International Scientific Journal

External Links


It is generally considered that the thermochemical sulfate reduction is one of the main origins of high content of hydrogen sulfide (H2S). Thermochemical sulfate reduction simulation experiments at different temperatures ranging from 200°C to 600°C were carried out to study the output of gaseous products, which include CO2, CH4, H2S, and heavy hydrocarbon (C2-6). Thermochemical sulfate reduction can promote the formation of CH4 and H2S, and can preferentially consume heavy hydrocarbons. The CH4 is difficult to participate in the reaction of formation H2S. The concentrations of CO2 and hydrogen are closely related to the evolution characteristics of H2S. The intermediate sulfur-containing products from thermochemical reaction and thermal cracking of coals can promote the progress of thermochemical sulfate reduction and possible formation of H2S.
PAPER REVISED: 2019-09-21
PAPER ACCEPTED: 2019-09-21
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2020, VOLUME 24, ISSUE Issue 4, PAGES [2475 - 2483]
  1. Cai, C. F., et al., Relative Reactivity of Saturated Hydrocarbons During Thermochemical Sulfate Reduction, Fuel, 253 (2019), Oct., pp. 106-113
  2. Geoffrey S., et al., Effects of Thermal Maturation and Thermochemical Sulfate Reduction on Com-pound-Specific Sulfur Isotopic Compositions of Organosulfur Compounds in Phosphoria Oils from the Bighorn Basin, USA, Organic Geochemistry, 103 (2017), 1, pp. 63-78
  3. Deng Q. G., et al., A Study of Hydrogen Sulfide Genesis in Coal Mine of Southeastern Margin of Jung-gar Basin, (in Chinese), Earth Science Frontiers, 24 (2017), 5, pp. 395-401
  4. Liu, M. J., et al., Origin of Hydrogen Sulfide in Coal Seams in China, Safety Science, 50 (2012), 4, pp. 1031-1038
  5. Deng, Q. G., et al., Research Advances of Prevention and Control of Hydrogen Sulfide in Coal Mines, The Scientific World Journal, 2019 (2019), ID 8719260
  6. Biehl, B. C., et al., Impacts of Hydrothermal Dolomitization and Thermochemical Sulfate Reduction on Secondary Porosity Creation in Deeply Buried Carbonates: A Case Study from the Lower Saxony Basin, Northwest Germany, Am. Assoc. Pet. Geol. Bull, 100 (2016), 4, pp. 597-621
  7. Deng, Q. G., et al., Thermal Simulation Experiment and Research on the System of coal/coal & water/coal & water & MgSO4/coal & water & CaSO4, Desalination and Water Treatment, 149 (2019), 5, pp. 388-397
  8. Cross, M. M., et al., Thermochemical Sulphate Reduction (TSR): Experimental Determination of Reaction Kinetics and Implications of the Observed Reaction Rates for Petroleum Reservoirs, Organic Geo-chemistry, 35 (2004), 4, pp. 393-404
  9. Zhang, P. W., et al., Alteration of Solid Bitumen by Hydrothermal Heating and Thermochemical Sulfate Reduction in the Ediacaran and Cambrian Dolomite Reservoirs in the Central Sichuan Basin, SW China, Precambrian Research, 321 (2018), 2, pp. 277-302
  10. Wu, B. X., et al., Study on Gas Generation from Low Maturity Asphalt in Sichuan Basin, Journal of China Coal Society, 38 (2013), 5, pp. 748-753
  11. Michael G., et al., The World-Class Howard's Pass SEDEX Zn-Pb District, Selwyn Basin, Yukon, Part II: The Roles of Thermochemical and Bacterial Sulfate Reduction in Metal Fixation, Mineralium Deposita, 52 (2017), 3, pp. 405-419
  12. Xiao, Q. L., et al., The Effects of Selected Minerals on Laboratory Simulated Thermochemical Sulfate Reduction. Organic Geochemistry, 122 (2018), 8, pp. 41-45
  13. Geoffrey S., et al., Effects of Thermal Maturation and Thermochemical Sulfate Reduction on Com-pound-Specific Sulfur Isotopic Compositions of Organosulfur Compounds in Phosphoria Oils from the Bighorn Basin, USA, Organic Geochemistry, 103 (2017), 1, pp. 63-78
  14. Lin, R. Y., et al., Hydrogen Suifide Formation Mechanism in the Process of Thermal Recovery, Acta Petrolei Sinica in Chinese, 35 (2014), 6, pp. 1153-1159
  15. Zhang, J. Y., et al., Influences of TSR on Gaseous Hydrocarbon Components and Carbon Isotopes: Revelations from High-Temperature and High-Pressure Simulation Experiments, (in Chinese), Petroleun Geology & Experiment, 34 (2012), 1, pp. 66-70
  16. Amrani, A., et al., The Role of Labile Sulfur Compounds in Thermochemical Sulfate Reduction, Geochimica et Cosmochimica Acta, 72 (2008), 12, pp. 2960-2972
  17. Hao, F., et al., The Fate of CO2 Derived from Thermochemical Sulfate Reduction(TSR) and Effect of TSR on Carbonate Porosity and Permeability, Sichuan Basin, (in Chinese), China, Earth Science Re-views, 141 (2015), 5, pp. 154-177
  18. Kelemen, S. R., et al., Characterization of Solid Bitumens Originating from Thermal Chemical Alteration and Thermochemical Sulfate Reduction, Geochimica et Cosmochimica Acta, 74 (2010), 18, pp. 5305-5332
  19. Zhao, H., et al., Study of Thermochemical Sulfate Reduction of Different Organic Matter: Insight from Systematic TSR Simulation Experiments, Marine and Petroleum Geology, 100 (2019), 2, pp. 434-446
  20. Mankiewicz, P. J., et al., Gas Geochemistry of the Mobile Bay Jurassic Norphlet Formation: Thermal Controls and Implications for Reservoir Connectivity, Am. Assoc. Pet. Geol. Bull, 93 (2009), 10, pp. 19-1346
  21. Gvirtzman, Z., et al., Compound-Specific Sulfur Isotope Analysis of Thiadiamondoids of Oils from the Smackover Formation, USA, Geochimica et Cosmochimica Acta, 167 (2015), 10, pp. 144-161
  22. Zhu, G. Y., et al., Discovery of the Lower Cambrian High-Quality Source Rocks and Deep Oil and Gas Exploration Potential in the Tarim Basin, China, Am. Assoc. Pet. Geol. Bull, 102 (2018), 10, pp. 2123-2151
  23. Li, K. K., et al., Fluid Inclusion and Stable Isotopic Studies of Thermochemical Sulfate Reduction: Up-per Permian and Lower Triassic Gas fields, Northeast Sichuan Basin, China, Geochimca Cosmochimca Acta, 246 (2019), 1, pp. 86-108
  24. Jenden, P. D., et al., Enrichment of Nitrogen and 13C of Methane in Natural Gases from the Khuff Formation, Saudi Arabia, Caused by Thermochemical Sulfate Reduction, Organic Geochemistry, 82 (2015), 5, pp. 54-68
  25. Wang, Y., et al. A Variational Formulation for Anisotropic Wave Traveling in a Porous Medium, Fractals, 27 (2019), June, 1950047
  26. Wang, K. L., He, C. H., A Remark on Wang's Fractal Variational Principle, Fractals, 27 (2019), 8, ID 1950134
  27. Wang, Y., Deng, Q. G., Fractal Derivative Model for Tsunami Traveling, Fractals, 27 (2019), 2, 1950017
  28. Wang, Y., et al., A Fractal Derivative Model for Snow's Thermal Insulation Property, Thermal Science, 23 (2019), 4, pp. 2351-2354
  29. He, J. H., Fractal Calculus and Its Geometrical Explanation, Results in Physics, 10 (2018), Sep., 272-276
  30. He, J. H., A Simple Approach to One-Dimensional Convection-Diffusion Equation and Its Fractional Modification for E Reaction Arising in Rotating Disk Electrodes, Journal of Electroanalytical Chemistry, 854 (2019), 113565
  31. Wang, Q. L., et al. Fractal Calculus and Its Application to Explanation of Biomechanism of Polar Bear hairs, Fractals, 26 (2018), 6, 1850086
  32. Wang, Q. l., et al. Fractal calculus and Its Application to Explanation of Biomechanism of Polar Bear Hairs (vol. 26, 1850086, 2018), Fractals, 27 (2019), 5, ID 1992001
  33. He, J. H., Ji, F. Y., Two-Scale Mathematics and Fractional Calculus for Thermodynamics, Thermal Science, 23 (2019), 4, pp. 2131-2133
  34. Ain, Q. T., He, J. H., On Two-Scale Dimension and Its Applications, Thermal Science, (2019), 3B, pp. 1707-171223
  35. Fan, J., et al., Fractal Calculus for Analysis of Wool Fiber: Mathematical Insight of Its Biomechanism, Journal of Engineered Fibers and Fabrics, On-line first,, 2019

© 2022 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence