technology, an International Journal, 63 (2025), 101983
- Bayramoglu, K., Nuran, M., Analyzing the Effect of Fuel Injection Timing and Injection Duration on Performance and Emissions in Diesel Engines, Journal of ETA Maritime Science, 8 (2020), 1, pp. 38-52
- Abdou, B. N., et al., Engine Roughness, Block Vibration and External Noise of Diesel Engine Running on Jojoba Biodiesel and Diesel Blends, International Journal of Thermofluids, 27 (2025), 101236
- Bousbaa, H., et al., Prediction and Simulation of Biodiesel Combustion in Diesel Engines: Evaluating Physicochemical Properties, Performance, and Emissions, Fire, 7 (2024), 10, 364
- Hasnain, S. M., et al., Investigation and Impact Assessment of Soybean Biodiesel, Methyl Oleate, and Diesel Blends on CRDI Performance and Emissions, Materials Science for Energy Technologies, 7 (2024), 1 pp. 124-132
- Bousbaa, H., et al., Investigations on a Compression Ignition Engine Using Animal Fats and Vegetable Oil As Fuels, Journal of Energy Resources Technology, 134 (2012), 022202-1
- Han, Z., Reitz, R. D., Turbulence Modelling of Internal Combustion Engines Using RNG k-ε Models, Combustion Science and Technology, 106 (1995), 4-6, pp. 267-295
- Ramos, J. I., Internal Combustion Engine Modelling, American Publication Corporation, Hemisphere, Scottsdale, Ariz., USA, 1989
- Kong, S. C., et al., The Development and Application of a Diesel Ignition and Combustion Model for Multidimensional Engine Simulation, J. of Engines, 104 (1995), 3, pp. 502-518
- Hamosfakidis, V., Reitz, R. D., Optimization of a Hydrocarbon Fuel Ignition Model for Two Single Component Surrogates of Diesel Fuel, Combustion and Flame, 132 (2003), 3, pp. 433-450
- Hiroyasu, H., Kadota, T., Models for Combustion and Formation of Nitric Oxide and Soot in Direct Injection Diesel Engines, SAE Transactions, (1976), pp. 513-526