ABSTRACT
In this research endeavor, the influence of thermal hydrolysis treatment on product distribution obtained through the pyrolysis of hydrolysis treated sludge and raw sewage sludge was investigated. Raw sewage sludge sample was received from a municipal sewage sludge treatment plant, and hydrolysis of sewage sludge was performed at a temperature of 200°C and a pressure of 0.4 MPa in a fixed-bed furnace. The pore structure of the obtained biochar and non-condensable gas collected at various temperatures was analyzed via Brunauer, Emmett, and Teller and gas chromatography techniques, respectively. The results revealed that thermal hydrolysis treatment had a significant impact on product distribution at varying temperatures (500-800°C). An increase in temperature led to a decrease in the biochar and biooil yield, while the yield of gas increased for both hydrolysis treated sludge and raw sewage sludge. It was observed that the concentration of H2, CH4, and CO from hydrolysis treated sludge was higher than raw sewage sludge. Furthermore, it was observed that by increasing the temperature, the pore volume and specific surface area of the biochar increased while the average pore width decreased. The maximum Brunauer, Emmett, and Teller surface area was measured from biochar obtained from hydrolysis treated sludge at 800°C as 50.61 m2/g. The findings suggest that thermal hydrolysis treatment is a viable method for the treatment of sewage sludge as compared to conventional methods.
KEYWORDS
PAPER SUBMITTED: 2023-12-08
PAPER REVISED: 2024-01-17
PAPER ACCEPTED: 2024-01-25
PUBLISHED ONLINE: 2024-03-10
THERMAL SCIENCE YEAR
2024, VOLUME
28, ISSUE
Issue 5, PAGES [3817 - 3824]
- Xu, D., et al., New Insights into Impact of Thermal Hydrolysis Pretreatment Temperature and Time on Sewage Sludge: Structure and Composition of Sewage Sludge from Sewage Treatment Plant, Environ. Res., 191 (2020), 110122
- Ali, M., et al., The Effect of Hydrolysis on Properties of Soot and Tar During the Pyrolysis of Sewage Sludge, Waste and Biomass Valorization, 11 (2020), 7, pp. 3433-3442
- Peng, C., et al., In-Depth Comparison of Morphology, Microstructure, and Pathway of Char Derived from Sewage Sludge and Relevant Model Compounds, Waste Manag., 102 (2020), Feb., pp. 432-440
- Ali, M., et al., The Effect of Hydrolysis on Combustion Characteristics of Sewage Sludge and Leaching Behavior of Heavy Metals, Environ. Technol., 39 (2018), 20, pp. 2632-2640
- Chen, R., et al., Sludge-to-Energy Approaches Based on Pathways that Couple Pyrolysis with Anaerobic Digestion (Thermal Hydrolysis pre/post-Treatment): Energy Efficiency Assessment and Pyrolysis Kinetics Analysis, Energy, 190 (2020), 116240
- Moon, J., et al., Effects of Hydrothermal Treatment of Sewage Sludge on Pyrolysis and Steam Gasification, Energy Convers. Manag., 103 (2015), Oct., pp. 401-407
- Zhu, X., et al., Pyrolysis of Pre-Dried Dewatered Sewage Sludge under Different Heating Rates: Characteristics and Kinetics Study, Fuel, 255 (2019), 115591
- Singh, V., et al., Estimation of Energy Recovery Potential of Sewage Sludge in India: Waste To Watt Approach, J. Clean. Prod., 276 (2020), 122538
- Su, Y., et al., Investigation on the Decomposition of Chemical Compositions during Hydrothermal Conversion of Dewatered Sewage Sludge, Int. J. Hydrogen Energy, 44 (2019), 49, pp. 26933-26942
- Jeong, S. Y., et al., Influence of Thermal Hydrolysis Pretreatment on Physicochemical Properties and Anaerobic Biodegradability of Waste Activated Sludge with Different Solids Content, Waste Manag., 85 (2019), Feb., pp. 214-221
- Ngo, P. L., et al., Thermal Hydrolysis of Primary Sludge and Waste Activated Sludge Mixture: Biogas Production and Formation of Inhibitors, J. Clean. Prod., 428 (2023), 139354
- Ngo, P. L., et al., Mechanisms, Status, and Challenges of Thermal Hydrolysis and Advanced Thermal Hydrolysis Processes in Sewage Sludge Treatment, Chemosphere, 281 (2021), 130890
- He, C., et al., Co-Pyrolysis of Sewage Sludge and Hydrochar with Coals: Pyrolytic Behaviors and Kinetics Analysis Using TG-FTIR and a Discrete Distributed Activation Energy Model, Energy Convers. Manag., 203 (2020), 112226
- Liang, J., et al., Thermal Hydrolysis of Wastewater Sludge Followed by Fungal Fermentation for Organic Recovery and Hyphae Fiber Production, Engineering, 7 (2021), 2, pp. 203-211
- Selvarajoo, A., Oochit, D., Effect of Pyrolysis Temperature on Product Yields of Palm Fibre and Its Biochar Characteristics, Mater. Sci. Energy Technol., 3 (2020), 2, pp. 575-583
- Vuppaladadiyam, A. K., et al., Bio Oil and Biochar from the Pyrolytic Conversion of Biomass: A Current and Future Perspective on the Trade-off between Economic, Environmental, and Technical Indicators, Sci. Total Environ., 857 (2023), 159155
- Ghodke, P. K., et al., Pyrolysis of Sewage Sludge for Sustainable Biofuels and Value-Added Biochar Production, J. Environ. Manage., 298 (2021), 113450
- Tian, W., et al., Optimal Design of a Multi-Dimensional Validated Synergistic Extraction Process for the Treatment of Atmosphere-Vacuum Distillation Wastewater, Sci. Total Environ., 817 (2022), 152986
- Ghodke, P., Mandapati, R. N., Investigation of Particle Level Kinetic Modelling for Babul Wood Pyrolysis, Fuel, 236 (2019), Sept., pp. 1008-1017
- Jin, Q., et al., Synergistic Effects during Co-Pyrolysis of Biomass and Plastic: Gas, Tar, Soot, Char Products and Thermogravimetric Study, J. Energy Inst., 92 (2019), 1, pp. 108-117
- Lu, Q., et al., Research on the Migration and Transformation Mechanism of Nitrogen during Biomass Pyrolysis, Ranliao Huaxue Xuebao/Journal Fuel Chem. Technol., 51 (2023), 8, pp. 1047-1059
- Trinh, T. N., et al., Influence of the Pyrolysis Temperature on Sewage Sludge Product Distribution, BioOil, and Char Properties, Energy and Fuels, 27 (2013), 3, pp. 1419-1427
- Gogoi, D., et al., A Comprehensive Review on "Pyrolysis" for Energy Recovery, Bioenergy Res., 16 (2023), 3, pp. 1417-1437
- Feng, G., et al., Effects of Thermal Treatment on Physical and Expression Dewatering Characteristics of Municipal Sludge, Chem. Eng. J., 247 (2014), July, pp. 223-230
- Li, S., et al., Microwave Pyrolysis of Sludge: A Review, Sustain. Environ. Res., 32 (2022), 1
- Wang, Z., et al., Effect of Temperature on Pyrolysis of Sewage Sludge: Biochar Properties And Environmental Risks from Heavy Metals, E3S Web Conf., 237 (2021), 01040
- Tomczyk, A., et al., Biochar Physicochemical Properties: Pyrolysis Temperature and Feedstock Kind Effects, Rev. Environ. Sci. Biotechnol., 19 (2020), 1, pp. 191-215