THERMAL SCIENCE

International Scientific Journal

Authors of this Paper

External Links

THE INFLUENCE OF TEMPERATURE ON THE ADSORPTION OF CATIONIC SURFACTANTS ON MUSCOVITE MICA

ABSTRACT
The attention in this paper is directed toward the modification of the mica surface by adsorption of quaternary ammonium surfactants, and the influence of temperature on the adsorption process. The aim is to produce a very well-ordered hydrophobic surface. In order to produce adsorbed layers, we realized numerous experiments and applied the solutions of different surfactants concentrations, be-low and above the critical micelle concentration. The characterization of adsorbed layers was performed by contact angle measurements and atomic force microscopy imaging, and we observed films of variable morphology. The influence of many parameters is responsible for different results, such as solution concentration, and temperature, humidity in sample analysis, as well as substrate properties (muscovite mica). Special attention was paid to the influence of temperature on the solution properties and the stability of the deposited surfactants layers.
KEYWORDS
PAPER SUBMITTED: 2018-04-15
PAPER REVISED: 2018-08-21
PAPER ACCEPTED: 2018-09-02
PUBLISHED ONLINE: 2019-01-19
DOI REFERENCE: https://doi.org/10.2298/TSCI18S5471M
CITATION EXPORT: view in browser or download as text file
THERMAL SCIENCE YEAR 2018, VOLUME 22, ISSUE Supplement 5, PAGES [S1471 - S1481]
REFERENCES
  1. Casalini, S., et al., Self-Assembled Monolayers in Organic Electronics, Chemical Society Review, 46 (2017), 1, pp. 40-71
  2. Swalen, J. D., et al., Molecular Monolayers and Films, Langmuir, 3 (1987), 6, pp. 932-950
  3. Mitić, V., et al., Dielectric Properties of BaTiO3 Ceramics and Curie-Weiss and Modified Curie-Weiss Affected by Fractal Morphology, Advanced Processing and Manufacturing Technologies for Nanostructured and Multifunctional Materials, Ceramic Engineering and Science Proceedings, 35 (2014), 6, pp. 123-133
  4. Stojanovic, D., et al., Screen Printed PLZT Thick Films Prepared from Nanopowders, Journal of the Eu-ropean Ceramic Society, 27 (2007), 13-15, pp. 4359-4362
  5. Thorkelssona, K., et al., Self-Assembly and Applications of Anisotropic Nanomaterials: A review, Nano Today, 10 (2015), 1, pp. 48-66
  6. Whitesides, G. M., Grzybowski B., Self-Assembly at All Scales, Science, 295 (2002), 5564, pp. 2418-2421
  7. Patel, J. R., Deheri G., A Study of thin Film Lubrication at Nanoscale for a Ferrofluid Based Infinitely Long Rough Porous Slider Bearing, Facta Universitatis Series: Mechanical Engineering, 14 (2016), 1, pp. 89-99
  8. Mellott, J. M., Schwartz, D. K., Supercritical Self-Assembled Monolayer Growth, Journal of the Ameri-can Chemical Society, 126 (2004), 30, pp. 9369-9373
  9. Carpick, R. W., Salmeron, M., Scratching the Surface: Fundamental Investigations of Tribology with Atomic Force Microscopy, Chemical Reviews, 97 (1997), 4, pp. 1163-1194
  10. Schwartz, D. K., Mechanisms and Kinetics of Self-Assembled Monolayer Formation, Annual Review of Physical Chemistry, 52 (2001), 1, pp. 107-137
  11. Donglei, B., et al., Impact of Nanografting on the Local Structure of Ternary Self-Assembled Monolay-ers, Nano Research, 8 (2015), 6, pp. 2102-2114
  12. Doudevski, I., Schwartz, D. K., Self-Assembled Monolayers in the Context of Epitaxial Film Growth, Applied Surface Science, 175 (2001), May, pp. 17-26
  13. Adamkiewicz, M., et al., Organic Chemistry on Surfaces: Direct Cyclopropanation by Dihalocarbene Addition to Vinyl Terminated Self-Assembled Monolayers (SAM), Journal of Organic Chemistry, 10 (2014), Dec., pp. 2897-2902
  14. Scherge, M., Schaefer, J. A., Microtribological Investigations of Stick/Slip Phenomena Using a Novel Oscillatory Friction and Adhesion Tester, Tribology Letters, 4 (1998), 1, pp. 37-42
  15. Hang C., Tribological Properties of Ultrathin Films for MEMS Applications, M. Sc. of Applied Science Graduate Department of Mechanical and Industrial Engineering, University of Toronto, Toronto, Ont., Canada, 2014
  16. Jaschke, M., et al., Surfactant Aggregates at a Metal Surface, Langmuir, 13 (1997), 6, pp. 1381-1384
  17. Sui, W., et al., Comparative Anti-Corrosion Properties of Alkylthiols SAM and Mercapto Functional Silica Sol-Gel Coatings on Copper Surface in Sodium Chloride Solution, Journal of Sol-Gel Science and Technology, 80 (2016), 2, pp. 567-578
  18. Schon, J. H., Bao, Z., Nanoscale Organic Transistors Based on Self-Assembled Monolayers, Applied Physics Letters, 80 (2002), 5, pp. 847-849
  19. Han, J., et al., Nanoscale Vacuum Channel Transistor, Nano Letters, 17 (2017), 4, pp. 2146-2151
  20. Chaki, N. K., Vijayamohanan, K., Self-Assembled Monolayers as a Tunable Platform for Biosensor Ap-plications, Biosensors & Bioelectronics, 17 (2002), 1-2, pp. 1-12
  21. Vendruscolo, M., Dobson, M. C., Protein Self-Assembly Intermediates, Nature chemical biology, 9 (2013), Mar., pp. 216-217
  22. Abe, K., et al., Dynamic Contact Angle Measurement of Au(111)-Thiol Self-Assembled Monolayers by the Wilhelmy Plate Method, Langmuir, 16 (2000), 5, pp. 2394-2397
  23. Chaki, N. K., et al., Applications of Self-Assembled Monolayers in Materials Chemistry, Proceedings, Indian Academy of Sciences-Chemical Sciences, 2001, Vol. 113, 5-6, pp. 659-670
  24. Brovelli, D., et al., Highly Oriented, Self-Assembled Alkanephosphate Monolayers on Tantalum (V) Oxide Surfaces, Langmuir, 15 (1999), 13, pp. 4324-4327
  25. Ulman, A., An Introduction to Ultrathin Organic Films: from Langmuir-Blodgett to Self-Assembly, Aca-demic Press, London, 1991
  26. He, Y., Study on the Interfacial Properties of Surfactants and their Interactions with DNA, Ph. D. thesis, University of Paris, Paris, SUD XI, 2013
  27. Perkin, S., et al., Stability of Self-Assembled Hydrophobic Surfactant Layers in Water, Journal of Phys-ical Chemistry B, 109 (2005), 9, pp. 3832-3837
  28. Tang, T., et al., Ion-Exchange and DNA Molecular Dip-Sticks: Studying the Nanoscale Surface Wetting of Muscovite Mica, Journal of Physical Chemistry C, 118 (2014), 9, pp. 4695-4701
  29. Sakai, H., et al., Atomic Force Microscopy Observation of the Nanostructure of Tetradecyltrime-thylammonium Bromide Films Adsorbed at the Mica/Solution Interface, Langmuir, 17 (2001), 6, pp. 1817-1820
  30. Manne, S., et al., Direct Visualization of Surfactant Hemimicelles by Force Microscopy of the Electrical Double-Layer, Langmuir, 10 (1994), 12, pp. 4409-4413
  31. Feng, T., Nanoscale Surface Chemistry In Self- and Directed-Assembly of Organic Molecules on Solid Surfaces and Synthesis of Nanostructured Organic Architectures, Pure and Applied Chemistry, 80 (2008), 1, pp. 45-57
  32. Horr, T. J., et al., XPS Film Thickness and Adsorption Studies of Alkyltrimethylammonium Bromides and Organosilanes on Silica Surfaces, Colloids and Surfaces A-Physicochemical and Engineering As-pects, 102 (1995), Sep., pp. 181-190
  33. Xu ,L., et al., Flotation and Adsorption of Mixed Cationic/Anionic Collectors on Muscovite Mica, Min-erals Engineering, 41 (2013), Feb., pp. 41-45
  34. Nishimura, S., et al., AFM Studies of Amine Surfactant Hemimicelle Structures at the Mica-Water Inter-face, Colloids and Surfaces A-Physicochemical and Engineering Aspects, 103 (1995), 3, pp. 289-298
  35. Patrick, H. N., et al., Surface Micellization Patterns of Quaternary Ammonium Surfactants on Mica, Langmuir, 15 (1999), 5, pp. 1685-1692
  36. Ducker, W. A., Wanless, E. J., Adsorption of Hexadecyltrimethylammonium Bromide to Mica: Na-nometer-Scale Study of Binding-Site Competition Effects, Langmuir, 15 (1999), 1, pp. 160-168
  37. Choi, J., et al., Role of Chain Length and Type on the Adsorption Behavior of Cationic Surfactants and the Silica Floatability, Materials Transactions, 55 (2014), 8, pp. 1344-1349
  38. Mellott, J. M., et al., Kinetics of Octadecyltrimethylammonium Bromide Self-Assembled Monolayer Growth at Mica from an Aqueous Solution, Langmuir, 20 (2004), 6, pp. 2341-2348
  39. Fujii, M., et al., Heterogeneous Growth and Self-Repairing Processes of Two-Dimensional Molecular Aggregates of Adsorbed Octadecyltrimethylammonium Bromide at Cleaved Mica Aqueous Solution In-terface as Observed by in situ Atomic Force Microscopy, Langmuir, 15 (1999), 10, pp. 3689-3692
  40. Li, B. Y., et al., Time Dependent Anchoring of Adsorbed Cationic Surfactant Molecules at Mice/Solution Interface, Journal of Colloid and Interface Science, 209 (1999), 1, pp. 25-30
  41. Eskilsson, K., Yaminsky, V. V., Deposition of Monolayers by Retraction from Solution: Ellipsometric Study of Cetyltrimethylammonium Bromide Adsorption at Silica-Air and Silica-Water Interfaces, Langmuir, 14 (1998), 9, pp. 2444-2450
  42. Ceotto, G., et al., Ionic Surfactant Films Imaged by Atomic Force Microscopy, Journal of Molecular Catalysis A-Chemical, 167 (2001), 1-2, pp. 225-233
  43. Doudevski, I., Schwartz, D. K., Mechanisms of Self-Assembled Monolayer Desorption Determined us-ing in Situ Atomic Force Microscopy, Langmuir, 16 (2000), 24, pp. 9381-9384
  44. Whitby, C. P., et al., The Adsorption of Dodecyltrimelhylammonium Bromide on Mica in Aqueous So-lution Studied by X-Ray Diffraction and Atomic Force Microscopy, Journal of Colloid and Interface Science, 235 (2001), 2, pp. 350-357
  45. Abe, K., Ohnishi, S., Stability of Dimethyldioctadecylammonium Bromide Monolayers on Cleaved Mi-ca in Water and at the Air/Water Interface, Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers, 36 (1997), 10, pp. 6511-6517
  46. Chen, Y. L., et al., Molecular Mechanisms Associated with Adhesion and Contact-Angle Hysteresis of Monolayer Surfaces, Journal of Physical Chemistry, 95 (1991), 26, pp. 10736-10747
  47. Chen, Y. L., Israelachvili, J. N., Effects of Ambient Conditions on Adsorbed Surfactant and Polymer Monolayers, Journal of Physical Chemistry, 96 (1992), 19, pp. 7752-7760
  48. Boschkova, K., et al., Lubrication in Aqueous Solutions Using Cationic Surfactants - a Study of Static and Dynamic Forces, Langmuir, 18 (2002), 5, pp. 1680-1687
  49. Manojlovic, J., Structure, Morphology and History Effects in Surfactant Self-Assembly, Ph. D. thesis, ETH Zurich, Switzerland, 2006
  50. Lamont, R. E., Ducker, W.A., Surface-Induced Transformations for Surfactant Aggregates, Journal of the American Chemical Society, 120 (1998), 30, pp. 7602-7607
  51. Zhao, F., et al., Adsorption Behavior of Hexadecyltrimethylammonium Bromide (CTAB) to Mica Sub-strates as Observed by Atomic Force Microscopy, Science in China Series B: Chemistry, 48 (2005), 2, pp. 101-106
  52. Sharma, B. G., et al., Characterization of Adsorbed Ionic Surfactants on a Mica Substrate, Langmuir, 12 (1996), 26, pp. 6506-6512
  53. Myers, D., Surfactant Science and Technology, 3rd ed., Wiley-Interscience, New York, USA, 2006
  54. Vakarelski, I. U., et al., Lateral Force Microscopy Investigation of Surfactant-Mediated Lubrication from Aqueous Solution, Langmuir, 20 (2004), 5, pp. 1724-1731
  55. Davey, T. W., et al., Krafft Temperature Depression in Quaternary Ammonium Bromide Surfactants, Langmuir, 14 (1998), 12, pp. 3210-3213
  56. Kekicheff, P., et al., Adsorption of Cetyltrimethylammonium Bromide to Mica Surfaces below the Criti-cal Micellar Concentration, Colloids and Surfaces, 40 (1989), 1-2, pp. 31-41

© 2019 Society of Thermal Engineers of Serbia. Published by the Vinča Institute of Nuclear Sciences, Belgrade, Serbia. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International licence