THERMAL SCIENCE
International Scientific Journal
NUMERICAL SIMULATION OF CO2 ABSORPTION BY AMP SOLUTION IN STRUCTURED PACKING WITH DIFFERENT PARAMETER CONDITION
ABSTRACT
The FLUENT software is utilized in this research to simulate the CO2 absorption process by 2-amino-2-methyl-1-propyl (AMP) alcohol through numerical simulation. A mathematical model is established to represent the mass transfer process between the AMP alcohol solution and CO2. Various operating parameters, such as the molar fraction of the solution, gas mass fraction, pressure, and gas-flow velocity, are investigated to calculate the absorption efficiency of CO2 under different conditions. The distribution of the product reveals that the AMP alcohol carbamate product more readily infiltrates the surface of the unit model when the gas phase velocity is relatively low. In contrast, the product AMP alcohol carbamate tends to accumulate in the upper half of the unit model when the gas phase velocity is relatively high. Sixteen simulation conditions are summarized to determine the optimal parameters. These optimal parameters include a AMP alcohol molar fraction of 0.4, atmospheric pressure, a flue gas-flow velocity of 0.0737 m/s, and a CO2 mass fraction of 0.12. This research serves as a valuable reference for engineering applications related to CO2 absorption using AMP alcohol solutions, providing essential technical support in the fight against climate change.
KEYWORDS
PAPER SUBMITTED: 2023-11-09
PAPER REVISED: 2024-01-07
PAPER ACCEPTED: 2024-01-15
PUBLISHED ONLINE: 2024-03-10
THERMAL SCIENCE YEAR
2024, VOLUME
28, ISSUE
Issue 4, PAGES [3293 - 3305]
- Zou, C., et al., Energy Revolution: From a Fossil Energy Era to A New Energy Era, Natural Gas Industry B, 3 (2016), 1, pp. 1-11
- Bragatto, T., et al., Electrical Energy Production from Coal: Technical and Economic Performances during the Last Twenty Years, Proceedings, 2022 IEEE International Conference on Environment and Electrical Engineering and 2022 IEEE Industrial and Commercial Power Systems Europe (EEEIC /I&CPS Europe), Prague, Czech Republic, 2022, pp. 1-6
- Andrew, R. M., Global CO2 Emissions from Cement Production, 1928-2018, Earth System Science Data, 11 (2019), 4, pp. 1675-1710
- Wang, Y., et al., Integrated assessment of CO2 Reduction Technologies in China's Cement Industry, International Journal of Greenhouse Gas Control, 20 (2014), Jan., pp. 27-36
- Guo, J., et al., Numerical Investigation on Oxy-Combustion Characteristics of a 200 MWe Tangentially Fired Boiler, Fuel, 140 (2015), Jan., pp. 660-668
- Wang, T., et al., Amine Reclaiming Technologies in Post-Combustion Carbon Dioxide Capture, Journal of Environmental Sciences, 27 (2015), Jan., pp. 276-289
- Cui, Z., et al., Waste Heat Recovery and Cascade Utilization of CO2 Chemical Absorption System Based on Organic Amine Method in Heating Season, Applied Thermal Engineering, 230 (2023), 120834
- Zhou, X., et al., Multi-Dimensional Assessment for the Novel Carbon Capture Process Integrated the Low-Temperature Adsorption and Desorption, Chemical Engineering Science, 282 (2023), 119207
- Luis, P., Use of Monoethanolamine (MEA) for CO2 Capture in a Global Scenario: Consequences and Alternatives, Desalination, 380 (2016), Feb., pp. 93-99
- Benamor, A., Aroua, M. K., An Experimental Investigation on the Rate of CO2 Absorption into Aqueous Methyldiethanolamine Solutions, Korean Journal of Chemical Engineering, 24 (2007), 1, pp. 16-23
- Feng, Z., et al., Absorption of CO2 in the Aqueous Solutions of Functionalized Ionic Liquids and MDEA, Chemical Engineering Journal, 160 (2010), 2, pp. 691-697
- Kierzkowska-Pawlak, H., et al., Kinetics of CO2 Desorption from Aqueous n-methyldiethanolamine Solutions, Chemical Engineering Journal, 168 (2011), 1, pp. 367-375
- Ahmady, A., et al., Kinetics of Carbon Dioxide absorption into aqueous MDEA+
- Glazyrin, S. A., et al., Study of the Possibilities of Integrated Treatment of Flue Gases and Waste-Water from Coal-Fired Heat Power Plants, Thermal Science, 25 (2021), 6A, pp. 4333-4345
- Bougie, F., Iliuta, M. C., Sterically Hindered Amine-Based Absorbents for the Removal of CO2 from Gas Streams, Journal of Chemical and Engineering Data, 57 (2012), 3, pp. 635-669
- Conway, W., et al., Toward the Understanding of Chemical Absorption Processes for Post-Combustion Capture of Carbon Dioxide: Electronic and Steric Considerations from the Kinetics of Reactions of CO2 (aq) with Sterically Hindered Amines, Environmental Science and Technology, 47 (2013), 2, pp. 1163-1169
- Bougie, F., Iliuta, M. C., Kinetics of Absorption of Carbon Dioxide into Aqueous Solutions of 2-amino-2-hydroxymethyl-1,3-propanediol, Chemical Engineering Science, 64 (2009), 1, pp. 153-162
- Sartori, G., Savage, D. W., Sterically Hindered Amines for Carbon Dioxide Removal from Gases, Industrial and Engineering Chemistry Fundamentals, 22 (1983), 2, pp. 239-249
- Khan, A. A., et al., Carbon Dioxide Capture Characteristics from Flue Gas Using Aqueous 2-amino-2-methyl-1-propanol (AMP) and monoethanolamine (MEA) Solutions in Packed Bed Absorption and Regeneration Columns, International Journal of Greenhouse Gas Control, 32 (2015), Jan., pp. 15-23
- Jamali, M., Azari, A., A Review on Computational Fluid Dynamics Simulations of Industrial Amine Absorber Columns for CO2 Capture, Chembioeng Reviews, 10 (2023), 1, pp. 6-21
- Huang, B., et al., Industrial test of CO2 Capture in Huaneng Beijing Coal-Fired Power Station, Proceedings of the CSEE, 29 (2009), 17, pp. 14-20
- Vaidya, P. D., Jadhav, S. G., Absorption of Carbon Dioxide into Sterically Hindered Amines: Kinetics Analysis and the Influence of Promoters, The Canadian Journal of Chemical Engineering, 92 (2014), 12, pp. 2218-2227
- Saha, A. K., et al., Solubility and Diffusivity of Nitrous Oxide and Carbon Dioxide in Aqueous Solutions of 2-amino-2-methyl-1-propanol, Journal of Chemical and Engineering Data, 38 (1993), 1, pp. 78-82
- Versteeg, G. F., et al., Solubility and Diffusivity of Acid Gases (Carbon Dioxide, Nitrous Oxide) in Aqueous Alkanolamine Solutions, Journal of Chemical and Engineering Data, 33 (1988), 1, pp. 29-34
- Sherman, B. J., et al., Thermodynamic and Mass-Transfer Modelling of Carbon Dioxide Absorption into Aqueous 2-Amino-2-Methyl-1-Propanol, Industrial and Engineering Chemistry Research, 56 (2017), 1, pp. 319-330
- Kim, Y. E., et al., Comparison of Carbon Dioxide Absorption in Aqueous MEA, DEA, TEA, and AMP Solutions, Bulletin of the Korean Chemical Society, 34 (2013), 3, pp. 783-787
- Higbie, R., The Rate of Absorption of a Pure Gas into a Still Liquid during Short Periods of Exposure, Trans. AIChE, 31 (1935), pp. 365-389