THERMAL SCIENCE

International Scientific Journal

SYNERGETIC EFFECTS DURING CO-PYROLYSIS OF WOODY BIOMASS AND ZHUNDONG COAL

ABSTRACT
Co-pyrolysis of biomass and coal is a promising way to produce liquid and char products while contributing to reduce CO2 emission. The co-pyrolysis behaviors and characteristics of poplar sawdust (PS) with Zhundong coal (ZD) in the different blending ratios were investigated using a thermogravimetry analyzer in this work. The results indicated that compared with ZD, PS had a lower characteristic temperature of volatile matter release and a stronger pyrolysis reactivity. There were synergistic promoting and inhibiting effects in the whole co-pyrolysis process of PS and ZD, which were related to the blending ratio. The PS addition percentage of 20%, 40%, and 80% into ZD presented the obvious positive synergistic interactions in the co-pyrolysis process, enhancing the thermal decomposition rate of volatile compounds. The important kinetic parameters were obtained using the first-order reaction model. Adding PS into ZD in the pyrolysis process changed the porous structure and surface morphology of ZD char particles. The results obtained are expected to be helpful in the equipment design and practical application of biomass and ZD co-pyrolysis.
KEYWORDS
PAPER SUBMITTED: 2024-03-24
PAPER REVISED: 2024-08-08
PAPER ACCEPTED: 2024-08-15
PUBLISHED ONLINE: 2024-10-12
DOI REFERENCE: https://doi.org/10.2298/TSCI240324211D
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2025, VOLUME 29, ISSUE Issue 2, PAGES [931 - 941]
REFERENCES
  1. Tokimatsu, K., et al., Global Zero Emissions Scenarios: The Role of Biomass Energy with Carbon Capture and Storage By Forested Land Use, Applied Energy, 185 (2017), Part 2, pp. 1899-1906
  2. Li, S., et al., Study on Co-Pyrolysis Characteristics of Rice Straw and Shenfu Bituminous Coal Blends in a Fixed Bed Reactor, Bioresource Technology, 155 (2014), Mar., pp. 252-257
  3. Lu, Y., et al., The Characteristics of Mineralogy, Morphology and Sintering during co-Combustion of Zhundong Coal and Oil Shale, RSC Advances, 7 (2017), 81, pp. 51036-51045
  4. Zhang, Z., et al., Recent Advances in Carbon Dioxide Utilization, Renewable and Sustainable Energy Reviews, 125 (2020), 109799
  5. Castells, B., et al., Kinetic Study of Different Biomass Pyrolysis and Oxygen-Enriched Combustion, Thermal Science, 26 (2022), 5B, pp. 4131-4145
  6. Gouws, S. M., et al., Co-Pyrolysis of Coal and Raw/Torrefied Biomass: A Review on Chemistry, Kinetics and Implementation, Renewable and Sustainable Energy Reviews, 135 (2021), 110189
  7. Gohar, H., et al., Investigating the Characterisation, Kinetic Mechanism, and Thermodynamic Behaviour of Coal-Biomass Blends in co-Pyrolysis Process, Process Safety and Environmental Protection, 163 (2022), July, pp. 645-658
  8. Shafizadeh, A., et al., Machine Learning-Enabled Analysis of Product Distribution and Composition in Biomass-Coal co-Pyrolysis, Fuel, 355 (2024), 129464
  9. Wang, W., et al., Thermogravimetric Analysis and Kinetic Modelling of the co-Pyrolysis of a Bituminous Coal and Poplar Wood, Chinese Journal of Chemical Engineering, 58 (2023), June, pp. 53-68
  10. Wu, Z., et al., Co-Pyrolysis of Lignocellulosic Biomass with Low-Quality Coal: Optimal Design and Synergistic Effect from Gaseous Products Distribution, Fuel, 236 (2019), Jan., pp. 43-54
  11. Ruan, R., et al., Evolution of Particulate Matter in the Post-Combustion Zone of Zhundong Lignite, Fuel, 281 (2020), 118780
  12. Zhang, J., et al., The TG-FTIR and Py-GC/MS Analyses of Pyrolysis Behaviors and Products of Cattle Manure in CO2 and N2 Atmospheres: Kinetic, Thermodynamic, and Machine-Learning Models, Energy Conversion and Management, 195 (2019), Sept., pp. 346-359
  13. Park, D., et al., Co-Pyrolysis Characteristics of Sawdust and Coal Blend in TGA and a Fixed Bed Reactor, Bioresource Technology, 101 (2010), 15, pp. 6151-6156
  14. Stefanidis, S. D., et al., A Study of Lignocellulosic Biomass Pyrolysis Via the Pyrolysis of Cellulose, Hemicellulose and Lignin, Journal of Analytical and Applied Pyrolysis, 105 (2014), Jan., pp. 143-150
  15. Yang, H., et al., Characteristics of Hemicellulose, Cellulose and Lignin Pyrolysis, Fuel, 86 (2007), 12-13, pp. 1781-1788
  16. Chen, D., et al., Insight Into Biomass Pyrolysis Mechanism Based on Cellulose, Hemicellulose, and Lignin: Evolution of Volatiles and Kinetics, Elucidation of Reaction Pathways, and Characterization of Gas, Biochar and Biooil, Combustion and Flame, 242 (2022), 112142
  17. Di Nola, G., et al., The TG-FTIR Characterization of Coal and Biomass Single Fuels and Blends under Slow Heating Rate Conditions: Partitioning of the Fuel-Bound Nitrogen, Fuel Processing Technology, 91 (2010), 1, pp. 103-115
  18. Wu, Z., et al., Synergistic Effect on Thermal Behavior during co-Pyrolysis of Lignocellulosic Biomass Model Components Blend with Bituminous Coal, Bioresource Technology, 169 (2014), Oct., pp. 220-228
  19. Lv, G., et al., Analytical Pyrolysis Studies of Corn Stalk and Its Three Main Components by TG-MS and Py-GC/MS, Journal of Analytical and Applied Pyrolysis, 97 (2012), Sept., pp. 11-18
  20. Darmstadt, H., et al., Co-Pyrolysis under Vacuum of Sugar Cane Bagasse and Petroleum Residue Properties of the Char and Activated Char Products, Carbon, 39 (2001), 6, pp. 815-825
  21. Lin, B., et al., Thermal Behavior and Gas Evolution Characteristics during co-Pyrolysis of Lignocellulosic Biomass And Coal: A TG-FTIR Investigation, Journal of Analytical and Applied Pyrolysis, 144 (2019), 104718
  22. Shi, L., et al., Pyrolysis Behavior and Bonding Information of Coal - A TGA Study, Fuel Processing Technology, 108 (2013), Apr., pp. 125-132
  23. Seo, D. K., et al., Study of Coal Pyrolysis By Thermo-Gravimetric Analysis (TGA) and Concentration Measurements of the Evolved Species, Journal of Analytical and Applied Pyrolysis, 92 (2011), 1, pp. 209-216
  24. Song, H., et al., Pyrolysis Characteristics and Kinetics of Low Rank Coals by TG-FTIR Method, Fuel Processing Technology, 156 (2017), Feb., pp. 454-460
  25. Chen, X., et al., Pyrolysis Characteristics and Kinetics of Coal-Biomass Blends during co-Pyrolysis, Energy and Fuels, 33 (2019), 2, pp. 1267-1278
  26. Sonobe, T., et al., Synergies in co-Pyrolysis of Thai Lignite and Corncob, Fuel Processing Technology, 89 (2008), 12, pp. 1371-1378
  27. Moghtaderi, B., et al., Pyrolytic Characteristics of Blended Coal and Woody Biomass, Fuel, 83 (2004), 6, pp. 745-750
  28. Zhang, Y., et al., Capture of Released Alkali Metals and Its Simultaneously Catalytic Performance on Secondary Reactions of Volatiles during Biomass Pyrolysis, Fuel, 317 (2022), 123557
  29. Soncini, R. M., et al., Co-Pyrolysis of Low Rank Coals and Biomass: Product Distributions, Fuel, 112 (2013), Oct., pp. 74-82
  30. Yuan, S., et al., Rapid co-Pyrolysis of Rice Straw and A Bituminous Coal in a High-Frequency Furnace and Gasification of the Residual Char, Bioresource Technology, 109 (2012), Apr., pp. 188-197
  31. Song, Y., et al., Pathway of Biomass-Potassium Migration in co-Gasification of Coal and Biomass, Fuel, 239 (2019), Mar., pp. 365-372
  32. Hosokai, S., et al., Spontaneous Generation of Tar Decomposition Promoter in a Biomass Steam Reformer, Chemical Engineering Research and Design, 83 (2005), 9, pp. 1093-1102
  33. Apaydin-Varol, E., et al., Pyrolysis Kinetics And Thermal Decomposition Behavior of Polycarbonate-a TGA-FTIR Study, Thermal Science, 18 (2014), 3, pp. 833-842
  34. Li, J., et al., Biochar-Assisted Catalytic Pyrolysis of Oily Sludge to Attain Harmless Disposal and Residue Utilization for Soil Reclamation, Environmental Science and Technology, 57 (2023), 13, pp. 7063-7073
  35. Li, Z., et al., Kinetic Study of Corn Straw Pyrolysis: Comparison of Two Different Three-Pseudocomponent Models, Bioresource Technology, 99 (2008), 16, pp. 7616-7622
  36. Ma, Z., et al., Determination of Pyrolysis Characteristics and Kinetics of Palm Kernel Shell Using TGA-FTIR and Model-Free Integral Methods, Energy Conversion and Management, 89 (2015), Jan., pp. 251-259
  37. Guo, F., et al., Characterization of Zhundong Lignite and Biomass co-Pyrolysis in a Thermogravimetric Analyzer and a Fixed Bed Reactor, Energy, 141 (2017), Dec., pp. 2154-2163
  38. Fu, P., et al., Evolution of Char Structural Features during Fast Pyrolysis of Corn Straw with Solid Heat Carriers in a Novel V-Shaped Down Tube Reactor, Energy Conversion and Management, 149 (2017), Oct., pp. 570-578

2025 Society of Thermal Engineers of Serbia. Published by the VinĨa Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence