THERMAL SCIENCE

International Scientific Journal

External Links

ANALYSIS OF THE DYNAMIC BEHAVIOUR OF A BURNING POROUS CHAR PARTICLE

ABSTRACT
The mathematical model developed describes the dynamic behaviour of a porous char particle during combustion. The model of the char particle involves two exothermic reactions: C + O2 = x:CO + y-CO2 — heterogeneous reaction on the internal and external char particle surfaces, and CO + O = CO2— homogeneous reaction inside the char particle. The temperature and gas concentration fields inside the char particle are defined by partial differential equations of heat and mass conservation. Changes of internal surface area and porosity during combustion are included in the mathematical model. The mathematical model results were compared with experiments done in a laboratory fluidized bed reactor. The comparison showed that the model predictions are in a very good accordance with experiments. The model successively followed combustion regime changes with bed temperature and coal type.
PAPER SUBMITTED: 1998-04-15
PAPER REVISED: 1998-06-30
PAPER ACCEPTED: 1999-07-22
PUBLISHED ONLINE: 2020-09-27
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 1998, VOLUME 2, ISSUE Issue 2, PAGES [61 - 73]
REFERENCES
  1. Srinivas, B., Amundson, N., A Single-Particle Char Gasification Model, AJChE, 26 (1980), 3, p. 487
  2. Sotirchos, S., Amundson, N., Diffusion and Reaction in a Char Particle and in the Surrounding Gas Phase, A Continuous Model, Ind. Eng. Chem. Fundam., 23 (1984), 2, p. 191
  3. Sotirchos, S., Burganos, V., Intraparticle Diffusion and Char Combustion, Chemical Engineering Science, 41 (1986), 6, p. 1599
  4. Hsuen, D., Sotirchos, S., Multiplicity Analysis of Intraparticle Char Combustion, Chemical Engineering Science, 44 (1989), 11, p. 2639
  5. Arthur, J., Reactions Between Carbon and Oxygen, Trans. Faraday Soc., 47 (1951), p. 164
  6. Baskakov, A., Filipovski, N., Munts, N., Temperature of Particles Heated in a Fluidized Bed of Inert Material, Journal Engineering Physics, 52 (1987), p. 574
  7. LaNauze, R., Jung, K., Mass Transfer Relationships in Fluidized Bed Combustors, Chem. Eng. Commun., 43 (1986), p. 275
  8. Patankar, S.,V., Numerical Heat Transfer and Fluid Flow, Hemisphere Publishing Corp., USA, 1980
  9. Bhatia, S., Perlmuttcr, D., A Random Pore Model for Fluid-Solid Reactions, I. Isothermal, Kinetic Control, AIChE, 26 (1980), 3, p. 379
  10. Laurendeau, N.: Heterogeneous Kinetics of Coal Char Gasification and Combustion, Progress in Energy and Combustion Sciences, 4 (1978), p. 221
  11. Ilić, M., Combustion of Char Particle in Unsteady Regimes of Fluidized Bed Combustors, Ph.D. Thesis (in Serbian), Faculty of Mechanical Engineering, Belgrade, 1998
  12. Dikalenko, V. A., Palchonok, G. I., Borodulya, V. A., Larfeld, J., Leckner, B., Model of Drying and Devolatilization of Biomass Particles of Different Shapes, 32nd IEA FBC Meeting, Géteborg, Sweden, 1996
  13. Smith, I.,W., The Intrinsic Reactivity of Carbons to Oxygen, Fuel, 57, (1978) 7, pp. 409-414
  14. Scholer, J., Ein Gesamtmodell für Dampferzeugeranlagen mit zirkulierender Wirbelschichtfeuerung, Ph. D. Thesis, Siegen University, Germany, 1992

© 2024 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence