THERMAL SCIENCE

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Evgeny I. Kraus

,

Ivan I. Shabalin

MELTING BEHIND THE FRONT OF THE SHOCK WAVE

ABSTRACT
A simple caloric model of the equation of state is proposed to describe thermodynamic properties of solid materials with phase transitions with the minimum number of parameters as initial data. Thermodynamic characteristics are calculated in the wide range of densities and pressures. The equation of state of the solid phase was modified by introducing configurational entropy, which made it possible to describe a liquid medium by the same functional dependence, but with its initial parameters. This allowed us not only to construct the equation of state for the liquid, but also to determine the dependence of the melting point on pressure as the boundary between the phases with the corresponding state. It is shown that the melting process is practically not noticeable on the shock adiabat in the pressure - volume plane; however, sharp adiabatic breaks are observed in the temperature - pressure plane. The calculated position of the melting curve agrees with the experimental data found; although this does not fully justify the conclusion about the accuracy of the calculation of the liquid phase adiabat, but fully confirms the qualitative picture.
KEYWORDS
equation of state, melting curve, height pressure, phase, equilibrium condition
PAPER SUBMITTED: 2018-09-07
PAPER REVISED: 2018-12-03
PAPER ACCEPTED: 2018-12-13
PUBLISHED ONLINE: 2019-05-05
DOI REFERENCE: https://doi.org/10.2298/TSCI19S2519K
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2019, VOLUME 23, ISSUE Supplement 2, PAGES [S519 - S524]
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Melting behind the front of the shock wave

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence