THERMAL SCIENCE
International Scientific Journal
STRUCTURAL AND MAGNETIC PROPERTIES OF NANOPARTICLE SEMICONDUCTORS LA1-XSRXMNO3
ABSTRACT
With a view to investigate the magneto-structural properties and influence of annealing on magnetoresistance of strontium-doped lanthanum manganite, samples of La1-xSrxMnO3 were prepared and their magneto-transport properties have been investigated in this article. Magnetoresistance is enhanced from 6% to about 94% at room temperature due to annealing. Resistivity and Seebeck coefficient were investigated over the temperature range 83 ≤ T ≤ 313 K. The quasi-static magnetization was investigated in the temperature range of 5-400 K under effect of a magnetic field of 100 Oe in both moods of field cooling presence besides the zero field cooling. The measurements of magnetization showed Curie transition from ferromagnetic behavior to paramagnetic one. The Curie transition values increased with increasing the strontium content suggesting that the transfer integral between two Mn sites would be enhanced due to the substitution of smaller La ions (117.2 pm) by greater Sr ions (132 pm). Various parameters were calculated from the application of variable range hopping and single polaron hopping models. Both models were utilized to investigate the effect of Sr on the conduction behavior. The behavior of thermopower with temperature was demonstrated on the basis scatterings of phonon-and magnon-.
KEYWORDS
PAPER SUBMITTED: 2024-08-24
PAPER REVISED: 2024-10-27
PAPER ACCEPTED: 2024-11-19
PUBLISHED ONLINE: 2025-02-22
THERMAL SCIENCE YEAR
2025, VOLUME
29, ISSUE
Issue 1, PAGES [383 - 394]
- Dorr, K., Ferromagnetic Manganites: Spin-Polarized Conduction vs. Competing Interactions, J. Phys. D, Appl. Phys., 39 (2006), 125
- Ahmed, A. M., et al., The Annealing Influence on the Electrical and Magnetic Behavior of Magnetoresistive/Insulator System, J. Low Temp. Phys., 42 (2016), 9, pp. 951-958
- Jenker, G. H., van Santen, J. H., Ferromagnetic Compounds of Manganese with Perovskite Structure, Physica, 16 (1950), 337
- Jenker, G. H., van Santen, J. H., Electrical Conductivity of Ferromagnetic Compounds of Manganese with Perovskite Structure, Physica, 16 (1950), 599
- Zener, C., Interaction between the d-Shells in the Transition Metals, II Ferromagnetic Compounds of Manganese with Perovskite Structure, Phys. Rev., 82 (1951), 403
- Dinesh Varshney, D. N., Electrical Resistivity of the Hole Doped La0.8Sr0.2MnO3 Manganites: Role of Electron-Electron/Phonon-/Magnon-Interactions, Mate. Chem. Phys., 129 (2011), 3, pp. 896-904
- Ahmed, A. M., et al., Enhanced Electro-Magnetic Properties in La0.7Sr0.3MnO3/ZrO2 Composites, Indian J. Phys., 89 (2015), 6, pp. 561-570
- De Teresa, J. M. et al., Evidence for Magnetic Polarons in the Magnetoresistive Perovskites, Nature, 386 (1997), Mar., pp. 256-259
- Rao, C. N. R., Rachaudhuri, A. K., Colossal Magnetoresistance, Charge Ordering and Other Novel Properties of Manganites and Related Materials, 1 (1998), 13
- Mollah, S., et al., Adiabatic Small Polaron-Hopping Conduction in Ln0.85Ca0.15MnO3 (Ln=Nd, Pr and Sm) Perovskites, J. Phys. Chem. Solids, 69 (2008), 1023
- Iguchi, E., et al., Correlation between Hopping Conduction and Transferred Exchange Interaction in La2NiO4+δ below 300 K, Physica B, (1999), 3-4, pp. 270-332
- Tabuchi, A., et al., Dielectric Relaxation in LaSrCo1−xAlxO4 Ceramics, J. All. Compo., 1214 (2006), May, pp. 408-412
- Adam, A. M., et al., Effects of Transition Metal Element Doping on the Structural and Thermoelectric Properties of n-Type Bi2-xAgxSe3 Alloys, J. All. Compo., 851 (2021), 156887
- Ahmed, A. M., et al., Crystal Structure and Some Transport Properties of Na-Doped LaMnOy, J. Magm. Magn. Mater., 301 (2006), 452
- Mahesh, R., et al., Effect of Particle Size on the Giant Magnetoresistance of La0.7Ca0.3MnO3, Appl. Phys. Lett., 68 (1996), 2291
- Roy, S., et al., Interplay of Structure and Transport Properties of Sodium-Doped Lanthanum Manganite, J. Phys. Condens. Matter., 13 (2001), 9547
- Kouta, I., et al., Thermoelectric Properties of Polycrystalline La1−xSrxCoO3, Solid State Chem., 181 (2008), 11, pp. 3145-3150
- JDhahri, J., et al. The Effect of Deficit of Strontium on Structural, Magnetic and Electrical Properties of La0.8Sr0.2−x⋅xMnO3 Manganites, J. All. Compo., 394 (2005), 1-2, pp. 51-57
- Zemni, S., et al., The Effect of a Cation Radii on Structural, Magnetic and Electrical Properties of Doped Manganites La0.6−xPrxSr0.4MnO3, J. Solid State Chemistry, 177 (2004), 7, pp. 2387-2393
- Elsehly, E. M., et al., Annealing Effect on the Thermoelectric Properties of Multiwall Carbon Nanotubes, Physica E: Low-Dimensional Systems and Nanostructures, 146 (2023), 115566
- Dutta, A., Effect of Particle Size on the Magnetic and Transport Properties of La0.875Sr0.125MnO3, Phys. Rev. B, 68 (2003), 054432
- Furukawa, N., Transport Properties of the Kondo Lattice Model in the Limit S = ∞ and D = ∞, J. Phys. Soc. Jpn., 63 (1994), 3214
- Rao, C. N. R., Raychaudhur, A. K., Colossal Magneto- Resistance, Charge Order and Other Novel Properties of Manganites and Related Materials, World Scientific Publishing, Singapur, Singapur, 1998, p. 7
- Mannella, N., et al., Direct Observation of High-Temperature Polaronic Behavior in Colossal Magnetoresistive Manganites, Phys. Rev. Leters, 92 (2004), 16
- Sun, C. H., et al., The Transport Properties in Nd0.75Sr1.25CoO4 Film Evidence for Polaronic Transport, J. Phys. Chem. Solids, 70 (2009), pp. 286-290
- Austin, I. G., Mott, N. F., Polarons in crystalline and Non-Crystalline Materials, Adv. Phys., 18 (1969), 41
- Mollah, S., et al., Non-Adiabatic Small-Polaron Hopping Conduction in Pr0.65Ca0.35−xSrxMnO3 Perovskites above the Metal-Insulator Transition Temperature, J. Magm. Magn. Mater., 284 (2004), 1, pp. 383-394
- Soma, D., Dey, T. K., Thermoelectric Power of Potassium Doped Lanthanum Manganites at Low Temperatures, J. Magm. Magn. Mater., 311 (2007), 2, pp. 714-723
- Jaime, M., et al., High-Temperature Thermopower in La2/3Ca1/3MnO3 Films: Evidence for Polaronic Transport. Phys. Rev. B, 54 (1996), 11914
- Banerjee, P. S., Polaron Hopping Conduction and Thermoelectric Power in LaMnO3+δ, J. Appl. Phys., 89 (2001), 4955
- Viret, M., et al., Magnetic Localization in Mixed-Valence Manganites, Phys. Rev. B, 55 (1996), 8067
- Ravi, S., Kar, M., Study of Magneto-Resistivity in La1−xAgxMnO3, Compounds. Physica B, 348 (2004), 169
- Khan, W., et al., Small Polaron Hopping Conduction Mechanism in Fe Doped LaMnO3, J. Chem. Phys. 135 (2011), 054501
- Jung, W. H., Magnetic and Transport Properties of Ce2/3TiO2.981, J. Condens. Matter Phys., 17 (1998), 1317
- Banerjee, A., Nature of Small-Polaron Hopping Conduction and the effect of Cr Doping on the Transport Properties of Rare-Earth Manganite La0.5Pb0.5Mn1−xCrxO3, J. Chem. Phys., 115 (2001), 1550
- Ahmed, A. M., Influence of Heat Treatment on the Magnetic and Magnetocaloric Properties in Nd0.6Sr0.4MnO3 Compound, Solid State Sci., 57 (2016), July, pp. 1-8
- Abd El-Moez, A., Magnetoresistive and Magnetocaloric Response of Manganite/Insulator System, J. Alloys Compd., 657 (2016), Feb., pp. 495-505
- Venkataiah, G., Venugopal Reddy, P., Electrical Behavior of Sol-Gel Prepared Nd0.67Sr0.33MnO3 Manganite System, J. Magn. Magn. Mater., 285 (2005), 3, pp. 343-352
- Sagdeo, P. R., et al., The Contribution of Grain Boundary and Defects to the Resistivity in the Ferromagnetic State of Polycrystalline Manganites, J. Magn. Magn. Mater., 306 (2006), 1, pp. 60-68
- Y. Kalyana Lakshmi, P. Venugopal Reddy, Electrical Behavior of Some Silver-Doped Lanthanum-Based CMR Materials, J. Magn. Magn. Mater., 321 (2009), 9, pp. 1240-1245
- Adam, A. M., et al., Thermoelectric Power Properties of Ge doped PbTe Alloys, J. Alloys Compd., 872 (2021), 159630
- Nolas, G. S., et al., Thermoelectrics Basic Principles and New Materials Developments, Springer Series in Materials Science, Heidelberg, Germany, 2001, Vol. 45
- Jaime, M., et al., Magnetothermopower in La0.67Ca0.33MnO3 Thin Films, Appl. Phys. Lett., 68 (1996), 1576
- Mollah S., Non-Adiabatic Small-Polaron Hopping Conduction in Pr0.65Ca0.35-xSrxMnO3 Perovskites above the Metal-Insulator Transition Temperature, J. Magn. Magn. Mater., 284 (2004), 1, pp. 383-394
- Ravi, S., Kar, M., Study of Magneto-Resistivity in La1−xAgxMnO3 Compounds, Physica B, 348 (2004), 169
- Mandal, P., Emperature and Doping Dependence of the Thermopower in LaMnO3, Phys. Rev. B, 61 (2000), 14675
- Bhattacharya, S., et al., Effect of Li Doping on the Magnetotransport Properties, of La0.7Ca0.3−yLiyMnO3 System: Decrease of Metal-Insulator Transition Temperature, Appl. Phys. Lett., 82 (2003), 4103
- Kim, H. B., et al., Magnon-Drag Effect as the Dominant Contribution the Thermopower in Bi0.5−xLaxSr0.5MnO3 (0.1 ≤ x ≤ 0.4), J. Appl. Phys., 103 (2008), 3717